Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds

Front Matter....Pages i-xxiv
Front Matter....Pages 1-1
Molecular Electrochemistry of Coordination Compounds -Present State and New Trends....Pages 3-11
Front Matter....Pages 13-13
Direct Electrochemical Synthesis of Inorganic and Organometallic Compounds....Pages 15-31
Electrochemical Generation of Substrate-Binding Sites in Organometallic Complexes with the {Mo 2 (μ-SR) n Core. Electrosynthesis of Cyanide and Isocyanide Derivatives.....Pages 33-38
Front Matter....Pages 39-39
The Parameterisation of Metal Centred Redox Couples....Pages 41-55
Electrochemical Ligand Parameters for Phosphonium-Functionalized Isocyanides and Derived Carbenes and Indoles of Group VI Transition Metal Carbonyls....Pages 57-62
Redox Properties and Ligand Effects for the Hydrido-Technetium-Dinitrogen, -Carbonyl and -Isocyanide Complexes trans -[TcH(L)(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ] (L = N 2 , CO or CNR)....Pages 63-67
Electrochemical Studies of Coordination Complexes of Osmium....Pages 69-75
Molybdenum Macrocycles and Molecular Electronics....Pages 77-88
An Electrochemical Evaluation of Long Range Metal-Metal Interactions Through Hydrocarbon Bridges....Pages 89-93
Electrochemical Properties of Molybdenum Complexes Containing a Bulky Tris(Pyrazolyl)Borate Ligand....Pages 95-99
Redox Properties of Symmetrical and Unsymmetrical Sandwich Complexes of Lutetium(III) with Phthalocyaninato and Naphthalocyaninato Ligands....Pages 101-106
New Polydentate Ligands and Comlexes: Protic and Topographic Effects on Redox Properties....Pages 107-119
Redox-Structural Correlations in Metal Thioether Macrocyclic Complexes: The Stabilisation of Mononuclear Silver(II) and Gold(II)....Pages 121-129
Bioelectrochemistry: Making Use of the Electrochemical Behaviour of Proteins....Pages 133-149
Electrochemical Studies of Synthetic Models of Copper Proteins....Pages 151-170
Cyclic Voltammetric Behaviour of Some Copper Complexes with a BIS(Pyrazole)BIS(Thioether)Ligand....Pages 171-176
Front Matter....Pages 177-177
Correlation Between Structure and Heterogeneous Electron Transfer Rates of Coordination Compounds....Pages 179-191
Some Electronic and Dynamical Factors in Electron-Transfer Chemistry: Metal Complexes, Clusters, and Surfaces....Pages 193-206
Theoretical Study of Electron Transfer Reactions in Porphyrins and Cytochromes....Pages 207-214
Front Matter....Pages 215-215
Supramolecular Electrochemistry: Polynuclear Metal Compounds.....Pages 217-228
Front Matter....Pages 215-215
The Redox Propensity of High Nuclearity Metal Clusters....Pages 229-245
Redox-Active Tetrapalladia Units [Pd 4 ] n+ (n = 0, 1, 2, 3, 4) from Double Oxidative Carbon-Carbon Coupling....Pages 247-251
Front Matter....Pages 253-253
Using Electrochemical Information for Organometallic Coordination Chemistry: Stoichiometric and Catalytic Reactions....Pages 255-268
Oxidatively Induced, Electrocatalytic Ligand Substitution in 17-Electron Manganese Complexes: An Investigation of the Kinetics by Derivative Cyclic Voltammetry....Pages 269-275
Electron-Transfer-Chain Catalysis: Role of Transition-Metal Radicals, Side Reactions and Coupling with Organometallic Catalysis....Pages 277-294
Molecular Catalysis of Electrochemical Reactions by Low Valent Transition Metal Complexes: Metalloporphyrins....Pages 295-306
One Two-Electron vs Two One-Electron Mechanisms in the Catalysis of Electrocarboxylation of Aryl Halides by Nickel and Palladium Complexes....Pages 307-310
Electrochemical Reduction of CO 2 Catalysed by Transition Metal Complexes....Pages 311-316
Organometallic Electrochemistry of Metal Alkyne and Related Complexes....Pages 317-329
Electrochemical Behaviour of Complexes Derived from the Activation of Alkynes, Isocyanides and Nitriles....Pages 331-344
