Novel Trends in Electroorganic Synthesis

Front Matter....Pages II-XXI
Front Matter....Pages 1-1
Electroactivation of Transition Metal Redox Couples for the Carbonylation of Alcohols to Dialkylcarbonates....Pages 3-6
Electroorganic Cyclisation of Oxygen-Containing Compounds....Pages 7-10
Electrochemical Oxidation of Alcohol with Nickel Hydroxide Electrocatalyst Studied by the in Situ Techniques: Infrared Spectroscopy, Potential Modulated Reflectance Spectroscopy and Electrochemical Methods. An Attempt for Electrooganic Synthesis of Organic Acids....Pages 11-14
Redox Catalysis of Novel Heterocyclic o -Quinone Coenzymes....Pages 15-18
Natural Product Syntheses Using Phenolic Oxidation in the Key Step....Pages 19-22
Reactivity of O,O’-Dihalogenated Phenols in Anodic Oxidations....Pages 23-24
Electrochemical Synthesis of Euglobal Skeletons via Biomimic Cycloaddition....Pages 25-28
Electrochemical Cleavage of Benzylic Single and Double Carbon-Carbon Bonds....Pages 29-32
Some Observations on Intermediates of c-Hexene Bifunctionalization....Pages 33-36
Formation and Reactivity of Radical Cations of Cyclopropane Derivatives....Pages 37-38
Epoxidation of 1,4-Naphthoquinones by Electrochemically Generated Hypohalogen Acids....Pages 39-40
Experimental and Theoretical Studies on Preparation of Hydroquinone from Benzene in a Paired Packed-Bed Electrode Reactor....Pages 41-44
Useful Electro-Oxidative Conversions of Aromatic Compounds....Pages 45-48
The Electrochemical Trifluoromethylation and Perfluoroalkoxylation of Aromatic Compounds....Pages 49-50
Anodic Electrochemistry: Recent Advances in the Total Synthesis of Complex Organic Molecules....Pages 51-54
Electrogenerated N,O -Acetals in Cyclization and Cycloaddition Reactions....Pages 55-60
Anodic Oxydation of Heterocycles: Alkaloids Synthesis....Pages 61-64
Iminoquinones as Electrogenerated Electrophilic Species....Pages 65-68
The Mechanism of the C-S Bond Cleavage in Electron Transfer Reactions of α-Organothio-Substituted Heteroatom Compounds....Pages 69-70
Modification of Cephalosporins Bearing Substituents at C(3’)Position via Electrogenerated Radical-Cation of Sulfide....Pages 71-72
Front Matter....Pages 1-1
Electrolytic C-S Cleavages Giving Rise to Ketones and Carboxylic Acids....Pages 73-76
Ring Opening Reaction of Phenylthio-Cyclopropanes by Anodic or Photochemical One-Electron Oxidation....Pages 77-78
Addition of Electrochemically Generated Chalcogenolate Anions and/or Radicals on the Activated Double Bond....Pages 79-80
Anodic Oxidation of Bis(2,6-Dimethoxyphenyl)Chalcogenides....Pages 81-82
Redox Properties of Hydroxyphenyl Nitronyl Nitroxide....Pages 83-86
Synthesis of Terminal-Biradical Compounds Consisting of Two N -Oxyl Groups Connected with Conjugated π-Systems....Pages 87-88
Interfacial Redox Behavior of Mono- and Multilayers of Tetrathiafulvalene Terminated Alkane-Tetrathiol on Gold Electrode....Pages 89-90
Electrochemical Reactions of Phosphorous Acid Esters....Pages 91-94
Reactions of Electrochemically Generated Alkoxy Phosphonium Ions....Pages 95-98
A New Concept and Technology in Electrooxidative Carbon-Carbon Bond Formation....Pages 99-102
Anodic Oxidation of Cyclic Organic Polysilanes....Pages 103-108
Synthesis, Chemistry, and Anodic Oxidation of 1,2- Bis (Trialkylsilyl)Ethanes....Pages 109-112
Synthesis of Optically Active 1,3-Dienes from Alkenylstannanes by a Combination of Electro-Oxidation and Copper-Mediated Homocoupling Reaction....Pages 113-114
Selective Anodic Fluorination of Heterocycles. Potential Application towards Pharmaceuticals....Pages 115-118
Electrochemical Partial Fluorination of α, β -Unsaturated Esters....Pages 119-122
