Encyclopedia of Inorganic Chemistry

Actinides: Inorganic &
Coordination Chemistry......Page 2
Actinides: Organometallic
Chemistry......Page 33
Alkali Metals: Inorganic
Chemistry......Page 60
Alkali Metals:
Organometallic Chemistry......Page 84
Alkaline Earth Metals:
Inorganic Chemistry......Page 95
Alloys......Page 117
Aluminum: Inorganic
Chemistry......Page 131
Aluminum:
Organometallic Chemistry......Page 147
Ammonia & N-donor
Ligands......Page 172
Analytical Chemistry of
the Transition Elements......Page 199
Antimony: Inorganic
Chemistry......Page 211
Antimony: Organometallic
Chemistry......Page 219
Arsenic: Inorganic
Chemistry......Page 228
Arsenic: Organoarsenic
Chemistry......Page 249
Asymmetric Synthesis by Homogeneous Catalysis......Page 271
Beryllium & Magnesium:
Organometallic Chemistry......Page 294
Biomineralization......Page 321
Bismuth: Inorganic Chemistry......Page 334
Bismuth: Organometallic
Chemistry......Page 355
Bonding Energetics of
Organometallic
Compounds......Page 371
Borates: Solid-stateChemistry......Page 390
Borides: Solid-stateChemistry......Page 400
Boron Hydrides......Page 413
Boron: Inorganic
Chemistry......Page 418
Boron:
Metallacarbaboranes......Page 443
Boron–Nitrogen
Compounds......Page 465
Boron: Organoboranes......Page 481
Boron: Polyhedral
Carboranes......Page 520
Cadmium: Inorganic &
Coordination Chemistry......Page 524
Cadmium: Organometallic
Chemistry......Page 542
Calcium-binding Proteins......Page 552
Carbides: Transition Metal
Solid-state Chemistry......Page 588
Carbon: Fullerenes......Page 604
Carbon: Inorganic
Chemistry......Page 627
Carbonyl Complexes of the
Transition Metals......Page 640
Carbonylation Processes
by Homogeneous Catalysis......Page 658
Cation-activated Enzymes......Page 691
Chalcogenides: Solid-state
Chemistry......Page 700
Chlorine, Bromine, Iodine,
& Astatine: Inorganic
Chemistry......Page 739
Chromium: Biological
Relevance......Page 760
Chromium: Inorganic &
Coordination Chemistry......Page 766
Chromium:
Organometallic Chemistry......Page 780
Cobalt: B12 Enzymes &
Coenzymes......Page 798
Cobalt: Inorganic &
Coordination Chemistry......Page 818
Cobalt: Organometallic
Chemistry......Page 843
Coordination Chemistry:
History......Page 880
Coordination Numbers &
Geometries......Page 904
Coordination &
Organometallic
Chemistry: Principles......Page 916
Copper: Hemocyanin/
Tyrosinase Models......Page 932
Copper: Inorganic &
Coordination Chemistry......Page 941
Copper: Organometallic
Chemistry......Page 960
Copper Proteins with
Dinuclear Active Sites......Page 975
Copper Proteins: Oxidases......Page 990
Copper Proteins with
Type 1 Sites......Page 1016
Cyanide Complexes of the
Transition Metals......Page 1044
Cytochrome Oxidase......Page 1055
Decarbonylation Catalysis......Page 1067
Defects in Solids......Page 1073
Dielectric Polarizabilities
of Oxides & Fluorides......Page 1092
Diffraction Methods in
Inorganic Chemistry......Page 1100
Dinuclear Organometallic
Cluster Complexes......Page 1136
Dioxygen & Related
Ligands......Page 1163
Electrochemistry:
Applications in Inorganic
Chemistry......Page 1171
Electron Transfer in
Coordination Compounds......Page 1177
Electron Transfer
Reactions: Theory......Page 1199
