دسترسی نامحدود
برای کاربرانی که ثبت نام کرده اند
برای ارتباط با ما می توانید از طریق شماره موبایل زیر از طریق تماس و پیامک با ما در ارتباط باشید
در صورت عدم پاسخ گویی از طریق پیامک با پشتیبان در ارتباط باشید
برای کاربرانی که ثبت نام کرده اند
درصورت عدم همخوانی توضیحات با کتاب
از ساعت 7 صبح تا 10 شب
ویرایش: [-, 4 ed.]
نویسندگان: Sudarsan Guha . J. D. Lee
سری: -
ISBN (شابک) : 9788126598311, 9788126515547
ناشر: Wiley India Pvt. Ltd.
سال نشر: 2019
تعداد صفحات: 718
زبان: English
فرمت فایل : PDF (درصورت درخواست کاربر به PDF، EPUB یا AZW3 تبدیل می شود)
حجم فایل: 20 Mb
در صورت تبدیل فایل کتاب J.D. Lee Concise Inorganic Chemistry for JEE (Main & Advanced) [, 4 ed.] به فرمت های PDF، EPUB، AZW3، MOBI و یا DJVU می توانید به پشتیبان اطلاع دهید تا فایل مورد نظر را تبدیل نمایند.
توجه داشته باشید کتاب J.D. Lee Concise Inorganic شیمی برای JEE (اصلی و پیشرفته) [، 4 ویرایش] نسخه زبان اصلی می باشد و کتاب ترجمه شده به فارسی نمی باشد. وبسایت اینترنشنال لایبرری ارائه دهنده کتاب های زبان اصلی می باشد و هیچ گونه کتاب ترجمه شده یا نوشته شده به فارسی را ارائه نمی دهد.
J.D. Lee Concise Inorganic Chemistry برای JEE (اصلی و پیشرفته) اقتباس شده توسط Sudarshan Guha (IIT Kanpur، موسسه شغلی ALLEN) وایلی هند Pvt. Ltd.، 4436/7، جاده انصاری، دریاگانج، دهلی نو-110002 مفید برای JEE اصلی JEE پیشرفته IIT-JEE المپیاد KVPY BITSAT JEE(adv) INChO NSEC NSEJS IChO
J.D. Lee Concise Inorganic Chemistry for JEE (Main & Advanced) adapted by Sudarshan Guha (IIT Kanpur, ALLEN career institute) Wiley India Pvt. Ltd., 4436/7, Ansari Road, Daryaganj, New Delhi-110002 useful for JEE main JEE advanced IIT-JEE Olympiad KVPY BITSAT JEE(adv) INChO NSEC NSEJS IChO
Cover Title Copyright Preface Note to the Student Contents 1. Structure of an Atom 1.1 Atoms 1.2 Some Important Definitions 1.3 Electronic Configuration of an Atom Quantum numbers Aufbau principle Pauli exclusion principle Hund’s rule Stability of half-filled and fully-filled shells Electronic configuration of ions Nodal planes of different orbitals Slater’s rule Periodic variation of Zeff values Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion-Reasoning Type Questions Integer Answer Type Questions Matrix-Match Type Questions Answers 2. Periodic Table and Periodic Properties 2.1 Periodic Table Genesis of periodic classification Dobereiner’s triad Newland’s octave law Lother Meyer’s curve Mendeleev’s periodic table Moseley’s work Modern periodic law 2.2 Classification of Elements Based on Electronic Configuration Prediction of period and group number of an element from its electronic configuration Neil Bohr’s classification Naming of super heavy elements 2.3 Periodic Trends in Properties Atomic radius Covalent radius Metallic radius van der Waals radius Periodic variation of atomic radii Ionic radius Ionization energy Periodic variations in ionization energy Applications of ionization energy Electron affinity Periodic trends of electron affinity Electronegativity Periodic variations of electronegativity Applications of Electronegativity Lattice Energy Hydration Energy Ionic Mobility Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 3. Chemical Bonding 3.1 Attainment of a Stable Configuration 3.2 Types of Bonds 3.3 Transitions Between the Main Types of Bonding Ionic bonds Covalent bonds Oxidation numbers Coordinate bonds Double and triple bonds Metallic bonds and metallic structures 3.4 The Covalent Bond The Lewis theory The octet rule Exceptions to the octet rule Sidgwick–Powell theory 3.5 Valence Bond Theory What is the essence of hybridization? Features of hybrid orbitals Calculation of steric number 3.6 Valence Shell Electron Pair Repulsion (VSEPR) Theory Effect of lone pair Effect of double bond Effect of electronegativity Back bonding 3.7 The Extent of d Orbital Participation in Molecular Bonding 