Fluorine Chemistry for Organic Chemists

Contents......Page 10
Part I. Problems......Page 16
2. Bond Dissociation Energy of the Molecule of Fluorine......Page 18
4. Rearrangement in the Replacement of Hydroxyl by Fluorine in Saccharides......Page 19
5. Reaction of β-Dicarbonyl Compounds with Diethylaminosulfur Trifluoride......Page 20
8. Reaction of Isopropyl Alcohol with 2-Fluorocyclohexanone......Page 21
10. Reaction of Perfluoro-o-phenylenediamine with Lead Tetraacetate......Page 22
13. Addition of Hydrogen Bromide to Chlorotrifluoroethylene......Page 23
17. Chlorination of o-Fluorotoluene......Page 24
20. Reaction of 1,1-Difluoroethylene with Trifluoroacetyl Hypochlorite......Page 25
23. Reaction of Perfluoro-2-butyltetrahydrofuran with Aluminum Chloride......Page 26
26. Reaction of Sulfur Trioxide with Enol Ethers......Page 27
30. Reaction of Sulfur Trioxide with Perfluorotoluene......Page 28
34. Reaction of 1-Phenylperfluoropropene with Aluminum Chloride......Page 29
36. Hydrolysis of ω-Fluorocarboxylic Acids and Their Nitriles......Page 30
39. Reaction of 2,5-bis(Trifluoromethyl)aniline with Sodium Hydroxide......Page 31
43. Hydrolysis of Geminal Difluorides......Page 32
46. Product of Treatment of p-Trifluoromethylphenol with Potassium Hydroxide......Page 33
49. Reaction between 1-Chloro-2-fluoroethane and Ethyl Acetoacetate......Page 34
53. Reaction of Chlorotrifluoroethylene with Sodium Ethoxide......Page 35
56. Reaction of Perfluorodecalin with Sodium Thiophenoxide......Page 36
60. Reaction of Perfluorobenzotrichloride and Chlorodifluoromethane......Page 37
64. Reaction of Chlorotrifluoroethylene with Dimethylamine......Page 38
67. Reaction of 1,2-Difluorotetrachlorobenzene with Sodium Methoxide......Page 39
70. Reaction of Perfluoronaphthalene with Sodium Alkoxides or Aryloxides......Page 40
73. Acylations with Mixed Anhydrides of Trifluoroacetic Acid......Page 41
76. Reaction of Dibromodifluoromethane and tris(Dimethylamino)phosphine with Fluorinated Ketones......Page 42
79. Reaction of Ethyl Chlorofluoroacetate with Grignard Reagents......Page 43
82. Reaction of 1,2-Dichloro-1-fluoroethylene with Butyllithium and Acetone......Page 44
86. Reaction of Aldehydes with 1,1,1-Trichlotrifluororoethane and Zinc in the Presence of Aluminum Chloride......Page 45
89. Reaction of 1,1-Dichlorodifluoroethylene with 1,3-Butadiene......Page 46
93. Reaction between Hexafluoroacetone Azine and Acetylene......Page 47
96. Reaction of Alkalis with Fluorinated Cyclopropanes......Page 48
98. Reaction of 1-Bromo-2-fluorocyclohexanes with Bases......Page 49
102. The Hofmann Degradation of Perfluorobutyramide......Page 50
104. Reaction of 2-Bromoperfluoronaphthalene with Antimony Pentafluoride......Page 51
105. Claisen Rearrangement of Fluoroaromatic Acetylenic Ethers......Page 52
Part II. Solutions......Page 54
REFERENCES......Page 128
H......Page 133
R......Page 134
Z......Page 135
B......Page 136
C......Page 137
D......Page 138
E......Page 139
F......Page 140
H......Page 141
P......Page 142
T......Page 144
Y......Page 145