Electronic Structure of
Clusters......Page 1214
Electronic Structure of
Main-group Compounds......Page 1234
Electronic Structure of
Organometallic
Compounds......Page 1262
Electronic Structure of
Solids......Page 1287
Fluorides: Solid-state
Chemistry......Page 1313
Fluorine: Inorganic
Chemistry......Page 1339
Gallium: Inorganic
Chemistry......Page 1364
Gallium: Organometallic
Chemistry......Page 1397
Germanium: Inorganic
Chemistry......Page 1405
Germanium:
Organometallic Chemistry......Page 1426
Gold: Inorganic &
Coordination Chemistry......Page 1449
Gold: Organometallic
Chemistry......Page 1464
Halides: Solid-state
Chemistry......Page 1475
Heterogeneous Catalysis
by Metals......Page 1495
High Pressure Synthesis of
Solids......Page 1512
Hydride Complexes of the
Transition Metals......Page 1528
Hydrides: Solid State
Transition Metal
Complexes......Page 1536
Hydroboration Catalysis......Page 1569
Hydrocyanation by
Homogeneous Catalysis......Page 1578
Hydrodesulfurization &
Hydrodenitrogenation......Page 1584
Hydrogen: Inorganic
Chemistry......Page 1601
Hydrogenation &
Isomerization of Alkenes......Page 1625
Hydrosilation Catalysis......Page 1644
Hypervalent Compounds......Page 1656
Indium: Inorganic
Chemistry......Page 1677
Indium: Organometallic
Chemistry......Page 1694
Cluster Compounds:
Inorganometallic
Compounds Containing
Transition Metal & Main
Group Elements......Page 1743
Intercalation Chemistry......Page 1764
Ionic Conductors......Page 1801
Iridium: Inorganic &
Coordination Chemistry......Page 1835
Iridium: Organometallic
Chemistry......Page 1853
Iron: Heme Proteins &
Dioxygen Transport &
Storage......Page 1871
Iron: Heme Proteins &
Electron Transport......Page 1885
Iron: Heme Proteins,
Mono- & Dioxygenases......Page 1906
Iron: Heme Proteins,
Peroxidases, Catalases &
Catalase-peroxidases......Page 1936
Iron: Inorganic &
Coordination Chemistry......Page 1957
Iron: Models of Proteins
with Dinuclear Active Sites......Page 2002
Iron: Organometallic
Chemistry......Page 2014
Iron Porphyrin Chemistry......Page 2098
Iron Proteins with
Dinuclear Active Sites......Page 2230
Iron Proteins with
Mononuclear Active Sites......Page 2245
Iron Proteins for Storage
& Transport & their
Synthetic Analogs......Page 2266
Iron–Sulfur Models of
Protein Active Sites......Page 2288
Iron–Sulfur Proteins......Page 2299
Iron Transport:
Siderophores......Page 2330
Lead: Inorganic Chemistry......Page 2357
Lead: Organometallic
Chemistry......Page 2371
Ligand Field Theory &
Spectra......Page 2380
Luminescence......Page 2400
Macrocyclic Ligands......Page 2418
Magnetic Oxides......Page 2438
Magnetism of Extended
Arrays in Inorganic Solids......Page 2473
Magnetism of Transition
Metal Ions......Page 2497
Manganese: Inorganic &
Coordination Chemistry......Page 2508
Manganese:
Organometallic Chemistry......Page 2521
Manganese: The
Oxygen-evolving Complex
&Models......Page 2537
Manganese Proteins with
Mono- & Dinuclear Sites......Page 2552
Mechanisms of Reaction of
Organometallic Complexes......Page 2563
Mercury: Inorganic &
Coordination Chemistry......Page 2583
Mercury: Organometallic
Chemistry......Page 2598
Metal Ion Toxicity......Page 2607
Metal Vapor Synthesis of