3.8 Types of Covalent Bonds (Sigma (σ) and Pi (π) Bonds) Bridge bonding 3.9 Molecular Orbital Method 3.10 Lcao Method s–s combinations of orbitals s–p combinations of orbitals p–p combinations of orbitals p–d combinations of orbitals d–d combinations of orbitals Non-bonding combinations of orbitals 3.11 Rules for Linear Combination of Atomic Orbitals 3.12 Examples of Molecular Orbital Treatment for Homonuclear Diatomic Molecules H2+ molecule ion H2 molecule He2+ molecule ion He2 molecule Li2 molecule Be2 molecule B2 molecule C2 molecule N2 molecule O2 molecule O2- ion F2 molecule 3.13 Examples of Molecular Orbital Treatment for Heteronuclear Diatomic Molecules NO molecule CO molecule 3.14 Dipole Moment Applications of dipole moment Some special cases 3.15 The Ionic Bond Radius ratio rules Calculation of some limiting radius ratio values 3.16 Close Packing 3.17 Ionic Compounds of the Type AX (ZnS, NaCl, CsCl) Structures of zinc sulphide Sodium chloride structure Caesium chloride structure 3.18 Ionic Compounds of the Type AX2 (CaF2, TiO2, SiO2) Calcium fluoride (fluorite) structure Rutile structure β-cristobalite (silica) structure 3.19 Layer Structures (CdI2, CdCl2, [NIAs]) Cadmium iodide structure Cadmium chloride structure Nickel arsenide structure 3.20 Lattice Energy 3.21 Stoichiometric Defects Schottky defects Frenkel defects 3.22 Nonstoichiometric Defects Metal excess F-centres Interstitial ions and electrons Metal deficiency Positive ions absent Extra interstitial negative ions 3.23 Born–Haber Cycle 3.24 Polarizing Power and Polarizability – Fajans’ Rules Properties of ionic compounds affected by polarization 3.25 Melting Point of Ionic Compounds 3.26 Solubility of Ionic Compounds Prediction of solubility order in ionic compounds 3.27 Electrical Conductivity and Colour 3.28 Acidic Nature of Oxides 3.29 Thermal Stability of Ionic Compounds 3.30 Weak Forces Attractive intermolecular forces Repulsive intermolecuar forces Lennard–Jones potential 3.31 Interactions between Ions and Covalent Molecules 3.32 The Metallic Bond Conductivity Lustre Malleability and cohesive force Crystal structures of metals Bond lengths 3.33 Theories of Bonding in Metals Free electron theory Valence bond theory Molecular orbital or band theory 3.34 Conductors, Insulators and Semiconductors Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 4. Hydrolysis 4.1 Introduction 4.2 Hydrolysis Through SN1 Mechanism 4.3 Hydrolysis Through SN2 Mechanism 4.4 Hydrolysis Through Addition–Elimination Mechanism 4.5 Hydrolysis Through Addition Mechanism 4.6 Hydrolysis Through Redox Reaction 4.7 Hydrolysis Through Push–Pull Mechanism 4.8 Hydrolysis Through Mixed Mechanism Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 5. Coordination Compounds 5.1 Double Salts and Coordination Compounds 5.2 Werner’s Work 5.3 More Recent Methods of Studying Complexes 5.4 Classification of Ligands 5.5 Effective Atomic Number (EAN) Sidgwick EAN rule 5.6 Shapes of d Orbitals 5.7 Bonding in Transition Metal Complexes Valence bond theory Crystal field theory Molecular orbital theory 5.8 Valence Bond Theory 5.9 Crystal Field Theory Octahedral complexes 5.10 Effects of Crystal Field Splitting 5.11 Tetragonal Distortion of Octahedral Complexes (Jahn-Teller Distortion) 5.12 Square Planar Arrangements 5.13 Tetrahedral Complexes 5.14 Magnetism 5.15 Extension of the Crystal Field Theory to Allow for Some Covalency 5.16 Nomenclature of Coordination Compounds 5.17 Isomerism Polymerization isomerism Ionization isomerism Hydrate isomerism Linkage isomerism Coordination isomerism Coordination position isomerism Geometrical isomerism and optical isomerism Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 6. Metallurgy 6.1 Types of Ores 6.2 Principal Steps in the Recovery