Electrochemical Behaviour of Aminooxy-, Dioxy- and Diaminocarbene Complexes of Palladium(II) and Platinum(II)....Pages 345-350
Electrochemistry of Platinum Phosphine Complexes: C-H and C-X Activation by Highly Reactive Intermediates....Pages 351-356
Azametallic Electrochemistry....Pages 357-380
Electrocatalysis of the Reduction of O 2 Within Polyelectrolyte Coatings on Electrodes....Pages 381-389
Electrochemical Studies on Activation of Dioxygen at Cobalt Macrocycles Derived from Cobaloxime....Pages 391-404
Behaviour of the Ionomer / Metal Interface Towards the Electroreduction of Oxygen....Pages 405-410
Redox Properties of the Amavadine Models [V(HIDA) 2 ] 2 - and [V(HIDPA) 2 ] 2 - and Their Electroinduced Reactivity Towards Activated-Thiols and -Phenols....Pages 411-415
Electrochemical Study of the Oxidation Chemistry of Chromium Carbonyl Thiolates RSCr(CO) 5 - and RSCr 2 (CO) 10 - ....Pages 417-421
New Developments in Voltammetric Behaviour and Electrocatalytic Activity of Ni(II) Tetraazamacrocyclic Complexes....Pages 423-429
Electrooxidation as a Route to Dihydrogen Complexes....Pages 431-434
Front Matter....Pages 435-435
Mechanistic Studies in Organo-Metallic Electrochemistry. The Role of Computer Based Techniques & Simulation....Pages 437-452
Numerical Methods in Synthesis and Analysis of Electrochemical Responses....Pages 453-466
Molecules with Identical Electroactive Centres as a Probe for Dielectric Properties of Electrolytes....Pages 467-475
A Comparative Study of Numerical Methods for Cyclic Voltammetry Digital Simulation of an Electrochemical Process with a Coupled Chemical Reaction....Pages 477-482
Mechanism of the Electroactivation of the Metal-Hydride Bond in [ReCIH(NCR)(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ][BF 4 ]....Pages 483-487
Electrochemistry and Cis/Trans -Isomerization of Cr III/II- Aminocarboxylate Complexes....Pages 489-494
Three Dimensional Electrochemistry: An Alternative Experimental way for the Study of Electrochemical Processes....Pages 495-500
Front Matter....Pages 501-501
Spectroelectrochemical (UV/VIS/Near IR, EPR) Studies of Coordination Complexes....Pages 503-517
One- and Two-Electron Oxidations of Bimetallic Fulvalene Complexes Studied by Voltammetry and IR Spectroelectrochemistry....Pages 519-532
Spectro-Electrochemistry and Electrochemical Spectroscopy....Pages 533-547
Application of “In Situ” Reflectance Spectroscopy to Molecular Electrocatalysis....Pages 549-571
Low Temperature Electrochemistry and Spectroelectrochemistry of Catalytically Important Tungsten(O) Complexes....Pages 573-582
Electrochemistry and Spectroelectrochemistry of Dinuclear Ruthenium and Osmium Complexes....Pages 583-588
The Optical Spectra and Voltammetry of Mixed Halide / Nitrile / Carbonyl Osmium(III) Complexes. Additive and Non-Additive Effects....Pages 589-593
Buckminsterfullerene and Its Electrogenerated Anions C 60 1- . C 60 2- and C 60 3- ....Pages 595-600
Front Matter....Pages 601-601
Practical Aspects of Electrochemistry and Applications Towards the Solving of Chemical Problems....Pages 603-613
Charge Transport Properties of Electrodes Modified with Osmium Containing Polymer Films....Pages 615-621
Front Matter....Pages 623-623
Unconventional Electrochemistry at Ultramicroelectrodes: New Approaches for the Investigation of Chemical Reactivity....Pages 625-644
A Microelectrode Study of Metal Hexacarbonyls in Aprotic Solvents....Pages 645-648
The use of Microelecrodes in Kinetic Studies of Homogeneous Chemical Reactions of Molybdenum Complexes....Pages 649-652
Front Matter....Pages 653-653
Report 1 Round Table Discussion....Pages 655-656
Report 2 General Discussions and Prospects....Pages 657-658
Report 3 General Comments....Pages 659-660
Back Matter....Pages 661-667