Transition Metal
Compounds......Page 2618
Metallic Materials
Deposition: Metal-organic
Precursors......Page 2629
Metalloregulation......Page 2652
Metallothioneins......Page 2668
Metathesis Polymerization
Processes by Homogeneous
Catalysis......Page 2681
Mixed Donor Ligands......Page 2692
Mixed Valence Compounds......Page 2714
Molecular Orbital Theory......Page 2727
Molybdenum: Inorganic &
Coordination Chemistry......Page 2751
Molybdenum:
MPT-containing Enzymes......Page 2779
Molybdenum:
Organometallic Chemistry......Page 2799
Mossbauer Spectroscopy......Page 2817
Nickel Enzymes &
Cofactors......Page 2844
Nickel: Inorganic &
Coordination Chemistry......Page 2860
Nickel: Models of Protein
Active Sites......Page 2892
Nickel: Organometallic
Chemistry......Page 2910
Niobium & Tantalum:
Inorganic & Coordination
Chemistry......Page 2930
Niobium & Tantalum:
Organometallic Chemistry......Page 2955
Nitrogen Monoxide (Nitric
Oxide): Bioinorganic
Chemistry......Page 2984
Nitrides: Transition Metal
Solid-state Chemistry......Page 3005
Nitrogen: Inorganic
Chemistry......Page 3022
Nitrogenase: Metal Cluster
Models......Page 3091
Nitrogenase Catalysis &
Assembly......Page 3105
Noble Gases: Inorganic
Chemistry......Page 3122
Noncrystalline Solids......Page 3141
Nucleic Acid–Metal Ion
Interactions......Page 3159
Nutritional Aspects of
Metals & Trace Elements......Page 3193
Oligomerization &
Polymerization by
Homogeneous Catalysis......Page 3201
Organic Synthesis using
Transition Metal Carbonyl
Complexes......Page 3217
Organic Synthesis using
Transition Metal
Complexes Containing
π-Bonded Ligands......Page 3282
Osmium: Inorganic &
Coordination Chemistry......Page 3337
Osmium: Organometallic
Chemistry......Page 3361
Oxidation Catalysis by
Transition Metal
Complexes......Page 3379
Oxide Catalysts in
Solid-state Chemistry......Page 3385
Oxides: Solid-state
Chemistry......Page 3406
Oxygen: Inorganic
Chemistry......Page 3454
P-donor Ligands......Page 3500
Palladium: Inorganic &
Coordination Chemistry......Page 3527
Palladium: Organometallic
Chemistry......Page 3547
Paramagnetic
Organometallic Complexes......Page 3588
Peptide–Metal Interactions......Page 3600
Periodic Table: Trends in
the Properties of the
Elements......Page 3614
Phosphates: Solid-state
Chemistry......Page 3628
Phosphides: Solid-state
Chemistry......Page 3644
Phosphorus: Inorganic
Chemistry......Page 3697
Phosphorus–Nitrogen
Compounds......Page 3718
Phosphorus:
Organophosphorus
Chemistry......Page 3745
Photochemistry of
Transition Metal
Complexes......Page 3763
Photochemistry of
Transition Metal
Complexes: Theory......Page 3808
Photoelectron
Spectroscopy of Transition
Metal Systems......Page 3823
Photosynthesis......Page 3851
Platinum-based Anticancer
Drugs......Page 3879
Platinum: Inorganic &
Coordination Chemistry......Page 3890
Platinum: Organometallic
Chemistry......Page 3899
Polonium: Inorganic
Chemistry......Page 3935
Polonium: Organometallic
Chemistry......Page 3943
Polyhedra......Page 3946
Polynuclear
Organometallic Cluster
Complexes......Page 3950
Polyoxometalates......Page 3967
Polyphosphazenes......Page 3978
Polysiloxanes & Polysilanes......Page 3985
Quasicrystals......Page 4003
Rhenium: Organometallic
