Interaction of gases with surfaces : detailed description of elementary processes and kinetics

Lecture Notes in Physics: Monographs 25 ......Page 1
Interaction of Gases with Surfaces ......Page 3
Preface ......Page 11
Contents ......Page 13
1.1 Gas-Surface Interaction Potential ......Page 17
1.2 Path Integral Representation of S-matrix ......Page 19
1.3 Stationai-y Phase Method for Path Integrals ......Page 22
1.4 Path Integral over Variables of Normal Motion ......Page 24
1.5 Internal Degrees of Freedom of Scattered Particles ......Page 27
2.1 Dynamic Structural Factor in Thermal Regime ......Page 29
2.2 Inelastic Scattering in Diffraction Regime ......Page 31
2.3 Single Phonon Approximation ......Page 33
2.4 Rotational and Vibrational Resoneinces ......Page 34
3.1 Gaussian Approximation to the Dyneimic Structural Factor ......Page 35
3.2 Multiphonon Scattering from Monolayer Adsorbate ......Page 37
4.1 Statistical Structural Factor ......Page 39
4.2 Influence of Local Defects ......Page 41
5 Concluding Remarks on Quasiclassical Approach to Gas-Surface Scattering ......Page 42
6 Microscopic Models of Detailed Kinetics ......Page 47
6.1 Lattice Gas (LG) Model ......Page 48
6.2 Unified Gas-Adsorbate Layer (UGAL) Model ......Page 52
6.3 Knudsen Layer Problem with Adsorbate ......Page 54
7.1 Model of 3D LG Adsorbate ......Page 56
7.3 Mechanisms of Surface Reactions ......Page 60
8.1 Dimensionless Form of Kinetic Equations ......Page 61
8.2 Fast Relaxation ......Page 62
8.3 Fast Isothermal Energy Relaxation ......Page 65
8.5 Diffusion Form of LG Model Equations ......Page 66
9.1 Equilibrium Distribution for Structureless Gas ......Page 69
9.2 Specific Features of Equilibrium Distributions ......Page 70
9.3 Evaluation of Characteristics of Growing Film ......Page 73
9.4 Statistical Evaluation of Equilibrium Parameters of Adsorbed Films ......Page 75
10.1 Description of Adlayer Dynamics by Methods of Statistical Thermodynamics ......Page 79
10.2 Description of Adlayer Dyneimics by Methods of Thermodynamics of Irreversible Processes ......Page 83
11.1 Incubation Stage ......Page 99
11.3 Coagulation Stage ......Page 103
12.1 General Kinetic Model ......Page 106
12.2 Kinetic Model of Multilayer Film Growth ......Page 109
13.1 Capillai-y Model ......Page 112
13.2 Generalized Kolmogorov Model ......Page 117
13.3 Multilayer Adsorption Film ......Page 122
Part IV Kinetic Boundary Condition (KBC) and Inverse Scattering Problem ......Page 129
14.1 General Representations of KBC ......Page 130
14.2 Simplified Representations of KBC ......Page 133
14.3 Phenomenological Approximations for Boundary Operators ......Page 134
15.1 Gas-Cold Surface Interaction Potential Extraction: Quasiclassical Approach ......Page 138
15.2 Extraction of the Interaction Potential from Excheinge Coefficients: Quasiclassical Approach ......Page 141
References ......Page 143