Engineering Chemistry

Title......Page 1
TOC......Page 3
Wave Mechanical Concept of Atom
......Page 9
Application of Schrodinger Equation
......Page 14
Probability Distribution
......Page 15
Exercises
......Page 19
2. Valency and Chemical Bonding......Page 20
Electronegativity
......Page 22
Hydrogen Bond
......Page 23
Dipole Moment
......Page 24
Chemical Bonding (Wave-Mechanical Concept)
......Page 26
VSEPR Theory and Molecular Model
......Page 33
Aromatic Character
......Page 41
Short Questions and Answers
......Page 43
Exercises
......Page 49
Radioactivity
......Page 51
Nuclear Fission
......Page 55
Nuclear Reactors
......Page 58
Uses of Radioisotopes
......Page 61
Short Questions and Answers
......Page 70
Exercises
......Page 73
4. Thermodynamics......Page 76
The First Law of Thermodynamics
......Page 78
Thermochemistry
......Page 88
Bond Energy
......Page 91
Second Law of Thermodynamics
......Page 92
Third Law of Thermodynamics
......Page 95
Short Questions and Answers
......Page 106
Exercises
......Page 108
Introduction
......Page 112
Mathematical Formulation of First Order Reaction
......Page 114
Mathematical Formulation of a Second Order Reaction
......Page 116
Third Order Reaction
......Page 119
Disturbing Factors in the Determination of an Order
......Page 124
Collision Theory
......Page 128
Solved Examples
......Page 129
Short Questions and Answers
......Page 139
Exercises
......Page 143
Definition
......Page 145
Types of Catalysis
......Page 146
Short Questions and Answers
......Page 151
Catalytic Applications of Organometallic Complexes
......Page 153
Exercises
......Page 156
Reaction Types
......Page 158
Energy Changes During the Progress of a Reaction
......Page 161
Resonance
......Page 165
Steric Hindrance
......Page 166
Isomerism
......Page 168
R.S System of Nomenclature
......Page 174
E and  Z Nomenclature
......Page 178
Short Questions and Answers
......Page 179
Exercises
......Page 190
Law of Mass Action and Ionisation
......Page 192
Acids and Bases
......Page 193
pH Scale
......Page 195
Buffer Solutions
......Page 197
Solubility Product
......Page 200
Solved Examples
......Page 203
Short Questions and Answers
......Page 205
Exercises
......Page 210
Electrolysis
......Page 212
Faraday's Laws of Electrolysis
......Page 213
Relative Speeds of Ions During Electrolysis (Transport Number)
......Page 216
Determination of Transport Number (Hittorf's Method)
......Page 218
Specific Conductance
......Page 219
Conductometric Titration
......Page 225
Solved Examples
......Page 227
Short Questions and Answers
......Page 231
Exercises
......Page 236
Electrode Potential
......Page 238
Interpretation of the Electrochemical Series
......Page 242
Latimer Diagram
......Page 243
Frost Diagram
......Page 245
Concentration Cell
......Page 247
Indicator Electrodes
......Page 250
Battery
......Page 256
Solved Examples
......Page 260
Short Questions and Answers
......Page 264
Exercises
......Page 271
Introduction
......Page 274
The Phase Rule
......Page 275
The Water System
......Page 276
Sulfur System
......Page 277
Eutectic Systems
......Page 279
Iron-Carbon Alloy System
......Page 281
Short Questions and Answers
......Page 283
Exercises
......Page 285
Classification of Colloids
......Page 286
Preparation of Colloidal Solutions
......Page 288
Purification of Colloidal Solutions
......Page 290
Properties of Colloidal Solutions
......Page 291
Coagulation of Colloids
......Page 293
Protection of Colloid
......Page 294
Application of Colloids
......Page 296
Short Questions and Answers
......Page 297
Exercises
......Page 298
Transition Metals
......Page 300
Crystal Field Theory (CFT)
......Page 311
Short Questions
......Page 314
Exercises
......Page 315
Introduction to the Study of Metals
......Page 316
Common Minerals
......Page 317
Ores
......Page 319
Fluxes
......Page 321
Furnaces
......Page 322
Powder Metallurgy
......Page 328
Some Specific Examples of Extraction of Metals
......Page 330
Exercises
......Page 334
Adhesives
......Page 337
Adhesive Strength Development
......Page 338
Technique of Bonding
......Page 339
Classification of Adhesives
......Page 341
Exercises
......Page 344
Explosives
......Page 346
Classification of Explosives
......Page 347
Manufacture of Important Explosives
......Page 351
Propellants
......Page 353
Exercises
......Page 356
Sources of Water
......Page 358
Hardness of Water
......Page 359
Sludge and Scale Formation in Boilers
......Page 360
Softening of Water
......Page 364
Cold Lime-Soda Process
......Page 365
Hot Lime-Soda Process
......Page 366
Permutit or Zeolite Process
......Page 367
Ion Exchange or Demineralization
......Page 368
Treatment of Water for Domestic Use
......Page 370
Chemical Analysis of Water
......Page 374
Short Questions and Answers
......Page 380
Exercises
......Page 383
Problems
......Page 385
Calorific Value
......Page 387
Solid Fuels
......Page 391
Liquid Fuels
......Page 398
Gaseous Fuels
......Page 407
Solved Examples
......Page 412
Short Questions and Answers
......Page 415
Exercises
......Page 420
Introduction
......Page 423
Cement
......Page 426
Glass
......Page 430
Pottery and Porcelain
......Page 435
Refractories
......Page 438
Short Questions and Answers
......Page 443
Exercises
......Page 445
Polymerization
......Page 447
Plastics (Resins)
......Page 453
Important Thermoplastics
......Page 457
Important Thermosetting Resins
......Page 461
Rubber
......Page 468
Miscellaneous Polymers
......Page 472
Short Questions and Answers
......Page 473
Exercises
......Page 476
Paints
......Page 479
Varnishes
......Page 483
Enamels and Japans
......Page 485
Short Questions and Answers
......Page 486
Exercises
......Page 488
Crystal
......Page 489
Fundamental Laws of Crystallography
......Page 490
Crystal Lattice
......Page 493
Cubic Crystals
......Page 495
Transistors (Semiconductor Triodes)
......Page 500
Elements of Band Theory
......Page 501
Conductors, Semiconductors and Insulators
......Page 504
Problems
......Page 509
Exercises
......Page 511
Types of Chromatography
......Page 512
Exercises
......Page 519
Introduction
......Page 520
Some Terms Concerning UV
......Page 521
Beer-Lambert's Law
......Page 527
Infrared Spectroscopy
......Page 530
Some IR Spectra:
......Page 533
Shielding, Deshielding and Chemical Shift
......Page 537
Mass Spectrometry
......Page 545
Short Questions and Answers
......Page 548
Exercises
......Page 555
25. Photochemistry......Page 556
Properties of the Excited States
......Page 557
Photolysis
......Page 558
Types of Photophysical Pathways
......Page 560
Photochemical Processes for Excited Molecules
......Page 562
Photosynthesis
......Page 564
Exercises
......Page 568
26. Role of Metals in Biology......Page 569
Iron
......Page 570
Zinc
......Page 571
Nickel
......Page 572
Electron Transfer
......Page 573
Electron Transport and Oxidative Phosphorylation
......Page 575
Short Questions and Answers
......Page 577
Exercises
......Page 578
Air Pollution
......Page 579
Water Pollution
......Page 587
Soil Pollution
......Page 591
Radioactive Pollution
......Page 592
Noise Pollution
......Page 593
Thermal Pollution
......Page 594
Short Questions and Answers
......Page 595
Exercises
......Page 597