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ویرایش: نویسندگان: G.F. Froment, B. Delmon and P. Grange (Eds.) سری: Studies in Surface Science and Catalysis 106 ISBN (شابک) : 9780444825568 ناشر: Academic Press, Elsevier سال نشر: 1997 تعداد صفحات: 1-582 [564] زبان: فرمت فایل : PDF (درصورت درخواست کاربر به PDF، EPUB یا AZW3 تبدیل می شود) حجم فایل: 10 Mb
در صورت تبدیل فایل کتاب Hydrotreatment and Hydrocracking of Oil Fractions, Proceedings of the 1st International Symposium/6th European Workshop به فرمت های PDF، EPUB، AZW3، MOBI و یا DJVU می توانید به پشتیبان اطلاع دهید تا فایل مورد نظر را تبدیل نمایند.
توجه داشته باشید کتاب هیدروتریک و هیدروکراکینگ فراکسیون های نفتی، مجموعه مقالات اولین سمپوزیوم بین المللی / ششمین کارگاه اروپایی نسخه زبان اصلی می باشد و کتاب ترجمه شده به فارسی نمی باشد. وبسایت اینترنشنال لایبرری ارائه دهنده کتاب های زبان اصلی می باشد و هیچ گونه کتاب ترجمه شده یا نوشته شده به فارسی را ارائه نمی دهد.
سمپوزیوم در مورد تصفیه هیدرولیکی و هیدروکراکینگ فراکسیون های نفتی با هدف ارائه یک چشم انداز جهانی و بازرسی از پیشرفته ترین این فرآیندها است. مقررات زیست محیطی جدید آمریکا، اروپا و ژاپن نیازمند فرآیندهای تصفیه آب پیشرفته برای HDS و HDN برای حذف اجزای S و Ni از بخش های نفتی است. اینها صفحه محصول پالایشگاه های نفت و ترکیب هیدروکربنی این محصولات را تغییر می دهند. هیدروکراکینگ نقش مهمی در این تغییر خواهد داشت. تطبیق شرایط عملیاتی برای رسیدن به مشخصات و بازده محصول مورد نظر کافی نخواهد بود. باید کاتالیزورهای کافی ایجاد شود. اکنون ابزارهای قدرتمندی برای این کار در دسترس هستند، به عنوان مثال. تکنیکهای علوم سطح، مدلسازی مولکولی و انواع جدید راکتورها در حالت غیر ثابت کار میکنند. ابزار دیگر در بهبود واحدهای تصفیه هیدرولیکی و هیدروکراکینگ، در دسترس بودن مدلهای جنبشی واقعیتر است. اینها بر اساس یک بینش عاقلانه از مکانیسم واکنش است که توسط ابزارهای ذکر شده در بالا نیز ارائه شده است. پیشرفت در تکنیکهای تحلیلی باعث کاهش تودهای اجزا در این مدلهای سینتیکی شده و معادلات جنبشی مرتبه اول به تدریج با معادلات جذب اجزای مختلف جایگزین میشوند. مدلهای راکتور دقیقتر و واقعیتر در حال حاضر مبتنی بر مدلهای هیدرودینامیکی دقیق هستند و کاربرد آنها از طریق امکانات به سرعت در حال افزایش رایانهها امکانپذیر شده است.
The symposium on Hydrotreatment and Hydrocracking of Oil Fractions aims to provide a global perspective and an inspection of the state-of-the-art of these processes. New American, European and Japanese environmental regulations call for advanced hydrotreatment processes for HDS and HDN for the removal of S- and Ni-components from oil fractions. These will alter the product slate of the oil refineries and the hydrocarbon composition of these products. Hydrocracking will play an important part in this shift. Adapting the operating conditions will not suffice to reach the desired product specifications and yields. Adequate catalysts will have to be developed. Powerful tools are now available for this, e.g. surface science techniques, molecular modeling and new types of reactors operated in a nonsteady mode. Another instrument in the improvement of hydrotreatment and hydrocracking units is the availability of more realistic kinetic models. These are based on a judicious insight into the reaction mechanism, also provided by the above-mentioned tools. Progress in the analytical techniques has allowed the reduction of the lumping of components in these kinetic models and first order kinetic equations are gradually replaced by equations accounting for the adsorption of the various components. More detailed and more realistic reactor models are now based on rigorous hydrodynamic models and their application has become possible through the rapidly increasing possibilities of computers.
