Natural Gas Conversion VI

Content: 
Preface
Page v
Enrique Iglesia, James J. Spivey, Theo H. Fleish

Program Committee
Page vi

Organizing Committee
Page vii

International Advisory Board
Page vii

Sponsors
Page viii

Modeling millisecond reactors Original Research Article
Pages 1-12
Lanny D. Schmidt

Molecular design of highly active methanol synthesis catalysts Original Research Article
Pages 13-19
Alexis T. Bell

Partial oxidation of methane to syngas over NiO/γ-Al2O3 catalysts prepared by the sol-gel method Original Research Article
Pages 21-26
Yuhong Zhang, Guoxing Xiong, Weishen Yang, Shishan Sheng

Mo/MCM-22: a selective catalyst for the formation of benzene by methane dehydro-aromatization Original Research Article
Pages 27-32
Y.-Y. Shu, D. Ma, L.-L. Su, L.-Y. Xu, Y.-D. Xu, X.-H. Bao

The synthesis of dimethyl ether from syngas obtained by catalytic partial oxidation of methane and air Original Research Article
Pages 33-38
XU Hengyong, GE Qingjie, LI Wenzhao, HOU Shoufu, YU Chunying, JIA Meilin

Development of the high pressure ITM syngas process Original Research Article
Pages 39-44
M.F. Carolan, P.N. Dyer, E. Minford, T.F. Barton, D.R. Peterson, A.F. Sammells, D.L. Butt, R.A. Cutler, D.M. Taylor

An integrated ITM syngas/Fischer-Tropsch process for GTL conversion Original Research Article
Pages 45-50
C.M. Chen, P.N. Dyer, K.F. Gerdes, C.M. Lowe, S.R. Akhave, D.R. Rowley, K.I. sen, E.H. Eriksen

LiLaNiO/γ-Al2O3 catalyst for syngas obtainment by simultaneous catalytic reaction of alkanes with carbon dioxide and oxygen Original Research Article
Pages 51-56
Shenglin Liu, Longya Xu, Sujuan Xie, Qingxia Wang, Guoxing Xiong

Impact of syngas generation technology selection on a GTL FPSO Original Research Article
Pages 57-62
Cliff Lowe, Karl Gerdes

Developments in Fischer-Tropsch technology and its application Original Research Article
Pages 63-68
B. Jager, P. Van Berge, A.P. Steynberg

An innovative approach for ethylene production from natural gas Original Research Article
Pages 69-74
Zhu Aimin, Tian Zhijian, Xu Zhusheng, Xu Yunpeng, Xu Longya, Lin Liwu

Methane conversion via microwave plasma initiated by a metal initiator Original Research Article
Pages 75-80
Xu Yunpeng, Tian Zhijian, Xu Zhusheng, Zhu Aimin, Lin Liwu

Production of ethylbenzene by alkylation of benzene with dilute ethylene obtained from ethane oxidative dehydrogenation with CO2 Original Research Article
Pages 81-86
S-J Xie, L-Y Xu, Q-X Wang, J Bai, Y-D Xu

Oxidative dehydrogenation of ethane with carbon dioxide to ethylene over Cr-loaded active carbon catalyst Original Research Article
Pages 87-92
Yang Hong, Lin Liwu, Wang Qingxia, Xu Longya, Xie Sujuan, Liu Shenglin

Catalytic performance of hydrothermally synthesized Mo-V-M-O (M=Sb and Te) oxides in the selective oxidation of light paraffins Original Research Article
Pages 93-98
Kenzo Oshihara, Tokio Hisano, Youhei Kayashima, Wataru Ueda

A novel two-stage reactor process for catalytic oxidation of methane to synthesis gas Original Research Article
Pages 99-104
Shikong Shen, Zhiyong Pan, Chaoyang Dong, Qiying Jiang, Zhaobin Zhang, Changchun Yu

