Handbook of palladium-catalyzed organic reactions: synthetic aspects and catalytic cycles

Handbook of Palladium-Catalyzed Organic Reactions: Synthetic Aspects and Catalytic Cycles......Page 4
Copyright Page......Page 5
Table of Contents......Page 6
Foreword......Page 10
Abbreviations......Page 11
I- Introduction......Page 14
II- Graphical abstracts of reaction numbers (RXN)......Page 18
RXN1 Cross-Coupling of Organometallics with RX Derivatives......Page 36
RXN2 Cross-Coupling of Organometallics with RCOX Derivatives......Page 61
RXN3 Cross-Coupling of Siloxycyclopropanes with RX and RCOX Derivatives......Page 66
RXN4 Cross-Coupling of Terminal Alkynes with RX Derivatives......Page 68
RXN5 Intermolecular HECK Reaction......Page 74
RXN6 Intramolecular HECK Reaction......Page 85
RXN7 Intramolecular Coupling of Di(Vinyl Halides)......Page 93
RXN8 Tandem HECK-Anion Capture Process of Alkenes, Alkynes, Allenes and Dienes......Page 95
RXN9 Tandem HECK-Anion Capture Process of Norbornene and Related Compounds......Page 99
RXN10 Tandem Arylsulfonation-Cyclization Process......Page 102
RXN11 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Alkenes, Allenes and Alkynes......Page 104
RXN12 Tandem Cyclization-Anion-Capture Process of Ene-Vinyl, Ene-Aryl and Ene-Alkyl Halides......Page 108
RXN13 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Yne-Vinyl and Yne-Aryl Halides......Page 112
RXN14 Hydroarylation and Hydrovinylation of Alkenes and Alkynes......Page 115
RXN15 Reduction of Alkenes......Page 119
RXN16 Semihydrogenation of Alkynes and 1,3-Dienes......Page 121
RXN17 Hydroboration, Hydrogermylation, Hydrosilylation and Hydrostannation of Alkynes, Allenes, Dienes and Enynes......Page 123
RXN18 Hydroselenation of Alkynes......Page 126
RXN19 1,4- Disilylation of Conjugated Enones......Page 128
RXN20 Hydrocarboxylation, Hydrocarboalkoxylation and Hydrocarboamination of Alkenes and Alkynes......Page 130
RXN21 Tandem Carbonylation-Arylation with Alkynes......Page 133
RXN22 1,2-Dimetallation of Alkynes and Alkenes and Related Reactions......Page 136
RXN23 1,2-Dimetallation of Isonitriles......Page 139
RXN24 1,2-Dimetallation of Allenes or 1,3-Dienes......Page 141
RXN25 Coupling of Aryl Derivatives with Alkenes Involving a Pd(II) Catalyst......Page 144
RXN26 Homocoupling of Aryl and Vinyl Derivatives......Page 146
RXN27 Codimerization of Alkynes......Page 148
RXN28 Codimerization of Terminal Alkynes with Allenes......Page 151
RXN29 Codimerization of Alkynes and Allyl Halides......Page 153
RXN30 Cyclopropanation of Alkenes and 1,3-Dienes by Diazomethane......Page 156
RXN31 Rearrangement of α-Hydroxy Diazo Compounds......Page 158
RXN32 Substitution, Addition and Elimination on Pro-π-Allyl Substrates......Page 160
RXN33 [3,3]-Sigmatropic Rearrangement and [1,3]-Shift on Allylic Derivatives......Page 184
RXN34 1,3-Diene Monoepoxide Rearrangement......Page 188
RXN35 Ring Extension of Cyclobutane Derivatives......Page 190
RXN36 [3+2], [3+4], [3+6], [1+2] Cycloadditions......Page 193
RXN37 Intramolecular Ene-Like Reactions......Page 197
RXN38 Cyclization of Hexatrienolate Derivatives......Page 201
RXN39 Amination or Amidation of Alkenes......Page 203
RXN40 Alkoxylation of Alkenes and Alkynes......Page 205
RXN41 Acetalization of Alkenes......Page 207
