Hydrogen Effects in Catalysis: Fundamentals and Practical Applications

Cover......Page 1
Half Title......Page 2
Series Page......Page 3
Title Page......Page 6
Copyright Page......Page 7
Preface......Page 8
Contributors......Page 12
Contents......Page 16
Part I Surface Chemistry Of Hydrogen On Metals......Page 22
 1. Hydrogen Sorption on Pure Metal Surfaces......Page 24
 2. Vibrational Spectroscopy of Hydrogen Adsorbed on Metal Surfaces......Page 78
Part II Characterization Of Surface Hydrogen On Catalysts......Page 104
 3. Energetics of Hydrogen Adsorption on Porous and Supported Metals......Page 106
 4. Hydrogen as a Tool for Characterization of Catalyst Surfaces by Chemisorption, Gas Titration, and Temperature-Programmed Techniques......Page 138
 5. Hydrogen Adsorption on Supported Cobalt, Iron, and Nickel......Page 160
 6 Neutron Scattering Studies of Hydrogen in Catalysts......Page 188
 7. Infrared Spectroscopy of Adsorbed Hydrogen......Page 204
 8. Effects of Adsorption of Hydrogen on the Magnetic and Electrical Properties of Metals......Page 216
 9. Electrochemical Investigation of Surface Hydrogen on Metal Catalysts......Page 246
Part III Hydrogen As A Partner In Producing Active Catalysts......Page 278
 10. Hydrogen Effects in Sintering of Supported Metal Catalysts......Page 280
 11. Hydrogen-Induced Sintering of Unsupported Metal Catalysts......Page 314
 12. Spillover of Hydrogen......Page 332
 13. Strong Metal-Support Interactions......Page 368
 14. Catalytic Properties of Metal Hydrides......Page 394
Part IV Hydrogen Effects In Catalytic Reactions......Page 418
 15. General Kinetics of Hydrogen Effects: Hydrocarbon Transformations over Metals as Model Reactions......Page 420
 16. Role of Hydrogen in Low- and High-Pressure Hydrocarbon Reactions......Page 446
 17. Hydrogen Effects in Skeletal Reactions of Hydrocarbons over Metal Catalysts......Page 470
 18. Hydrogen Effects in Organic Hydrogenations......Page 520
 19. Hydrogen Effects in Catalytic Transformations of Oxygenated Carbon Compounds on Metals......Page 542
 20. Role of Hydrogen in CO Hydrogenation......Page 564
 21. Effect of Hydrogen on the Activity of Oxide Catalysts......Page 586
 22. Reactivity of Hydrogen in Sulfide Catalysts......Page 604
Part V Technological Implications......Page 630
 23. Hydrogen Effects in Industrial Catalysis......Page 632
 24. Selectivity in Competitive Hydrogenation Reactions......Page 642
 25. Hydrogen and Catalytic Reforming......Page 674
 26. Metal Membranes for Hydrogen Diffusion and Catalysis......Page 700
 27. Hydrogen Transfer in Catalysis on Zeolites......Page 716
 28. Hydrogen Effects in Olefin Polymerization Catalysts......Page 744
Index......Page 768