Composite steam reforming catalysts prepared from Al2O3/Al matrix precursor Original Research Article
Pages 105-110
S.F. Tikhov, V.A. Sadykov, I.I. Bobrova, Yu.V. Potapova, V.B. Fenelonov, S.V. Tsybulya, S.N. Pavlova, A.S. Ivanova, V.Yu. Kruglyakov, N.N. Bobrov

Relation between the structure and activity of Ru-Co/NaY catalysts studied by X-ray absorption spectroscopy (XAS) and co hydrogenation Original Research Article
Pages 111-116
L. Guczi, D. Bazin, I. Kovács, L. Borkó, I. Kiricsi

Development of a high efficiency GTL process based on CO2/steam reforming of natural gas and slurry phase FT synthesis Original Research Article
Pages 117-122
T. Wakatsuki, Y. Morita, H. Okado, K. Inaba, H. Hirayama, M. Shimura, K. Kawazuishi, O. Iwamoto, T. Suzuki

Kinetic modeling of the slurry phase Fischer-Tropsch synthesis on iron catalysts Original Research Article
Pages 123-128
Lech Nowicki, Dragomir B. Bukur

Mechanism of carbon deposit/removal in methane dry reforming on supported metal catalysts Original Research Article
Pages 129-134
K. Nagaoka, K. Seshan, J.A. Lercher, K. Aika

New catalysts based on rutile-type Cr/Sb and Cr/V/Sb mixed oxides for the ammoxidation of propane to acrylonitrile Original Research Article
Pages 135-140
N. Ballarini, R. Catani, F. Cavani, U. Cornaro, D. Ghisletti, R. Millini, B. Stocchi, F. Trifirò

ALMAX catalyst for the selective oxidation of n-butane to maleic anhydride: a highly efficient V/P/O system for fluidized-bed reactors Original Research Article
Pages 141-146
S. Albonetti, F. Budi, F. Cavani, S. Ligi, G. Mazzoni, F. Pierelli, F. Trifirò

Oxygen transport membranes for syngas production Original Research Article
Pages 147-152
T.J. Mazanec, R. Prasad, R. Odegard, C. Steyn, E.T. Robinson

Deactivation of CrOx/Al2O3 catalysts in the dehydrogenation of i-butane Original Research Article
Pages 153-158
S.M.K. Airaksinen, J.M. Kanervo, A.O.I. Krause

Selectivity of fishcer-tropsch synthesis: Spatial constraints and forbidden reactions Original Research Article
Pages 159-164
Hans Schulz, Zhiqin Nie

Effect of CaO promotion on the performance of a precipitated iron Fischer-Tropsch catalyst Original Research Article
Pages 165-170
Dragomir B. Bukur, Xiaosu Lang, Lech Nowicki

Partial oxidation of methane at high temperatures over platinum and rhodium monolith catalysts Original Research Article
Pages 171-176
F. Monnet, Y. Schuurman, F.J. Cadete Santos Aires, C. Mirodatos

The promoting effect of ru and re addition to Co/Nb2O5 catalyst in the Fischer-Tropsch Synthesis Original Research Article
Pages 177-183
F. Mendes, F.B. Noronha, R.R. Soares, C.A.C. Perez, G. Marcheti, M. Schmal

Comparative studies of the oxidative dehydrogenation of propane in micro-channels reactor module and fixed-bed reactor Original Research Article
Pages 185-190
N. Steinfeldt, O.V. Buyevskaya, D. Wolf, M. Baerns

Catalyst-assisted oxidative dehydrogenation of light paraffins in short contact time reactors Original Research Article
Pages 191-196
Alessandra Beretta, Pio Forzatti

Catalytic decomposition of methane: Towards production of CO-free hydrogen for fuel cells Original Research Article
Pages 197-202
T.V. Choudhary, C. Sivadinarayana, A. Klinghoffer, D.W. Goodman

CO2−CH4 reforming with Pt-Re/γ-Al2O3 catalysts Original Research Article
Pages 203-208
James T Richardson, Jain-Kai Hung, Jason Zhao

The catalytic properties of alkaline earth metal oxides in the selective oxidation of CH4-O2-NOx (x=1,2) Original Research Article
Pages 209-214
T. Takemoto, K. Tabata, Y. Teng, E. Suzuki, Y. Yamaguchi