Content:
Introduction
Page xi
B. Delmon, G.F. Froment, P. Grange
Processes and catalysts for hydrocracking of heavy oil and residues Original Research Article
Pages 1-16
F. Morel, S. Kressmann, V. Harlé, S. Kasztelan
An improved process for the production ofenvironmentally friendly diesel fuels Original Research Article
Pages 17-25
J. Grootjans, C. Olivier
Hydroprocessing to produce reformulated gasolines: The ISAL™ process Original Research Article
Pages 27-40
G.J. Antos, B. Solari, R. Monque
Molecules, catalysts and reactors in hydroprocessing of oil fractions Original Research Article
Pages 41-67
W.H.J. Stork
Simultaneous HDN/HDS of model compounds over Ni-Mo sulfide catalysts Original Research Article
Pages 69-82
Liping Zhang, Umit S. Ozkan
Kinetics of the catalytic removal of the sulphur components from the light cycle oil of a catalytic cracking unit Original Research Article
Pages 83-97
G.F. Froment, G.A. Depauw, V. Vanrysselberghe
A review of catalytic hydrotreating processes for the upgrading of liquids produced by flash pyrolysis Original Research Article
Pages 99-113
R. Maggi, B. Delmon
Dual-functional Ni-Mo sulfide catalysts on zeolite-alumina supports forhydrotreating and hydrocracking of heavy oils Original Research Article
Pages 115-128
H. Shimada, S. Yoshitomi, T. Sato, N. Matsubayashi, M. Imamura, Y. Yoshimura, A. Nishijima
Hydrocracking of C10 hydrocarbons over a sulfided NiMo/Y zeolite catalyst Original Research Article
Pages 129-136
J.L. Lemberton, A. Baudon, M. Guisnet, N. Marchal, S. Mignard
Novel hydrotreating catalysts based on synthetic clay minerals Original Research Article
Pages 137-146
R.G. Leliveld, W.C.A. Huyben, A.J. van Dillen, J.W. Geus, D.C. Koningsberger
Influence of the location of the metal sulfide in NiMo/HY hydrocracking catalysts Original Research Article
Pages 147-156
D. Cornet, M. El Qotbi, J. Leglise
Acidity induced by H2S adsorption on unpromoted and promoted sulfided catalysts Original Research Article
Pages 157-166
Cyrille Petit, Françoise Maugé, Jean-Claude Lavalley
Organo metallic siloxanes as an active components of hydrotreating catalysts Original Research Article
Pages 167-179
I.M. Kolesnikov, A.V. Yablonsky, M.M. Sugungun, S.I. Kolesnikov, M.Y. Kilyanov
Alumina supported HDS catalysts prepared by impregnation with newheteropolycompounds Original Research Article
Pages 181-194
A. Griboval, P. Blanchard, E. Payen, M. Fournier, J.L. Dubois
Genesis, characterizations and HDS activity of Mo-P-aluminabased hydrotreating catalysts prepared by a sol-gel method Original Research Article
Pages 195-210
R. Iwamoto, J. Grimblot
Effects of ethylenediamine on the preparation of HDS catalysts: Comparison between Ni-Mo and Co-Mo based solids Original Research Article
Pages 211-223
P. Blanchard, E. Payen, J. Grimblot, O. Poulet, R. Loutaty
Creation of acidic sites by hydrogen spillover in model hydrocracking systems Original Research Article
Pages 225-235
Alexandre M. Stumbo, Paul Grange, Bernard Delmon
Application of ASA supported noble metal catalysts in the deep hydrodesulphurisation of diesel fuel Original Research Article
Pages 237-244
H.R. Reinhoudt, R. Troost, S. van Schalkwijk, A.D. van Langeveld, S.T. Sie, H. Schulz, D. Chadwick, J. Cambra, V.H.J. de Beer, J.A.R. van Veen, J.L.G. Fierro, J.A. Moulijn
Reactor runaway in pyrolysis gasoline hydrogenation Original Research Article
Pages 245-254
E. Goossens, R. Donker, F. van den Brink