of a Metal from its Ore 6.3 Concentration or Dressing of Ore Gravity separation or levigation Magnetic separation Froth floatation or oil floatation Chemical method of separation: Leaching 6.4 Conversion of Concentrated Ore into its Oxide Calcination Roasting 6.5 Different Reduction Processes Carbon reduction Self reduction Thermite reduction (or Goldschmidt-Thermite process) Metal replacement method (Hydrometallurgy) Electrolytic reduction Thermal decomposition method 6.6 Purification or Refining of Metal Thermal refining Oxidation by air and poling Fractional distillation Liquation Zone refining Vapour phase refining Electrorefining 6.7 Thermodynamics of Reduction Process 6.8 Alloys and Amalgams Classification of alloys Characteristics of alloys Preparation of alloys Amalgam 6.9 Different Types of Furnaces Used in Metallurgy 6.10 Extraction of Silver Refining of Ag 6.11 Extraction of Gold by Cyanide Process Refining of Au 6.12 Extraction of Tin Refining of Sn 6.13 Extraction of Magnesium Electrolytic reduction Carbon reduction process Other processes 6.14 Extraction of Aluminium Beneficiation of bauxite Bayer’s process Hall’s process Serpeck’s process Electrolytic reduction of pure Al2O3 Electrorefining of aluminium 6.15 Extraction of Lead Carbon reduction Self reduction process Refining of lead 6.16 Extraction of Copper Refining of blister copper 6.17 Extraction of Zinc 6.18 Extraction of Iron Purification of iron or preparation of wrought iron Byproducts of iron extraction Steel making Some heat treatment processes related to steel Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 7. Qualitative Salt Analysis Tests for Acid Radicals 7.1 Action of Dilute Acids 7.2 Tests for CO23-/HCO3- and SO23-/HSO3- Radicals Distinction between carbonate and bicarbonate Detection of carbonate and bicarbonate when both are present together Distinction between sulphite and bisulphite Some other tests for SO23- ions 7.3 Tests for Sulphide (S2-) Radical 7.4 Tests for Thiosulphate (S2O23-) Radical 7.5 Tests for Nitrite (NO2-) Radical 7.6 Tests for Acetate, Formate and Oxalate Radicals Specific test for acetate (cacodyl oxide test) Specific test for formate (mercury (II) formate test) Specific tests for oxalate 7.7 Tests for Halide (Cl-, Br-, I-) Radicals Specific test for Cl- (chromyl chloride test) Specific test for Br- and I- (layer test) Other test for Br- Other tests for I- 7.8 Tests for Nitrate (NO3-) Radical 7.9 Tests for Sulphate (SO24-) Radical 7.10 Tests for Borate (Bo33-) Radical 7.11 Tests for Phosphate (PO34-) Radical 7.12 Tests for Chromate (CrO24-) and Dichromate (Cr2O27-) Radicals 7.13 Tests for Permanganate (MnO4-) and Manganate (MnO24-) Radicals Tests for Basic Radicals 7.14 Dry Tests for Basic Radicals Heating effects on the dry sample Residue Colour change Sublimation Gas evolved Flame test Borax bead test Sodium carbonate bead test 7.15 Wet Tests for Basic Radicals Classification of cations (group analysis) 7.16 Some General Tests for Cations Tests for group V cations Tests for group VI and zero group cations 7.17 Specific Tests for Some Cations Heating Effects Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 8. Hydrogen and the Hydrides 8.1 Electronic Structure 8.2 Position in the Periodic Table 8.3 Abundance of Hydrogen 8.4 Preparation of Hydrogen 8.5 Properties of Molecular Hydrogen Physical properties Chemical properties Use of hydrogen as fuel 8.6 Isotopes of Hydrogen 8.7 Ortho and Para Hydrogen 8.8 Hydrides Ionic or salt-like hydrides Covalent hydrides Metallic (or interstitial) hydrides Intermediate hydrides 8.9 The Hydrogen Ion 8.10 Hydrogen Bonding Intermolecular hydrogen bonding Effect of intermolecular hydrogen bonding on physical properties Intramolecular hydrogen bonding Effect of