Production and storage of hydrogen from methane mediated by metal oxides Original Research Article
Pages 215-220
K. Otsuka, A. Mito, S. Takenaka, I. Yamanaka

Oxidative dehydrogenation over Sol-Gel Mo/Si:Ti catalysts: Effect of Mo loading Original Research Article
Pages 221-226
Rick B. Watson, Umit S. Ozkan

NOx-Catalyzed partial oxidation of methane and ethane to formaldehyde by dioxygen Original Research Article
Pages 227-232
Ayusman Sen, Minren Lin

Comparative study of partial oxidation of methane to synthesis gas over supported Rh and Ru catalysts using in situ time-resolved FTIR and in situ microprobe Raman spectroscopies Original Research Article
Pages 233-238
Wei Zheng Weng, Qian Gu Yan, Chun Rong Lou, Yuan Yan Liao, Ming Shu Chen, Hui Lin Wan

Optimisation of Fischer-Tropsch reactor design and operation in GTL plants Original Research Article
Pages 239-244
Dag Schanke, Petter Lian, Sigrid Eri, Erling Rytter, Bente Helgeland Sann˦s, Keijo J. Kinnari

Catalytic partial oxidation of methane to syngas: staged and stratified reactors with steam addition Original Research Article
Pages 245-250
E.J. Klein, S. Tummala, L.D. Schmidt

Natural gas conversion in monolithic catalysts: Interaction of chemical reactions and transport phenomena Original Research Article
Pages 251-258
Olaf Deutschmann, Renate Schwiedernoch, Luba I. Maier, Daniel Chatterjee

Direct synthesis of acetic acid from methane and carbon dioxide Original Research Article
Pages 259-264
E.M. Wilcox, M.R. Gogate, J.J. Spivey, G.W. Roberts

Partial oxidation of methane to form synthesis gas in a tubular AC plasma reactor Original Research Article
Pages 265-270
T.A. Caldwell, H. Le, L.L. Lobban, R.G. Mallinson

Selective hydrogenation of acetylene to ethylene during the conversion of methane in a catalytic dc plasma reactor Original Research Article
Pages 271-276
C.L. Gordon, L.L. Lobban, R.G. Mallinson

The Nigerian gas-to-liquids (GTL) plant Original Research Article
Pages 277-282
R.J. Motal, S. Shadiya, R.C. Burleson, Dr.E. Cameron

Pt-Promotion of Co/SiO2 Fischer-Tropsch synthesis catalysts Original Research Article
Pages 283-288
George W. Huber, Calvin H. Bartholomew

Catalytic dehydrogenation of propane over a PtSn/SiO2 catalyst with oxygen addition: Selective oxidation of H2 in the presence of hydrocarbons Original Research Article
Pages 289-294
L. Lte, J.-I. Rundereim, E.A. Blekkan

Selectivity and activity changes upon water addition during Fischer-Tropsch synthesis Original Research Article
Pages 295-300
Anne-Mette Hilmen, Odd Asbjørn Lindvg, Edvard Bergene, Dag Schanke, Sigrid Eri, Anders Holmen

Synthesis gas production by partial oxidation of methane from the cyclic gas-solid reaction using promoted cerium oxide Original Research Article
Pages 301-306
J.C. Jalibert, M. Fathi, O.A. Rokstad, A. Holmen

Hydroconvesion of a mixture of long chain n-paraffins to middle distillate: effect of the operating parameters and products properties Original Research Article
Pages 307-312
V. Calemma, S. Peratello, S. Pavoni, G. Clerici, C. Perego

Ethylene production via partial oxidation and pyrolysis of ethane Original Research Article
Pages 313-318
M. Dente, A. Beretta, T. Faravelli, E. Ranzi, A. Abb`, M. Notarbartolo

The role of gallium oxide in methane partial oxidation catalysts: An experimental and theoretical study Original Research Article
Pages 319-324
Christopher A. Cooper, Charles R. Hammond, Graham J. Hutchings, Stuart H. Taylor, David J. Willock, Kenji Tabata