Electro-Oxidation of Enamines Using Iodide Ion as a Mediator....Pages 123-126
A Convenient Electrochemical O -Glycosylation of Thioglycoside Using Catalytic Br....Pages 127-128
Indirect Anodic Fluorodesulfurization Using Triarylamine Mediators....Pages 129-130
Electrooxidation of Cyclohexanol to Cyclohexanone in the Presence of a Mediatory System....Pages 131-134
Electrochemical Oxidation of Diols Mediated by Organotin Compounds....Pages 135-136
Front Matter....Pages 1-1
Photoinduced Electrochemical Oxidation of Alcohols Utilizing Flavin Analog Mediators in Organic Electrolytes....Pages 137-138
Application of Transition Metal Substituted α-Keggin Silicon Polyoxotungstates as Oxidation Electrocatalyst....Pages 139-142
New Conducting Polypyrroles Fused with Aromatic Rings....Pages 143-146
Electrochemical Cyclooligomerization of 1,4-Bis(1,4-Dithiafulven-6-yl)Benzene and Analogues....Pages 147-150
Rectifying and Photovoltaic Effects of Organic Hetero-Junction Films Based on Fluorenone Derivatives/Poly (3-Methylthiophene) Prepared by Electrochemical Polymerization and Undoping....Pages 151-152
Electrochemical Synthesis and Properties of Poly (3-Methylthiophene) Doped with Pentachlorostannate Anion....Pages 153-154
A New Method for Chemical Modification of Conducting Polypyrroles....Pages 155-156
Modification of Glassy Carbon Surfaces by Anodic Oxidation in 1-Alkanols....Pages 157-160
Modified Graphite Felt Electrode. Application to Electrocatalysis....Pages 161-164
Anodic Oxidation of Organics on Oxide Anodes....Pages 165-168
Electrocatalyric Oxidation on an ( S )-Enantioselective Chiral Tempo-Modified Electrode....Pages 169-172
Enantioselective, Electrocatalytic Oxidation of 1-Phenylethylamine on a Chiral Tempo-Modified Electrode....Pages 173-174
Modification of Thiols onto Single Crystal Surfaces of Gold Electrodes for Metalloportein Electrochemistry....Pages 175-176
Diels-Alder Reaction of in Situ Generated Quinones on a Lithium Perchlorate/Polyethyleneglycol Modified Electrode....Pages 177-178
Electrochemical Oxidation of Biological Amines on the Electrodes Modified with Hydrophobic Monolayers....Pages 179-180
Study on Anodic Oxidation of Esters on Transition Metal Oxide Electrodes....Pages 181-182
Unusual Rearrangement by Anodic Oxidation of Cycloalkanones in the Presence of Trifluoroacetic Acid....Pages 183-186
Conversion of Biomass Derived Products by Anodic Activation....Pages 187-190
Front Matter....Pages 191-191
Electrochemical Activation of Carbon Dioxide. Synthesis of Organic Carbonates and Carbamates....Pages 193-196
Electrocatalytic Reduction of CO 2 on the Dual-Film Electrodes Modified with Various Metal Complexes....Pages 197-200
Front Matter....Pages 191-191
Control of Product Distribution by Use of Surfactants in Cathodic Reduction of Acetophenone....Pages 201-204
Electroorganic Synthesis of Optically Active Alcohols from Ketone and Aldehyde Derivatives Using Alcohol Dehydrogenase as an Electrocatalyst....Pages 205-208
Electrochemistry of Diphenylcyclopropenone in Aprotic Solvents: Electrochemical Synthesis of Oligomers and Electrochemically Driven Decarbonylation Reaction....Pages 209-210
Remarkable Effect of Supporting Electrolyte on the Electroreductive Cyclization of Cyclic Enones....Pages 211-212
Influence of Electrogenerated Bases on the Electroreduction of Some Carbonyl Derivatives....Pages 213-216
Electroreductive Intermolecular Coupling of Unsaturated Compounds....Pages 217-220
Electroreductive Cyclization Reactions. Studies Directed Toward the Phorbol Esters and Bioactive Diterpenes....Pages 221-224
Selective Electroorganic Reductions in Undivided Cells....Pages 225-228
Enantioselective Cathodic Hydrogenation of Prostereogenic Activated Double Bonds....Pages 229-232