Surface property of alumina-supported Mo carbide and its activity for HDN Original Research Article
Pages 255-262
Toshihiro Miyao, Katsuhiko Oshikawa, Shinzo Omi, Masatoshi Nagai
The design of base metal catalysts for hydrotreating reactions;Temperature programmed sulphidation of NiW/Al2O3 catalysts and their activity in the hydrodesulphurisation of thiophene and dibenzothiophene Original Research Article
Pages 263-271
H.R. Reinhoudt, A.D. van Langeveld, R. Mariscal, V.H.J. de Beer, J.A.R. van Veen, S.T. Sie, J.A. Moulijn
Surface science models of CoMoS hydrodesulfurisation catalysts Original Research Article
Pages 273-280
A.M. de Jong, V.H.J. de Beer, J.A.R. van Veen, J.W. Niemantsverdriet
Molecular mechanics modelling of the interactions between MoS2 layers andalumina or silica support Original Research Article
Pages 281-292
Philippe Faye, Edmond Payen, Daniel Bougeard
In-situ FT-IR study of NO adsorbed on Co-Mo/Al2O3 sulfided athigh pressure (≦5.1 MPa) Original Research Article
Pages 293-302
Naoto Koizumi, Minoru Iijima, Takeo Mochizuki, Muneyoshi Yamada
Compound formation and hydrogen activity at sulfided catalysts:A combined surface science and quantum chemical approach Original Research Article
Pages 303-306
J. Paul, H. Akpati, P. Nordlander, W.S. Oh, D.W. Goodman, B. Demirel
Deactivation studies on NiO-MoO3/Al2O3 and CoO-MoO3/Al2O3hydrodesulphurization catalysts Original Research Article
Pages 307-310
R. Marinković-Nedučin, E. Kiš, M. Djurić, J. Kiurski, D.. Obadović, P. Pavlović, R. Mićić
Characterization of aged catalyst from hydrotreating petroleum residue Original Research Article
Pages 311-321
M.T. Martínez, J.M. Jiménez, M.A. Callejas, F.J. Gómez, C. Rial, E. Carbó
Hydrotreatment of spent lube oil: Catalysts and reactor performance Original Research Article
Pages 323-331
C. Yiokari, S. Morphi, A. Siokou, F. Satra, S. Bebelis, C.G. Vayenas, C. Karavassilis, G. Deligiorgis
Catalytic hydrodesulfurization of petroleum middle distillateand model sulfur compounds over a series of catalysts activity and scheme Original Research Article
Pages 333-342
Emmanuel Lecrenay, Isao Mochida
Hydrotreating of compounds and mixtures of compounds having mercapto and hydroxyl groups Original Research Article
Pages 343-352
T.-R. Viljava, A.O.I. Krause
Influence of high Mo loading on the HYD/HDS selectivity of alumina supported MoS2 catalysts Original Research Article
Pages 353-360
Pedro Da Silva, Nathalie Marchal, Slavik Kasztelan
Low temperature hydrocracking of paraffinic hydrocarbons over hybrid catalysts Original Research Article
Pages 361-370
I. Nakamura, K. Sunada, K. Fujimoto
Tail-selective hydrocracking of heavy gas oil in diesel production Original Research Article
Pages 371-378
M.V. Landau, L.O. Kogan, M. Herskowitz
Influence of the hydrocarbon chain length on the kinetics of the hydroisomerization and hydrocracking of n-paraffins Original Research Article
Pages 379-389
B. Debrabandere, G.F. Froment
Aromatics hydrogenation over supported platinumcatalysts: The influence of sulfur on the kinetics of toluene hydrogenation over Pt/Y-zeolite catalysts Original Research Article
Pages 391-401
Hkon Bergem, Edd A. Blekkan, Anders Holmen
Kinetic study of the hydrodenitrogenation of pyridine and piperidine on A NiMo catalyst Original Research Article
Pages 403-413
Ragnhild Pille, Gilbert Froment
Kinetic modelling of HDN reaction over (Ni)Mo(P)/Al2O3 catalysts Original Research Article
Pages 415-420