Low temperature routes for methane conversion, and an approach based on organoplatinum chemistry Original Research Article
Pages 325-332
Jay A. Labinger

NAS (novel aluminosilicates) as catalysts for the selective conversion of propane to fuels and chemicals-effects of crystallinity on catalytic behaviour Original Research Article
Pages 333-338
CP Nicolaides, NP Sincadu, MS Scurrell

The oxidative dehydrogenation of propane with CO2 over supported Mo2C catalyst Original Research Article
Pages 339-344
F. Solymosi, R. Németh, A. Oszkó

Decomposition/reformation processes and CH4 combustion activity of PdO over Al2O3 supported catalysts for gas turbine applications Original Research Article
Pages 345-350
G. Groppi, G. Artioli, C. Cristiani, L. Lietti, P. Forzatti

Effect of periodic pulsed operation on product selectivity in Fischer-Tropsch synthesis on Co-ZrO2/SiO2 Original Research Article
Pages 351-356
A.A. Nikolopoulos, S.K. Gangwal, J.J. Spivey

Synthesis and characterization of proton-conducting oxides as hydrogen transport membranes Original Research Article
Pages 357-362
Lin Li, Enrique Iglesia

Methane to syngas: Development of non-coking catalyst and hydrogen-permselective membrane Original Research Article
Pages 363-368
J. Galuszka, D. Liu

Site reactivity of Fischer-Tropsch synthesis catalysts studied by 12CO→13CO isotope transients Original Research Article
Pages 369-374
C.J. Bertole, C.A. Mims, G. Kiss, P. Joshi

Surface carbon coverage and selectivity in FT synthesis: a simple model for selectivity correlations Original Research Article
Pages 375-380
C.A. Mims, C.J. Bertole

Perovskites as catalysts precursors for methane reforming: Ru based catalysts Original Research Article
Pages 381-386
E. Pietri, A. Barrios, O. Gonzalez, M.R. Goldwasser, M.J. Pérez-Zurita, M.L. Cubeiro, J. Goldwasser, L. Leclercq, G. Leclercq, L. Gingembre

Fischer-Tropsch synthesis catalysts based on Fe oxide precursors modified by Cu and K: structure and site requirements Original Research Article
Pages 387-392
Senzi Li, George D. Meitzner, Enrique Iglesia

Catalytic dehydrocondensation of methane towards benzene and naphthalene on zeolite-supported Re and Mo-Templating roles of micropores and novel mechanism Original Research Article
Pages 393-398
Ryuichiro Ohnishi, Longya Xu, Kohtaro Issoh, Masaru Ichikawa

Lurgi's Mega-Methanol technology opens the door for a new era in down-stream applications Original Research Article
Pages 399-404
Jürgen Haid, Ulrich Koss

Selecting optimum syngas technology and process design for large scale conversion of natural gas into Fisher-Tropsch products (GTL) and Methanol Original Research Article
Pages 405-410
Roger Hansen, Jostein Sogge, Margrete Hnes Wesenberg, Ola Olsvik

CANMET's integrated acetic acid process: Coproduction of chemicals and power from natural gas Original Research Article
Pages 411-416
Andrew McFarlan, Dirkson Liu

Rhenium as a prometer of titania-supported cobalt Fischer-Tropsch catalysts Original Research Article
Pages 417-422
Charles H. Mauldin, Douglas E. Varnado

Market led GTL: The oxygenate strategy Original Research Article
Pages 423-428
T.H. Fleisch, R. Puri, R.A. Sills, A. Basu, M. Gradassi, G.R. Jones Jr.