Electroreduction of Organic Compounds with Two Reactive Centers. II. Isophthal Aldehyde....Pages 233-233
Synthetic Application of Homogeneous Charge Transfer Catalysis in the Electrocarboxylation of Benzyl Halides....Pages 235-238
Synthesis of α,β-Unsaturated Carboxylic Acids by Electrochemical Carboxylation of Vinyl Bromides and Its Application to the Synthesis of Anti-Inflammatory Agents....Pages 239-242
New and Convenient Synthesis of 3-Methylene-4-Pentenoic Acid by Electrochemical Carboxylation....Pages 243-244
Electrochemical Carboxylation of Several Organic Halides in Supercritical Carbon Dioxide....Pages 245-246
Synthesis of β-Keto Acids by Electrochemical Carboxylation of Vinyl Triflates....Pages 247-248
Use of Sacrificial Anodes in the Transformation of Organic Halides, Residuals from Industry....Pages 249-250
Electroreductive Carbon-Halogen Bond Fission of Alkyl Halides. Michael-Type Addition of Radicals Generated by One-Electron Reduction....Pages 251-252
Ultrasonic Effects on Electrocatalytic Processes....Pages 253-254
Electrochemical Darzens Synthesis....Pages 255-258
Electro-Organic Reactions. Part 48: Pathways for Carbon-Carbon Bond Formation: The Redox Chemistry of Quinodimethanes and of Alkenyl-Substituted Heteroaromatics....Pages 259-266
Front Matter....Pages 191-191
Intramolecular Radical Cyclization Reactions — Scope and Limitations for Electrochemical Processes....Pages 267-270
Electrosynthesis of Heterocyclic Compounds and Other Alternative Electrosynthetic Processes....Pages 271-274
Reactivity of Superoxide Ion with Organohalogens and Chalcones....Pages 275-277
Some Electrochemical Transformation of Polyhalomethanes....Pages 279-282
Investigation of the Coupling Reaction between Aromatic Radical Anions and Alkyl Radicals....Pages 283-286
Electrochemical Generation of Fluorinated Active Species — A New Approach to the Synthesis of Organofluorine Compounds....Pages 287-292
Electroreduction of Dihaloperfluoroalkanes and Perfluoroalkylhalides in Near-Critical and Supercritical CO2 -Methanol Medium....Pages 293-294
Electroreductive Defluorination of Trifluoromethyl Imines....Pages 295-296
Cathodic Cleavage of 1-Trifluoromethyl 1-Alkenyl Sulfone and Sulfoxide....Pages 297-298
Electrochemical Route to Fluorinated Kethoesters....Pages 299-300
Electrochemical Syntheses of Organofluorine Compounds....Pages 301-304
Electrochemical Introduction of Fluorinated Substituents into Organic Molecules....Pages 305-308
Investigation of the Mechanisms of Electrogeneration of Anions....Pages 309-312
Electrochemical Formation of Favorskii Rearrangement Type Intermediates and Their Reactivities....Pages 313-316
Studies of Cathodically-Promoted Addition Reactions of Nitromethane with Various Aldehydes....Pages 317-320
New Electroorganic Results in the Reduction of New Phenacyl Azide Derivatives....Pages 321-324
Chemical and Electrochemical Reductive Cyclizations of O -Nitroarenes Toward Nitrogen Containing Heterocycles....Pages 325-328
The Synthesis of Substituted Aminoindoles by Chemical and Electrochemical Reduction of Nitroindoles....Pages 329-332
Technological Aspects of Electrosynthesis of N, N — Dimethyl — p Phenylendiamine....Pages 333-336
Electroreduction of Organic Compounds with Two Reactive Centers. I. 1,2,4-Triazines....Pages 337-338
Front Matter....Pages 191-191
Single Electron-Transfer Reactions of Arylimines....Pages 339-340
Alkyl Transfer Reactions of Trialkylborane to the Carbonyl Groups by Electrochemical Method....Pages 341-342
Hydroboration of Alkenes or Alkynes by Electrolysis of Sodium Borohydride....Pages 343-344
Back-Biting Reactions of σ-Conjugated Polymers in Electrochemical Systems....Pages 345-346