intramolecular hydrogen bonding on physical and chemical properties Strength of hydrogen bonding Extent of hydrogen bonding Special cases of hydrogen bonding Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 9. The s-Block Elements and their Compounds Group 1 – The Alkali Metals 9.1 General Properties Electronic structure Size of atoms and ions Density Ionization energy Electronegativity and bond type 9.2 Structures of the Metals, Hardness and Cohesive Energy Melting and boiling points 9.3 Flame Colours and Spectra 9.4 Colour of Compounds 9.5 Chemical Properties Reaction with water Reaction with air Reaction with dinitrogen 9.6 Oxides, Hydroxides, Peroxides and Superoxides Reaction with air Normal oxides – monoxides Hydroxides Peroxides and superoxides 9.7 Sulphides 9.8 Oxosalts – Carbonates, Bicarbonates, Nitrates, Nitrites and Sulphates 9.9 Halides and Polyhalides 9.10 Hydrides 9.11 Solubility and Hydration 9.12 Solutions of Metals in Liquid Ammonia 9.13 Compounds with Carbon 9.14 Complexes, Crowns and Crypts 9.15 Biological Importance 9.16 Differences between Lithium and the Other Group 1 Elements 9.17 Preparation of Sodium Hydroxide 9.18 Electrolytic Processes Diaphragm cell Mercury cathode cell 9.19 Preparation of Sodium Carbonate 9.20 The Solvay (or Ammonia – Soda) Process Group 2 – The Alkaline Earth Elements 9.21 General Properties Electronic structure Size of atoms and ions Ionization energy Electronegativity Hydration energies Solubility and lattice energy Solutions of the metals in liquid ammonia 9.22 Anomalous Behaviour of Beryllium 9.23 Chemical Properties Reaction with water 9.24 Hydroxides 9.25 Hardness of Water 9.26 Reaction with Acids and Bases 9.27 Oxides and Peroxides 9.28 Sulphates 9.29 Nitrates 9.30 Hydrides 9.31 Halides 9.32 Nitrides 9.33 Carbides 9.34 Complexes 9.35 Biological Role of Mg2+ and Ca2+ 9.36 Differences between Beryllium and the Other Group 2 Elements Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 10. The p-Block Elements and their Compounds Part 1: The Group 13 Elements 10.1 Oxidation States and Types of Bonds The (+III) oxidation state The (+I) oxidation state – the ‘inert pair effect’ 10.2 General Properties Melting points, boiling points and structures Size of atoms and ions Electropositive character Ionization energy 10.3 Preparation of Boron 10.4 Reactions of Boron 10.5 Reactions of the Other Elements Reaction with water and air Reaction with acids and alkalis Reaction with dioxygen Reaction with the halogens and sulphate Alums Cement 10.6 Compounds of Boron and Oxygen Boron sesquioxide and the borates Acidic properties of H3BO3 or B(OH)3 Structures of borates Borax Sodium peroxoborate Qualitative analysis of boron compounds Fluoboric acid 10.7 The Other Group 13 Oxides Preparation of Al2O3 Amphoteric behaviour – aluminates 10.8 Tetrahydridoborates (Borohydrides) 10.9 Halides Trihalides Dihalides 10.10 Complexes 10.11 Differences Between Boron and the Other Elements (Anomalous Behaviour of Boron) 10.12 Boron Hydrides Compounds known Preparation 10.13 Reactions of the Boranes Hydroboration Reaction with ammonia Some other reactions of boranes 10.14 Structures of the Boranes 10.15 Organometallic Compounds Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers Part 2: The Group 14 Elements 10.16 Structure and Allotropy of the Elements 10.17 Differences Between Carbon, Silicon and the Remaining Elements 10.18 Physical Properties Covalent radii Ionization energy Melting points Metallic and non-metallic character Four-covalent compounds 10.19 Chemical Reactivity Inert pair effect 10.20 Carbides Salt-like carbides Interstitial carbides Covalent carbides 10.21 Oxygen Compounds of Carbon Carbon monoxide CO Carbon dioxide CO2 Preparation of CO2 Recovery of CO2 Carbon