Molecular Acoustics

1 Introduction....Pages 1-5
2.1.1 Sound velocity in gases and vapors....Pages 6-12
2.1.2.1.1 Inorganic liquids....Pages 12-14
C - C6....Pages 15-26
C7 - C57, CF....Pages 26-40
2.1.2.1.3 Alterations of sound velocity and density with substitution changes....Pages 40-44
2.1.2.1.4 Relationships between sound velocity and density in structural isomers....Pages 44-47
2.1.2.1.5 Sound velocity and density in silicoorganic compounds....Pages 48-49
2.1.2.1.6 Additive conformities and rules at the interrelations between sound velocity and molecular structure....Pages 49-51
2.1.2.1.7 The jump of the sound velocity at the normal boiling point and melting point....Pages 51-52
2.1.2.1.8 The sound velocity in the range of the critical point....Pages 52-57
2.1.2.1.9 Sound propagation in supercooled liquids....Pages 57-59
2.1.2.1.10 Sound propagation in crystalline liquids....Pages 60-60
2.1.2.2 Sound velocity as a function of pressure....Pages 61-63
2.1.2.3 Sound velocity in some polymeric liquids....Pages 64-65
2.1.2.4 Ultrasonic dispersion in fatty acids....Pages 65-66
2.1.2.5 Various interrelations between sound velocity and other properties of matter....Pages 67-68
2.1.2.6 The sound velocity in water, H2O and D2O....Pages 69-72
2.1.3 References for 2.1....Pages 73-74
2.2.0 Introduction....Pages 74-75
2.2.1.1 Sound velocity in gas mixtures....Pages 76-78
2.2.1.2 Sound velocity in binary liquid systems....Pages 78-78
2.2.1.2.1 Sound characteristics of binary mixtures of organic liquids....Pages 79-92
2.2.1.2.2 Sound characteristics of systems with miscibility gap....Pages 93-94
2.2.1.2.3 Isothermally and adiabatically measured sound characteristics of solutions....Pages 94-99
2.2.1.2.4 Sound characteristics of aqueous mixtures and solutions....Pages 99-108
2.2.1.3 References for 2.2.0 and 2.2.1....Pages 108-109
2.2.2.0 Introduction....Pages 109-109
2.2.2.1 Sound velocity, density, and compressibility as a function of concentration....Pages 110-117
2.2.2.2 Sound velocity as a function of temperature....Pages 118-122
2.2.2.3 Dispersion problems....Pages 122-123
2.2.2.4 Sound velocity alterations at small concentrations of electrolytes....Pages 123-125
2.2.2.5 References for 2.2.2....Pages 125-126
2.2.3 Sound velocity in nonaqueous solutions of electrolytes....Pages 126-126
3.1.0 Introduction and definitions....Pages 127-127
3.1.1 Translation relaxation in monoatomic gases....Pages 128-129
3.1.2 Rotation relaxation in diatomic gases....Pages 129-133
3.1.3 Vibration relaxation in diatomic gases....Pages 134-135
3.1.4 Vibration relaxation in triatomic gases....Pages 136-138
3.1.5 Vibration relaxation in vapors of polyatomic substances....Pages 138-146
3.1.7 Absorption and dispersion in gases with foreign-gas additions....Pages 147-153
3.1.8 References for 3.1....Pages 154-154
3.2.1 Sound absorption in liquid elements....Pages 155-156
3.2.2 The frequency-independent portions of sound absorption in organic liquids....Pages 157-168
3.2.3 Sound absorption in nonassociated inorganic liquids of simple molecules....Pages 169-170
3.2.4 Sound absorption in nonassociated aliphatic hydrocarbons....Pages 170-173
3.2.5 Sound absorption in cyclic hydrocarbons and in some of their derivates (without associations)....Pages 174-178
3.2.6 Sound absorption in aliphatic halogen containing carbon compounds without associations....Pages 178-181
3.2.7 Sound absorption in nonassociated ethers, aldehydes, and ketones....Pages 181-183
3.2.8 Sound absorption in nonassociated esters....Pages 183-187
3.2.9 Sound absorption in diethylamine and triethylamine....Pages 187-187
3.2.10 Sound absorption in water, H2O....Pages 188-189
3.2.11 Sound absorption in alcohols (associating liquids)....Pages 189-192
3.2.12 Sound absorption in fatty acids....Pages 192-193
3.2.13 References for 3.2....Pages 194-195
3.3.0 Introduction....Pages 195-195
3.3.1 Mixtures of components without association properties....Pages 196-198
3.3.2 Mixtures containing one component with association properties....Pages 199-209
3.3.3 Absorption in aqueous solutions....Pages 209-211
3.3.4 Specific absorption in solutions of higher molecular substances....Pages 211-212
3.3.5 Sound absorption and sound absorption anomalies in liquids of higher viscosity, especially in oils....Pages 213-214
3.4 Sound absorption in solutions of electrolytes....Pages 215-221
3.5 Sound propagation and depolymerization effect in polymers....Pages 222-226
4.1 Phase diagram of helium He4....Pages 227-228
4.2 Velocity and absorption of the ordinary sound: u1 and alpha1....Pages 228-232
4.3 Velocity of the second sound: u2 (second-sound-effect)....Pages 232-233
4.4 References for 4....Pages 233-233
5.0 Introduction....Pages 234-236
5.1.2 Metals....Pages 236-244
5.2 Organic solids....Pages 244-245
5.3 Solid high polymers....Pages 245-250
5.4 References for 5....Pages 251-251
6.0 Definitions....Pages 252-252
6.1 Measurements in gases....Pages 253-253
6.2 Measurements in water, mercury, and in organic liquids....Pages 254-255
6.3 Measurements in metals....Pages 256-258
6.4 References for 6....Pages 258-258
A Elements and inorganic compounds....Pages 259-262
B Organic compounds....Pages 262-274
C Solutions and mixtures....Pages 274-286