Chemistry......Page 4006
Rhodium: Inorganic &
Coordination Chemistry......Page 4053
Rhodium: Organometallic
Chemistry......Page 4083
Ruthenium: Inorganic &
Coordination Chemistry......Page 4118
Ruthenium:
Organometallic Chemistry......Page 4140
S-donor Ligands......Page 4172
Scandium, Yttrium & the
Lanthanides: Inorganic &
Coordination Chemistry......Page 4199
Scandium, Yttrium & the
Lanthanides:
Organometallic Chemistry......Page 4239
Selenium: Inorganic
Chemistry......Page 4292
Selenium: Organoselenium
Chemistry......Page 4316
Selenium Proteins
Containing Selenocysteine......Page 4331
Semiconductor Interfaces......Page 4341
Semiconductors......Page 4358
Short-lived Intermediates......Page 4374
Silicon: Inorganic
Chemistry......Page 4404
Silicon: Organosilicon
Chemistry......Page 4453
Silver: Inorganic &
Coordination Chemistry......Page 4483
Silver: Organometallic
Chemistry......Page 4493
Sol–Gel Synthesis of Solids......Page 4500
Solids: Characterization by
Powder Diffraction......Page 4511
Solids: Computer
Modeling......Page 4529
Stability Constants & their
Determination......Page 4546
Stereochemical Nonrigidity
of Organometallic
Complexes......Page 4555
Structure & Property
Maps for Inorganic Solids......Page 4589
Sulfur: Inorganic
Chemistry......Page 4608
Sulfur–Nitrogen
Compounds......Page 4644
Sulfur: Organic
Polysulfanes......Page 4670
Superconductivity......Page 4704
Supported
Organotransition Metal
Compounds......Page 4717
Surfaces......Page 4727
Symmetry Point Groups......Page 4752
Technetium & Rhenium:
Inorganic & Coordination
Chemistry......Page 4756
Technetium:
Organometallic Chemistry......Page 4773
Tellurium: Inorganic
Chemistry......Page 4783
Tellurium:
Organotellurium
Chemistry......Page 4806
Thallium: Inorganic
Chemistry......Page 4824
Thallium: Organometallic
Chemistry......Page 4836
Thin Film Synthesis of
Solids......Page 4849
Tin: Inorganic Chemistry......Page 4857
Tin: Organometallic
Chemistry......Page 4872
Titanium: Inorganic &
Coordination Chemistry......Page 4901
Titanium: Organometallic
Chemistry......Page 4912
Transition Metal
Carbonyls: Infrared
Spectra......Page 4942
Tungsten: Inorganic &
Coordination Chemistry......Page 4957
Tungsten: Organometallic
Chemistry......Page 4982
Tungsten Proteins......Page 5003
Vanadium in Biology......Page 5011
Vanadium: Inorganic &
Coordination Chemistry......Page 5023
Vanadium:
Organometallic Chemistry......Page 5040
Water & O-donor Ligands......Page 5060
Zeolites......Page 5078
Zinc: DNA-binding
Proteins......Page 5114
Zinc Enzymes......Page 5132
Zinc: Inorganic &
Coordination Chemistry......Page 5175
Zinc: Organometallic
Chemistry......Page 5201
Zintl Compounds......Page 5254
Zirconium & Hafnium:
Inorganic & Coordination
Chemistry......Page 5263
Zirconium & Hafnium:
Organometallic Chemistry......Page 5287
Alkaline Earth Metals:
Organometallic Chemistry......Page 5325
Biomimetic Synthesis of
Nanoparticles......Page 5356
Bond Lengths in Inorganic
Solids & Liquids......Page 5377
Metal-related Diseases of
Genetic Origin......Page 5384
Hard & Soft Acids and
Bases......Page 5398
Long-range Electron
Transfer in Biology......Page 5403
Luminescence Behavior &
Photochemistry of
Organotransition Metal