suboxides 10.22 Carbonates 10.23 Sulphides of Carbon 10.24 Oxides of Silicon 10.25 Oxides of Tin and Lead Oxides of Tin Preparation Properties Oxides of Lead Preparation of PbO Properties of PbO Preparation of PbO2 Properties of PbO2 Preparation of Pb2O3 Properties of Pb2O3 Preparation of Pb3O4 Properties of Pb3O4 10.26 Silicates Occurrence in the Earth’s crust Soluble silicates 10.27 Classification of Silicates Orthosilicates (neso-silicates) Pyrosilicates (soro-silicates, disilicates) Cyclic silicates Chain silicates Sheet silicates (phyllo-silicates) Three-dimensional silicates Zeolites 10.28 Glass 10.29 Organosilicon Compounds and the Silicones Organosilicon compounds Preparation of organosilicon compounds Silicones Uses of silicones 10.30 Hydrides of Silicon 10.31 Complexes 10.32 Internal π Bonding Using d Orbitals 10.33 Halides Tetrahalides Carbon Freons Silicon Tin and lead Catenated halides Dihalides 10.34 Organic Derivatives Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers Part 3: The Group 15 Elements 10.35 General Properties and Structures of the Elements Nitrogen Phosphorus Bond type Metallic and non-metallic character Reactivity 10.36 Hydrides Ammonia NH3 Ammonium salts Phosphine PH3 Arsine AsH3, stibine SbH3 and bismuthine BiH3 Structure of the hydrides Donor properties Hydrazine N2H4 Hydroxylamine NH2OH 10.37 Liquid Ammonia as a Solvent 10.38 Hydrogen Azide and the Azides 10.39 Nitrogen Fixation Cyanamide process Haber–Bosch process 10.40 NPK Fertilizers Urea Phosphate fertilizers 10.41 Halides Trihalides Pentahalides 10.42 Oxides of Nitrogen Nitrous oxide N2O Nitric oxide NO Nitrogen sesquioxide N2O3 Nitrogen dioxide NO2 and dinitrogen tetroxide N2O4 Dinitrogen pentoxide N2O5 10.43 Oxoacids of Nitrogen Nitrous acid HNO2 Nitric acid HNO3 Other Chemical Properties of HNO3 10.44 Oxides of Phosphorus Trioxides Pentoxides 10.45 Oxoacids of Phosphorus The phosphoric acid series Orthophosphoric acids Polyphosphates Graham's salt Metaphosphates – cyclophosphates The phosphorous acid series Orthophosphorous acid H3PO3 Hypophosphorous acid H3PO2 Major uses of phosphates Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers Part 4: The Group 16 Elements – Chalcogens 10.46 General Properties Electronic structure and oxidation states Acid rain and SO2 Uses of sulphur 10.47 Structure and Allotropy of the Elements Oxygen Ozone Preparation of ozone Physical properties Chemical properties Uses of ozone Estimation of ozone Sulphur 10.48 Physical Properties 10.49 Chemical Reactivity Oxidation states (+II), (+IV) and (+VI) Bond lengths and pπ – dπ bonding Differences between oxygen and the other elements 10.50 General Properties of Oxides Classification based on structure Normal oxides Peroxides Suboxides Classification based on chemical properties Basic oxides Amphoteric oxides Acidic oxides Neutral oxides 10.51 Oxides of Sulphur Dioxide SO2 Chemical properties Estimation of SO2 Detection of SO2 Uses Trioxide SO3 10.52 Oxoacids of Sulphur Sulphurous acid Sulphuric acid series Physical properties Chemical properties Dehydrating properties Uses of sulphuric acid Thiosulphuric acid and thiosulphates Pyrosulphates Thionic acid series Peroxoacid series 10.53 Oxohalides Thionyl compounds Sulphuryl compounds 10.54 Hydrides Water Other hydrides Peroxides and polysulphides Hydrogen peroxide Preparation Physical properties Chemical properties Uses 10.55 Halides Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers Part 5: The Group 17 Elements – The Halogens 10.56 Extraction and Uses of the Elements Fluorine Chlorine Bromine Iodine 10.57 General Properties Size of atoms and ions Ionization energy Type of bonds formed and oxidation states Melting and boiling points Bond energy in X2 molecules Oxidizing power 