Formation of Sn-Sn Bond and Synthesis of Polystannane by Electrolysis....Pages 347-348
A Consideration on Mechanism of Tin-Mediated Eleciro-Allylation of Carbonyl Compounds....Pages 349-350
Asymmetric Carbon-Carbon and Carbon-Silicon Bond Formation of Activated Olefins Promoted by Mg-Metal and Electroreduction....Pages 351-354
Recent Progress in the Electrochemical Synthesis of Polysilanes....Pages 355-358
The Electrochemistry of Biologically Active 2-Hydroxy Naphthoquinones: The Role of Hydrogen Bonding. Reductive Silylation and Acetylation, Useful Electrochemical Transformations....Pages 359-362
Electrochemistry of Organosilicon Compounds: From Halosilanes to Ethynylsilanes, Siloles, and Organosilicon Polymers....Pages 363-366
The Generation of Hydroxymethyl Radicals: Photoinduced Electron Transfer as Opposed to Electrochemical Electron Transfer....Pages 367-369
Electroreductive Synthesis of Sequence-Ordered Polysilanes Using Mg Electrodes....Pages 371-372
Catalytic Reduction of Halogenated Organic Compounds with Electrogenerated Metal(I) Salen Complexes....Pages 373-376
Palladium-Catalyzed Carboxylation of Vinyl Triflates. Electrosynthesis of α,β-Unsaturated Carboxylic Acids....Pages 377-378
Investigation of the Mechanism of Palladium-Catalyzed Reactions by Electrochemistry....Pages 379-382
Electrochemical Reduction of Some [(η 5 -Cyclopentadienyl) (η 6 -Arene) Iron(II)][PF 6 ] Complexes Bearing an Imine or a Nitrone Function in Benzylic Position of the Arene Ligand....Pages 383-386
Stereoselectivity in the Electroreductive Syntheses with Aryl and Alkenyl Halides Catalyzed by Nickel Complexes....Pages 387-390
Nickel-catalyzed Electrochemical Reductive Cleavage of the Oxygen-Carbon Bond of Allyl Ethers: Synthetic Applications....Pages 391-394
Exploring Co-Mediated Organic Reactions. Modelling Molecular Recognition in Vitamin B 12 Dependent Reactions....Pages 395-398
Electrochemical 1,2-Migration Reactions Mediated by Vitamin B 12 Derivatives....Pages 399-402
Front Matter....Pages 191-191
Catalytic Activity of Vitamin B 12 Derivative Having Amino Acid Residues....Pages 403-404
Electron Transfer Reactions of Semi-Artificial Biomolecules....Pages 405-408
Ultramicroelectrodes: Their Use in Semi-Artificial Synapses....Pages 409-412
Polypeptides Endowed with Artificial Redox Functions....Pages 413-416
Some Aspects of Development in Direct Cathodic Deprotonation....Pages 417-420
Electrochemical Reactions of Organic Materials on Diamond Electrodes....Pages 421-424
Catalysis of Metal Ions on Electron Transfer Reactions....Pages 425-430
Synthetic use of Electroinduced Hydrogen Abstraction....Pages 431-434
π-π Charge-Transfer Interaction of the Tetracyanoethylene π-Dianion Generated at Sequential Electroreduction Steps....Pages 435-436
Physical-Energetical Reaction Control in Electroorganic Processes....Pages 437-439
Method of Producing Choline of a High Purity....Pages 441-444
The Study of Nickel Hydroxide Catalyst Surface During Organic Electrosynthesis by Atomic Force Microscopy....Pages 445-446
Sandwich Electrodes and Their Possible Application in Organic Electrosynthesis Studied by Atomic Force Microscopy....Pages 447-448
Microstructural Analysis of Carbon Fiber for Lithium Rechargeable Battery....Pages 449-450
Application of Sydnones to Lithium Battery Electrolytes....Pages 451-452
Interfacial Reaction and Charge/Discharge Properties of LiMn 2 O 4 with Organic Eletrolyte....Pages 453-454
Stereochemistry and Electrochemistry, Synthetic and Analytical Implications in the Synthesis of Molecules of Defined Handedness....Pages 455-456
Reversible Electron Transfer in Electroorganic Chemistry....Pages 457-458
Back Matter....Pages 459-461