Compounds......Page 5415
Metal-based Drugs......Page 5446
Metal-based Imaging
Agents......Page 5475
Metal-mediated Protein
Modification......Page 5495
Metallocenter Biosynthesis
& Assembly......Page 5508
Metallochaperones &
Metal Ion Homeostasis......Page 5516
Metalloprotein Design &
Engineering......Page 5523
Multi-Heme Cytochromes
& Enzymes......Page 5557
Semiconductor
Nanocrystal Quantum Dots......Page 5574
Organic Synthesis Using
Metal-mediated Metathesis
Reactions......Page 5596
Organic Synthesis Using
Metal-mediated Coupling
Reactions......Page 5641
Porous Inorganic Materials......Page 5661
Self-assembled Inorganic
Architectures......Page 5682
Periodic Table: Historical
Aspects......Page 5727
Hydrogen Bonding &
Dihydrogen Bonding......Page 5737
Dihydrogen Complexes &
Related Sigma Complexes......Page 5742
Carbon–Carbon &
Carbon–Heteroatom
Activation......Page 5748
Carbene Complexes......Page 5754
Low Coordinated Group
13 Chelates......Page 5762
Main Group Carbenes......Page 5766
Main Group: Multiple
Bonding......Page 5785
Copper Proteins with
Type 2 Sites......Page 5792
Copper Enzymes in
Denitrification......Page 5817
Beryllium: Inorganic
Chemistry......Page 5828
Low Oxidation State Main
Group......Page 5834
Alkane Carbon–Hydrogen
Bond Activation......Page 5846
Transition Metal
Complexes with Bulky
Allyl Ligands......Page 5853
Subvalent Compounds......Page 5859
Group 14 Multiple
Bonding......Page 5877
Sol–Gel Encapsulation of
Metal and Semiconductor
Nanocrystals......Page 5918
Metal Nanoparticles,
Synthesis of......Page 5927
Metal Nanoparticles,
Organization &
Applications of......Page 5941
Carbon: Nanotubes......Page 5959
Inorganic Ring Systems......Page 5993
High-Energy Electron Diffraction......Page 6021
High Resolution Electron Energy-Loss Spectroscopy......Page 6048
Magnetic Circular Dichroism (MCD) Spectroscopy......Page 6066
Metal Analysis......Page 6082
Microwave Rotational Spectroscopy......Page 6103
Neutron Diffraction......Page 6119
Neutron Scattering......Page 6138
Nuclear Magnetic Resonance (NMR) Spectroscopy of
Inorganic/Organometallic Molecules......Page 6161
Nuclear Magnetic Resonance (NMR) Spectroscopy of
Metallobiomolecules......Page 6202
Nuclear Quadrupole Resonance (NQR) Spectroscopy......Page 6230
Nuclear Resonance Vibrational Spectroscopy (NRVS)......Page 6245
Perturbed Angular Correlations of γ -rays (PAC)
Spectroscopy......Page 6266
Photoelectron Spectroscopy......Page 6283
Photoluminescence and Electroluminescence, Solid State......Page 6302
Rapid Scan, Stopped-Flow Kinetics......Page 6310
Resonance Raman
Spectroscopy......Page 6329
Vibrational Spectroscopy......Page 6366
X-Ray Absorption Spectroscopy......Page 6390
X-Ray Powder Diffraction......Page 6406
Circular Dichroism (CD) Spectroscopy......Page 6437
Electrochemistry......Page 6453
Electron Paramagnetic Resonance (EPR) Spectroscopy......Page 6475
Electron Spin Echo Envelope Modulation (ESEEM)
Spectroscopy......Page 6491
Electronic Spectroscopy......Page 6514
Electron-Nuclear Double Resonance (ENDOR)
Spectroscopy......Page 6534
Freeze-Quench Kinetics......Page 6560
Gold in Homogeneous
Catalysis......Page 6578
N-Heterocyclic
Carbene-Containing Metal
Complexes......Page 6616