10.58 Reaction with Water 10.59 Reactivity of the Elements 10.60 Hydrogen Halides HX HF HCl HBr and HI 10.61 Halides Ionic halides Molecular (covalent) halides Bridging halides 10.62 Halogen Oxides Oxygen difluoride OF2 Dioxygen difluoride O2F2 Dichlorine monoxide Cl2O Bleaching powder Chlorine dioxide ClO2 Chlorine perchlorate Cl · ClO4 Dichlorine hexoxide Cl2O6 Dichlorine heptoxide Cl2O7 10.63 Oxoacids Hypohalous acids HOX Halous acids HXO2 Halic acids HXO3 Perhalic acids HXO4 Strength of the oxoacids 10.64 Interhalogen Compounds AX, AX3 and AX5 compounds 10.65 Polyhalides 10.66 Pseudohalogens and Pseudohalides Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers Part 6: The Group 18 Elements – Noble Gases 10.67 Occurrence and Recovery of the Elements 10.68 Uses of the Elements 10.69 Physical Properties 10.70 Special Properties of Helium 10.71 Chemical Properties of the Noble Gases Molecular ions formed under excited conditions Clathrate compounds 10.72 Chemistry of Xenon Xenon fluoride complexes 10.73 Structure and Bonding in Xenon Compounds XeF2 XeF4 XeF6 10.74 Structures of Some Xenon Compounds Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers Miscellaneous Questions Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 11. The d-Block Elements and some of their Compounds 11.1 Variable Oxidation State Stability of the various oxidation states 11.2 Complexes 11.3 Size of Atoms and Ions 11.4 Density 11.5 Melting and Boiling Points 11.6 Reactivity of Metals 11.7 Ionization Energies 11.8 Colour Polarization Incompletely filled d or f shell 11.9 Magnetic Properties 11.10 Catalytic Properties 11.11 Nonstoichiometry 11.12 Abundance 11.13 Chromate and Dichromate Preparation Properties 11.14 Manganate and Permanganate Preparation Properties 11.15 Silver and its Compounds Silver nitrate (AgNO3) Properties Properties Use 11.16 Zinc Compounds Zinc oxide (ZnO) Preparation Properties Uses Zinc chloride (ZnCl2) Preparation Properties Uses Zinc sulphate (ZnSO4) Preparation Properties Uses 11.17 Copper Compounds Copper oxide (CuO) Preparation Properties Copper chloride (CuCl2) Preparation Properties Copper sulphate (CuSO4) Preparation Properties 11.18 Iron Compounds Iron sulphate (FeSO4.7H2O) Preparation Properties Iron oxide (FeO) Preparation Properties Iron chloride (FeCl2) Preparation Properties Uses Single Correct Choice Type Questions Multiple Correct Choice Type Questions Comprehension Type Questions Assertion–Reasoning Type Questions Integer Answer Type Questions Matrix–Match Type Questions Answers 12. The f-Block Elements and their Properties 12.1 Lanthanoids Properties of lanthanoids and their ions Atomic and ionic radii Oxidation states Color Magnetic properties Some other properties of lanthanoids Uses of lanthanoids 12.2 Actinoids Properties of actinoids and their ions Atomic and ionic radii Oxidation states Magnetic properties Colour Melting points and boiling points Physical appearance Uses of actinoids 12.3 Comparison between Lanthanoids and Actinoids Similarities Differences Single Correct Choice Type Questions Answers Appendices Appendix A: Abundance of the Elements in the Earth’s Crust Appendix B: Melting Points of the Elements Appendix C: Boiling Points of the Elements Appendix D: Densities of the Solid and Liquid Elements Appendix E: Electronic Structures of the Elements Appendix F: Some Average Single Bond Energies and Some Double and Triple Bond Energies Appendix G: Solubilities of Main Group Compounds in Water Appendix H: Atomic Weights Based on 12 C = 12.000 Appendix I: Values of Some Fundamental Physical Constants Appendix J: Electrical Resistivity of the Elements at the Stated Temperature Appendix K: Hardness of Minerals – Mohs’ Scale JEE (ADVANCED) 2018 JEE Main 2019 Index Back Cover