M. Jian, R. Prins
A Kinetic model for hydrodesulfurisation Original Research Article
Pages 421-435
M. Sau, C.S.L. Narasimhan, R.P. Verma
Hydrotreating of gas-oils: A comparison of trickle-bed and upflow fixed bed lab scale reactors Original Research Article
Pages 437-442
Rune Myrstad, Jorunn Steinsland Rosvoll, Knut Grande, Edd A. Blekkan
Trickle-bed reactor modeling for middle-distillates hydrotreatment Original Research Article
Pages 443-448
C.G. Dassori, N. Fernández, R. Arteca, A. Díaz, S. Buitrago
Petroleum residua hydrotreating on Co and/or Ni containing catalysts Original Research Article
Pages 449-462
V.M. Kogan, N.M. Parfenova
Saturation of aromatics in diesel fuels: The catalytic toxicities of sulfur and nitrogen compounds Original Research Article
Pages 463-468
P. Kokayeff, G.J. Antos
Production of high octane gasoline components by hydroprocessing, of coalderived aromatic hydrocarbons Original Research Article
Pages 469-478
B. Demirel, W.H. Wiser
Process development in gasoil hydrotreating Original Research Article
Pages 479-484
RC Lawrence, DH McKinely, MA Wood
Benzene hydrogenation over transition metal carbides Original Research Article
Pages 485-490
Carlos Márquez-Alvarez, John B. Calridge, Andrew P.E. York, Jeremy Sloan, Malcolm L.H. Green
Hydrodesulfurization of dibenzothiophene in a micro trickle bed reactor Original Research Article
Pages 491-497
D. Letourneur, M. Vrinat, R. Bacaud
Use of dispersed catalysts for fossil fuel upgrading Original Research Article
Pages 499-503
A.S. Hirschon, R.B. Wilson
Hydrodesulphurization of gas oil using Co-Mo/Al2O3 catalyst Original Research Article
Pages 505-508
A.S. Nasution, E. Jasjfi
The application of cobalt containing acidic zeolites as catalysts forhydrodesulfurization reactions Original Research Article
Pages 509-517
Tamás I. Korányi, Ngan H. Pham, Andreas Jentys, Hannelore Vinek
Hydrodearomatization of naphtenic base machine oils Original Research Article
Pages 519-521
G. Kons, H.-J. Müller, M. Vicari, E. Schwab, M. Walter
Highly dispersed metal sulfide catalysts for the hydroconversion ofvacuum destillation residues Original Research Article
Pages 523-527
K. Büker, H. Berndt, B. Lücke, W. Kotowski
Hydrogenation of tetralin over a sulfided ruthenium on Y zeolite catalyst: comparison with a sulfided NiMo on alumina catalyst Original Research Article
Pages 529-534
J.L. Lemberton, M. Cattenot, V. Kougionas, M. Mhaouer, J.L. Portefaix, M. Breysse, G. Pérot
Catalysts of phosphotungstic or phosphomolybdic acidson different supports from dimethylformamide solutions Original Research Article
Pages 535-540
L.R. Pizzio, P.G. Vázquez, M.G. González, M.N. Blanco, C.V. Cáceres, H.J. Thomas
Infrared study on the acid sites of nitrided molybdena-alumina catalysts Original Research Article
Pages 541-546
Masatoshi Nagai, Osamu Uchino, Takuya Kusagaya, Shinzo Omi
Synthesis and characterization of zirconia-alumina mixed oxides Original Research Article
Pages 547-560
F. Dumeignil, P. Blanchard, E. Payen, J. Grimblot, O. Poulet
Selective synthesis of methylcyclopentane from cyclohexane using Pt-zeolitehybrid catalyst Original Research Article
Pages 561-566
I. Nakamura, A. Zhang, K. Fujimoto
Hydrocracking activity of NiMo-USY zeolite hydrotreating catalysts Original Research Article
Pages 567-572
B. Egia, J.F. Cambra, B. Güemez, P.L. Arias, B. Pawelec, J.L.G. Fierro
Authors index
Pages 573-576
Studies in Surface Science and Catalysis
Pages 577-582