Green Metathesis Chemistry

Cover......Page 1
Front Matter......Page 2
Table of Contents......Page 6
Preface......Page 9
List of Contributors......Page 11
1. Recent Advances in Ruthenium Catalysts for Alkene Metathesis......Page 20
2. New N-Heterocyclic Carbene Ligands in Grubbs and Hoveyda-Grubbs Catalysts......Page 34
3. Ruthenium-Indenylidene Complexes Bearing\rSaturated N-Heterocyclic Carbenes: Synthesis\rand Application in Ring-Closing Metathesis\rReactions......Page 47
4. Building Indenylidene-Ruthenium Catalysts\rfor Metathesis Transformations......Page 55
5. The Influence of the Anionic Counter-Ion on the Activity of Ammonium Substituted\rHoveyda-Type Olefin Metathesis Catalysts\rin Aqueous Media......Page 64
6. Ruthenium Catalysts Bearing Carboxylate Ligand......Page 72
7. Ruthenium-Arene Complexes Derived from NHC·CO2 and NHC·CS2 Zwitterionic Adducts\rand Their Use in Olefin Metathesis......Page 85
8. Mono- and Bimetallic Ruthenium-Arene\rCatalysts for Olefin Metathesis: A Survey......Page 103
9. Mesoporous Molecular Sieves Based Catalysts\rfor Olefin Metathesis and Metathesis\rPolymerization......Page 115
10. Binary and Ternary Catalytic Systems\rfor Olefin Metathesis Based on MoCl5/SiO2......Page 129
11. Ring-Closing Metathesis Synthesis of Medium\rand Large Rings: Challenges and Implications\rfor Sustainable Synthesis......Page 140
12. Functionalisation of Vinylsubstituted\r(Poly)Siloxanes and Silsesquioxanes via\rCross-Metathesis and Silylative Coupling\rTransformations......Page 168
13. The Olefin Metathesis Reactions in Dendrimers......Page 183
14. Alkene Metathesis and Renewable Materials:\rSelective Transformations of Plant Oils......Page 195
15. Recent Applications of Alkene Metathesis\rin Fine Chemical Synthesis......Page 217
16. Probing the Mechanism of the Double C–H\r(De)Activation Route of a Ru-Based Olefin\rMetathesis Catalyst......Page 285
17. A Comparison of the Performance of the Semiempirical PM6 Method Versus DFT Methods in Ru-Catalyzed Olefin Metathesis......Page 291
18. Mechanism of Gold-Catalyzed\rCycloisomerization of Enynyl Esters......Page 303
19. Carbonyl-Olefin Exchange Reaction\rand Related Chemistry......Page 314
20. Activation of Cycloolefin Metathesis by Ultrasonic Irradiation......Page 324
21. Microwave-Assisted Olefin Metathesis......Page 335
22. Acyclic Diene Metathesis (ADMET)\rPolymerization of Bis(4-pentenyl)\rdimethylstannane and Bis(4-pentenyl)\rdiphenylstannane with an Electrochemically\rActivated Catalyst System......Page 367
23. A Selective Route for Synthesis of Linear\rPolydicyclopentadiene......Page 375
24.Tuning Product Selectivity in ROMP\rof Cycloolefins with W-Based Catalytic Systems......Page 388
25. [RuCl2(p-Cymene)]2 Immobilized on Mesoporous Molecular Sieves SBA-15 as Catalyst for ROMP of Norbornene......Page 396
26. Behavior of Silyl-Containing Norbornenes in the Conditions of Addition Polymerization......Page 406
27. New Applications of Ring-Opening Metathesis Polymerization for Grafting Alkylene\rOxide-Based Copolymers......Page 414
Subject Index......Page 422
Author Index......Page 429