RXN42 Allylic Acyloxylation of Cycloalkenes......Page 209
RXN43 Tandem Acyloxylation-Cyclization of 1,5-Dienes......Page 211
RXN44 Tandem Acyloxychlorination-Cyclization of 1,6-Dienes......Page 213
RXN45 1,4-Acyloxychlorination of 1,3-Dienes......Page 215
RXN46 1,4-Diacyloxylation of 1,3-Dienes and Related Reactions......Page 217
RXN47 Intramolecular Amination, Alkoxylation or Acyloxylation of Alkynes......Page 219
RXN48 Tandem Intramolecular Amination, Alkoxylation or Acyloxylation-Allylation of Alkynes and Allenes......Page 221
RXN49 Tandem Intramolecular Amination, Alkoxylation or Acyloxylation-Carbonylation of Alkynes......Page 223
RXN50 Intramolecular Amination or Alkoxylation of Alkenes......Page 226
RXN51 Tandem Intramolecular Amination or Alkoxylation-Carbonylation of Alkenes and Allenes......Page 229
RXN52 Reductive Cyclization with Diynes and Enynes......Page 233
RXN53 Cycloisomerization of Diynes and Enynes......Page 235
RXN54 Cycloaddition of Aziridines with Carbodiimides......Page 239
RXN55 Telomerization of 1,3-Dienes with Nucleophiles......Page 241
RXN56 WACKER Process......Page 245
RXN57 Preparation of Ketones from Alcohols or Derivatives via a β-Hydride Elimination......Page 248
RXN58 Preparation of α,β-Unsaturated Carbonyl Derivatives via a β-Hydride Elimination......Page 251
RXN59 Preparation of α-Diketones Derivatives via an Oxidative Rearrangement of a Propargyl Acetate......Page 254
RXN60 Carbonylation......Page 256
RXN61 Isomerization of Alkynes......Page 266
RXN62 Addition of Thiols to Alkynes......Page 269
RXN63 Preparation of Allylic Acetates from Alkynes by Tandem Redox-Addition......Page 271
RXN64 Tandem Cyclization-Capture Process of Enynes......Page 273
RXN65 AldoI-Like Condensation of Enol Esters with Aldehydes......Page 275
RXN66 Addition of Fluoroalkyl Iodides to Alkenes or Alkynes via a Pd(I) Species......Page 277
RXN67 Intermolecular Tandem Carbonylation-Coupling-Cyclization Process of Aryl Halides with Terminal Alkynes......Page 279
RXN68 Intramolecular Coupling of Aryl Halides with Arenes......Page 281
RXN69 Tandem Intramolecular Alkoxylation-Vinylation of Alkenes......Page 283
RXN70 Carbonylative [2+2] Cycloaddition......Page 285
RXN71 Dicarboalkoxylation of Alkenes......Page 287
RXN72 Addition of Pronucleophiles on 1,3-Dienes or Allenes......Page 289
RXN73 Tandem Cycloisomerization-Cycloaddition of Dienynes with 1,3-Dienes via Metallodienes......Page 292
RXN74 Acylcyanation of Terminal Alkynes......Page 294
RXN75 1,4-Carbochlorination......Page 296
RXN76 Tandem Chlorination-Cyclization and Tandem Chlorination-Carbonylation-Cyclization of 1,6-Enynes......Page 298
RXN77 Intramolecular Cyclocarbonylation of Alkenes......Page 301
RXN78 Tandem Carbonylation-Cyclization of (Z)-β-Iodoenones and Related Reaction from Aryl Iodides and Internal Alkynes......Page 303
RXN79 Cross-Coupling of Organometallics with Terminal Alkynes and Iodotrimethysilane......Page 305
RXN80 Preparation of αβ-Unsaturated Carbonyl Derivatives from Enol Silanes......Page 307
RXN81 1,3-Butadien-2-ylaminocyclization of Allenyl Tosylcarbamates......Page 309
RXN82 Addition of Pronucleophiles on Aldehydes......Page 311
RXN83 Allylation of Pronucleophiles with Allylstannanes......Page 314
RXN84 Cross-coupling Carbonylation of Aryl Iodides with Five-Membered Cyclic Olefins......Page 316