Gas-to-liquids R&D: Setting cost reduction targets Original Research Article
Pages 429-434
Michael J. Gradassi

Syngas for large scale conversion of natural gas to liquid fuels Original Research Article
Pages 435-440
Ib Dybkj˦r, Thomas S. Christensen

CO2 reforming for large scale methanol plants—an actual case Original Research Article
Pages 441-446
H. Holm-Larsen

Water-gas shift reaction: reduction kinetics and mechanism of Cu/ZnO/Al2O3 catalysts Original Research Article
Pages 447-452
M.J.L. Ginés, C.R. Apesteguía

Design/economics of an associated (or sub-quality) gas Fischer-Tropsch plant Original Research Article
Pages 453-458
Gerald N. Choi, Anne Helgeson, Anthony Lee, Sam Tam, Venkat Venkataraman, Shelby Rogers

Expanding markets for GTL fuels and specialty products Original Research Article
Pages 459-464
Paul F. Schubert, Charles A. Bayens, Larry Weick, Michael O. Haid

Development of dense ceramic membranes for hydrogen separation Original Research Article
Pages 465-470
U. (Balu) Balachandran, T.H. Lee, G. Zhang, S.E. Dorris, K.S. Rothenberger, B.H. Howard, B. Morreale, A.V. Cugini, R.V. Siriwardane, J.A. Poston Jr., E.P. Fisher

Methane oxyreforming over the Al2O3 supported rhodium catalyst as a promising route of CO and H2 mixture synthesis Original Research Article
Pages 471-476
B. Pietruszka, M. Najbar, L. Lityńska-Dobrzyńska, E. Bielańska, M. Zimowska, J. Camra

Catalytic partial oxidation of ethane to acetic acid over Mo1V0.25Nb0.12Pd0.0005Ox—Catalyst performance, reaction mechanism, kinetics and reactor operation Original Research Article
Pages 477-482
David Linke, Dorit Wolf, Manfred Baerns, Uwe Dingerdissen, Sabize Zeyß

A non stationary process for H2 production from natural gas Original Research Article
Pages 483-488
C. Marquez-Alvarez, E. Odier, L. Pinaeva, Y. Schuurman, C. Millet, C. Mirodatos

From natural gas to oxygenates for cleaner diesel fuels Original Research Article
Pages 489-494
M. Marchionna, R. Patrini, D. Sanfilippo, A. Paggini, F. Giavazzi, L. Pellegrini

Some critical issues in the analysis of partial oxidation reactions in monolith reactors Original Research Article
Pages 495-500
Sebastián C. Reyes, John H. Sinfelt, Ioannis P. Androulakis, Marylin C. Huff

Indirect internal steam reforming of methane in solid oxide fuel cells Original Research Article
Pages 501-506
P. Aguiar, E. Ramírez-Cabrera, N. Lapeña-Rey, A. Atkinson, L.S. Kershenbaum, D. Chadwick

Catalytic properties of supported MoO3 catalysts for oxidative dehydrogenation of propane Original Research Article
Pages 507-512
Kaidong Chen, Enrique Iglesia, Alexis T. Bell

Quantitative comparison of supported cobalt and iron fischer tropsch synthesis catalysts Original Research Article
Pages 513-518
Roberto Zennaro, Gianni Pederzani, Sonia Morselli, Shiyong Cheng, Calvin H. Bartholomew

CO2 abatement in gas-to-liquid plants Original Research Article
Pages 519-524
Harry Audus, Gerald Choi, Alasdair Heath, Samuel S. Tam

Study on stability of Co/ZrO2/SiO2 catalyst for F-T synthesis Original Research Article
Pages 525-529
J.-G. Chen, X.-Z. Wang, H.-W. Xiang, Y.-H. Sun

Partial oxidation of methane to formaldehyde on Fe-doped silica catalysts Original Research Article
Pages 531-536
F. Arena, F. Frusteri, J.L.G. Fierro, A. Parmaliana

Production of light olefins from natural gas Original Research Article
Pages 537-542
B.V. Vora, P.R. Pujadó, L.W. Miller, P.T. Barger, H.R. Nilsen, S. Kvisle, T. Fuglerud

Novel techniques for the conversion of methane hydrates Original Research Article
Pages 543-548
Dirk D. Link, Charles E. Taylor, Edward P. Ladner

List of authors
Pages 549-551