Ionic Equilibria in Analytical Chemistry

Front Matter....Pages 1-1
Front Matter....Pages 1-1
Solvents—Composition of Solutions....Pages 3-11
Thermodynamics and Equilibrium....Pages 13-36
Activities and Activity Coefficients....Pages 37-48
Front Matter....Pages 49-49
Definitions of Acids and Bases: Strength of Acids and Bases....Pages 51-75
Calculations of pH Values in Aqueous Solutions....Pages 77-105
Buffer Solutions....Pages 107-118
Some General Points Concerning Titrations....Pages 119-125
Neutralization or Acid-Base Indicators....Pages 127-134
Acid-Base Titration Curves....Pages 135-156
Acid–Base Titrations: Further Theoretical Studies....Pages 157-167
Acid–Base Reactions and Chemical Analysis....Pages 169-190
Front Matter....Pages 191-191
Generalities on Oxidation-Reduction....Pages 193-203
Redox Reactions and Electrochemical Cells....Pages 205-227
Predicting Redox Reactions....Pages 229-246
Predicting Redox Reactions by Graphical Means....Pages 247-263
Calculating Equilibrium Potentials of Solutions Containing Several Redox Couples....Pages 265-283
A Study of Some Redox Titration Curves....Pages 285-312
Oxidoreductimetry: Direct and Indirect Iodometries....Pages 313-345
Iodometry in Alkaline Medium, Iodatometry, Periodimetry, and Bromometry....Pages 347-367
Oxidizations with Permanganate, Dichromate, and Ceric Ions....Pages 377-403
Front Matter....Pages 191-191
Some Applications of Redox Reactions in Qualitative Analysis....Pages 405-419
Front Matter....Pages 421-421
General Definitions Concerning Complexes....Pages 423-428
Some Elements Concerning the Chemistry of Complexes....Pages 429-437
Stability of Complexes: Some Elements Concerning the Kinetics of Their Formation....Pages 439-459
Superimposition of Varied Equilibria to Complexation Equilibria....Pages 461-484
Conditional Stability Constants....Pages 485-501
Complexometry I: Mercurimetry (Votocek–Dubsky’s Method)....Pages 503-511
Complexometry II: Titrations with EDTA....Pages 513-523
Complexometry III: Metal Cation Indicators and Types of EDTA Titrations....Pages 525-541
Applications of the Formation of Complexes in Inorganic Analysis....Pages 543-572
Applications of the Formation of Complexes in Organic Analysis....Pages 575-608
Front Matter....Pages 573-573
Intrinsic, Ionic, and Total Solubilities; Solubility Product and Precipitation....Pages 609-617
Dependence of the Solubility on the Solution’s Ionic Strength and on the Presence of Common Ions: Superimposition of Several Precipitation Equilibria....Pages 619-631
Solubility and pH....Pages 633-658
Precipitation and Complexation....Pages 659-677
Theoretical Study of Some Precipitation Titration Curves....Pages 679-688
Titrimetric Methods Involving a Precipitation....Pages 689-703
Gravimetry by Precipitation....Pages 705-720
Some Applications of the Precipitation Phenomenon in Inorganic and Organic Qualitative and Quantitative Analysis....Pages 721-741
Back Matter....Pages 729-729