macromolecules containg metal and metal-like elements (boron-containing polymers

Cover Page......Page 1
Title Page......Page 6
ISBN 0471730122......Page 7
Contributors......Page 8
Contents (with page links)......Page 10
Preface......Page 14
Series Preface......Page 16
1. The State of the Art in Boron Polymer Chemistry......Page 18
A. A Brief Historical Perspective on Boron and Its Polymers......Page 19
i. π-Conjugated Organoboron Polymers Used in Optical and Sensing Applications......Page 25
a. Formed by the Hydroboration Route......Page 26
b. Formed by Other Synthetic Routes......Page 28
a. Boron Polymers Containing P Atoms......Page 32
c. Boron Polymers Containing Organometallic Moieties......Page 34
a. Boron Ligands/Polymers Used in Olefin Polymerization Reactions......Page 39
b. Organoboron Polymers Used in Other Organic Transformations......Page 46
iv. Organoboron Polymers that Function as Flame-Retardant Materials......Page 48
B. Polymers Containing Boron Ring Systems in the Backbone or in Pendent Groups......Page 50
a. SiC-Producing Borazine Polymer Systems......Page 51
b. Si/B/C/N-Producing Systems......Page 53
iii. Organoboron Polymers that Contain Polypyrazolylborate or Pyrazabole Ring Systems......Page 54
i. Monomeric and Polymeric Organic Analogs of Boron Cluster Systems......Page 55
ii. Poly(carboranylenesiloxanes) and Related Polymers......Page 59
iii. Conducting Polymers Containing Carborane Clusters......Page 69
iv. Carborane Polymers in Medicine......Page 71
v. Carborane Polymers Used in the Production of High-Performance Fibers......Page 74
a. Carborane Polymers of Polyetherketones......Page 77
b. Carborane Polymers for Use in Catalytic Reactions......Page 78
vii. Carborane Supramolecular Chemistry......Page 80
IV. References......Page 88
2. Polymers Incorporating Icosahedral Closo-Dicarbaborane Units......Page 94
I. Introduction......Page 95
A. Polymers Incorporating Decaborane......Page 96
B. Polymers with Pendant Carborane Groups......Page 97
II. Poly(M-Carborane-Siloxane) Rubbers......Page 98
III. Synthesis......Page 99
A. Bis(ureido)silanes: Condensation Polymerization......Page 103
A. Nuclear Magnetic Resonance Spectroscopy......Page 105
C. Thermal and Chemical Properties......Page 106
V. Thermal and Radiation Stability......Page 110
A. Stability to Neutrons......Page 113
A. Poly(ether-ketone-carbaborane)......Page 114
B. Polyphosphazene Incorporating Carboranyl Units......Page 115
VII. Energetic Carborane Polymer Systems......Page 116
VIII. Summary......Page 117
IX. References......Page 118
3. Boron- and Nitrogen-Containing Polymers for Advanced Materials......Page 120
I. Introduction......Page 121
A. tris(Alkylamino)boranes–Derived Poly[B-(alkylamino)borazines]......Page 122
B. tris(B-Alkylamino)borazine–Derived Poly[B-(alkylamino)borazines]......Page 124
i. Two-Step Polycondensation (Thermal Route)......Page 129
ii. One-Step Polycondensation......Page 133
IV. Summary......Page 135
V. References......Page 136
4. Organoboron Polymers......Page 138
I. Introduction......Page 139
A. Hydroboration Polymerization of Diene Monomers......Page 140
B. Reactions of Organoboron Polymers Prepared by Hydroboration Polymerization......Page 141
C. Hydroboration Polymerization of Diyne Monomers......Page 146
D. Conjugated Organoboron Polymers......Page 147
E. Poly(cyclodiborazane)s Prepared by Hydroboration Polymerization of Dicyano Monomers......Page 149
F. Conjugated Poly(cyclodiborazane)s......Page 151
G. Organoboron Polymers as an Anion Sensor......Page 154
A. Haloboration Polymerization......Page 155
B. Phenylboration Polymerization......Page 156
C. Alkoxyboration Polymerization......Page 157
A. Grignard and Organolithium Reagents......Page 158
B. Poly(cyclodiborazane)s via Cross-Coupling Reactions......Page 159
C. Poly(pyrazabole)s via Cross-Coupling Reactions......Page 160
VI. References......Page 162
5. Boron- and Nitrogen-Containing Polymers......Page 166
I. Introduction......Page 167
III. Polymers Derived from Borazine......Page 168
A. Poly(B-amino)borazines Prepared in a One-Step Process......Page 173
B. Poly(B-borylamino)borazines Prepared in a One-Step Process......Page 176
C. Poly(B-amino)borazines Prepared in a Two-Step Process......Page 178
D. Poly(B-borylamino)borazines Prepared in a Two-Step Process......Page 183
V. Polymers Derived from tris(Alkylamino)boranes......Page 186
VI. Summary......Page 188
VII. References......Page 189
6. Organoboron Polymer Electrolytes for Selective Lithium Cation Transport......Page 192
I. Introduction......Page 193
II. Anion-Trapping-Type Organoboron Polymer Electrolytes via Hydroborane Monomer......Page 194
III. Comblike Organoboron Polymer Electrolytes......Page 197
IV. Facile Preparation of Organoboron Polymer Electrolytes via Dehydrocoupling Reaction of 9-Borabicyclo[3.3.1]nonane and Poly(propylene oxide)......Page 199
V. Poly(organoboron halide)-imidazole Complexes......Page 200
VI. Lithium Borate–Type Polymers via Polymer Reactions......Page 203
VII. Direct Synthesis of Poly(lithium organoborate)s......Page 205
VIII. Polymer/Salt Hybrid Including Boron-Stabilized Imidoanion......Page 207
IX. Summary......Page 210
X. References......Page 211
B......Page 214
D......Page 216
G......Page 217
M......Page 218
N,O......Page 219
P......Page 220
T......Page 222
U,V,Z......Page 223