Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications

Front Matter....Pages i-xx
The Alkene Metathesis Ruthenium Catalyst Saga....Pages 1-21
Ruthenium Carbenes as Catalysts for Alkene Metathesis....Pages 23-42
Metathetical Conversion and Silylative Coupling of Alkadienes and Cycloalkenes with Mono- and Divinylsilicon Compounds....Pages 43-49
Synthesis of Organosilicon Reagents of Vinylsilicon Functionality via Cross-Metathesis and Silylation of Alkenes....Pages 51-64
Catalytic Properties and Chemical Transformations of CIS -W(CO) 4 (C 5 H 5 N) 2 Initiator in Ring Opening Metathesis Polymerization....Pages 65-71
The Impact of Well-Defined Transition Metal Initiators on ROMP....Pages 73-85
Dual Activity of Ruthenium Catalysts in Controlled Radical Reactions and Olefin Metathesis....Pages 87-100
O,N- Bidentate Ligands Co-Ordinated on Ru-Based Olefin Metathesis Catalysts....Pages 101-119
Catalytic Activity of W-Sn and Mo-Sn Bimetallic Compounds in Metathesis and Related Reactions....Pages 121-129
Polymerizations Catalyzed with Rhodium Complexes....Pages 131-154
Mesoporous Molecular Sieves Immobilized Catalysts for Polymerization of Phenylacetylene and Its Derivatives....Pages 155-165
Study of the Stability and Activity of Electrochemically Produced Tungsten-Based Metathesis Catalyst with Symmetrical Alkenes....Pages 167-171
Immobilized Tungsten-Containing Catalysts for the Metathesis of Linear and Functionalized Olefins....Pages 173-177
The Incorporation of Amino Acids into Polymers ADMET....Pages 179-189
Graft Copolymers Attained by ATRP and ADMET....Pages 191-202
Synthesis, Conformation, and Functions of Helical Poly( N -Propargylamides):....Pages 203-213
Synthesis of Block Copolymers and Star Polymers through Living Polymerization of Substituted Acetylenes....Pages 215-227
Well-Defined Linear and Crosslinked Materials via ROMP and RTM Processing....Pages 229-235
Ring Opening Metathesis Polymerisation (ROMP) of Cyclooctene and Substituted Norbornene Derivatives Using a Ruthenium Catalyst Containing a Triazol-5-Ylidene Ligand....Pages 237-242
Acyclic Diene Metathesis (ADMET) Polymerization by Electrochemically Generated Tungsten-Based Active Catalyst System: Optimization of Reaction Conditions....Pages 243-247
Probing the Tacticity of Ring-Opened Metathesis Polymers of Norbornene and Norbornadiene Diesters by NMR Spectroscopy....Pages 249-261
Metathesis and Polyolefin Growth on Cadmium Selenide Surfaces Using Ruthenium-Based Catalysts....Pages 263-270
Acyclic Diene Metathesis Condensation (ADMET) of 1,2-Divinylferrocene (DVFC)....Pages 271-276
Acyclic Diyne Metathesis Condensation of 3-ALKYL-2,5-DI (1-Propynyl)-Thiophenes....Pages 277-284
Ring Closing Versus Cyclic Isomerization of 1,6-Dienes by Ruthenium Allenylidene Complexes....Pages 285-293
Application of Uniform Macroporous Polystyrene Particles as Support in W(CO) 6 /CC14/hv Photocatalytic Olefin Metathesis System....Pages 295-301
Reactions of Atomic Carbon with 2-Norbornene....Pages 303-308
Intramolecular Trapping of Strained Bicyclic Allene in Carbon Atom Reactions....Pages 309-312
Industrial Applications of Olefin Metathesis....Pages 313-322
Synthesis of Cyclobutane Hydrocarbons By Combination of (2+2) π -Cycloaddition and Olefin Metathesis. Their Abilities as Effective Propellants....Pages 323-340
Directional Synthesis of Membrane Materials by ROMP of Silyl-Substituted Norbornadienes and Norbornenes....Pages 341-349
Back Matter....Pages 351-354