Efficient Preparations of Fluorine Compounds

دسته بندی: شیمی ارگانیک
ویرایش:  
 
سری:  
ISBN (شابک) : 9781118078563, 9781118409466 
ناشر:  
سال نشر: 2012 
تعداد صفحات: 479 
زبان: English 
فرمت فایل : PDF (درصورت درخواست کاربر به PDF، EPUB یا AZW3 تبدیل می شود) 
حجم فایل: 24 مگابایت 

قیمت کتاب (تومان) : 47,000

The definitive guide to creating fluorine-based compounds?and the materials of tomorrow

Discovered as an element by the French chemist Henri Moissan in 1886, through electrolysis of potassium fluoride in anhydrous hydrogen fluoride?"le fluor," or fluorine, began its chemical history as a substance both elusive and dangerous. With a slight pale yellow hue, fluorine is at room temperature a poisonous diatomic gas. Resembling a spirit from a chemical netherworld, fluorine is highly reactive, difficult to handle, yet very versatile as a reagent?with the power to form compounds with almost any other element.

Comprising 20% of pharmaceutical products and 30% of agrochemical compounds, as well as playing a key role in electric cars, electronic devices, and space technology, compounds containing fluorine have grown in importance across the globe. Learning how to safely handle fluorine in the preparation of innovative new materials?with valuable new properties?is of critical importance to chemists today. Bringing together the research and methods of leading scientists in the fluorine field, Efficient Preparations of Fluorine Compounds is the definitive manual to creating, and understanding the reaction mechanisms integral to a wide variety of fluorine compounds. With sixty-eight contributed chapters, the book's extensive coverage includes:

• Preparation of Elemental Fluorine
• Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications
• Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions
• Direct Fluorination of Organic Compounds with Elemental Fluorine
• Efficient Preparations of Bioorganic Fluorine Compounds
• Asymmetric Fluorocyclization Reactions
• Preparations of Rare Earth Fluorosulfides and Oxyfluorosulfides

The book offers methods and results that can be reproduced by students involved in advanced studies, as well as practicing chemists, pharmaceutical scientists, biologists, and environmental researchers. The only chemical resource of its kind, Efficient Preparations of Fluorine Compounds?from its first experiment to its last?is a unique window into the centuries old science of fluorine and the limitless universe of fluorine-based compounds.

Content:
Chapter 1 Preparation of Elemental Fluorine (pages 1–6): Karl O. Christe
Chapter 2 Preparation of Highly Active Cesium Fluoride (pages 7–8): Konrad Seppelt
Chapter 3 Preparation of Highly Active Silver Fluoride (pages 9–10): Konrad Seppelt
Chapter 4 A Room?Temperature Non?Irradiative Synthesis of XeF2 (pages 11–15): Ulf Breddemann, John R. Debackere and Gary J. Schrobilgen
Chapter 5 Efficient Perfluorination of K2B12H12 in Neutral Acetonitrile (pages 16–18): Dmitry V. Peryshkov, Eric V. Bukovsky and Steven H. Strauss
Chapter 6 Efficient Preparation of the Highly Soluble ortho? and para?C60(CF2C6F5)2 Derivatives (pages 19–21): Igor V. Kuvychko, Bryon W. Larson, Steven H. Strauss and Olga V. Boltalina
Chapter 7 Synthesis of Cs[1?H?CB11F11] (pages 22–25): Michal Valasek, Filip sembera, Michael J. Hughes, Ivan Stibor, Zbynek Janousek and Josef Michl
Chapter 8 Synthesis of Zero?Valent Trifluoromethyl Chalcogenato Derivatives, [NMe4]ECF3 (E = S, Se, Te), and Related Compounds (pages 26–34): Wieland Tyrra and Silke Kremer
Chapter 9 Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications (pages 35–59): Dayal T. Meshri, N. C. Mathur and Ritesh R. Jain
Chapter 10 Tris(pentafluorophenyl)borane, B(C6F5)3, a Powerful, Well?Soluble, Nonoxidizing Lewis Acid and the Weakly Coordinating Tetrakis(pentafluorophenyl)borate Anion, [B(C6F5)4]? (pages 60–64): Hermann?Josef Frohn
Chapter 11 Pentafluorophenyldifluoroborane, C6F5BF2, and Pentafluorophenyltrifluorosilane, C6F5SiF3, Versatile Reagents for Fluorine/Pentafluorophenyl Substitution Reactions in Strongly Oxidizing Hypervalent Nonmetal Fluorides (pages 65–71): Hermann?Josef Frohn
Chapter 12 Iodine(III and V) Fluorides: Interesting Fluorinating Agents (pages 72–75): Hermann?Josef Frohn
Chapter 13 Tetramethylammonium Fluoride, [N(CH3)4]F, a Widely Applicable Reagent to Introduce Fluoride Ions and a Suitable Nucleophile to Initiate the Transfer of Perfluoroorganyl Groups to Electrophiles (pages 76–78): Hermann?Josef Frohn
Chapter 14 Preparation of Transition Metal Sulfide Fluorides (pages 79–81): Michael Gerken
Chapter 15 Transition Metal Carbonyl Sulfur Dioxide and Thiazylfluoride Complexes: Reactions at the Metal Center and at the Ligand (pages 82–87): Rudiger Mews
Chapter 16 Cesium, Mercury, and Silver Salts with Sulfur–Nitrogen–Fluorine Anions: Useful Transfer Reagents for NSF Building Blocks (pages 88–93): Rudiger Mews
Chapter 17 Laboratory?Scale Synthesis of Gold Trifluoride and Uranium Hexafluoride (pages 94–99): Thomas M. Klapotke
Chapter 18 Preparation of Transition Metal Fluorides using ClF3 (pages 100–107): Ralf Haiges
Chapter 19 Preparation of Fluorine?Containing Molecular Halides and Heteropolar Salts with Elements of Group 15 and Niobium and Tantalum Halides (pages 108–116): Lothar Kolditz
Chapter 20 Fluoro and Fluorohydroxy Complexes of As, Sb, and Sn (pages 117–120): Lothar Kolditz
Chapter 21 Trifluoromethyl Compounds via Electrophilic and Nucleophilic Reactions (pages 121–126): Jean'ne M. Shreeve
Chapter 22 Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions (pages 127–132): Jean'ne M. Shreeve
Chapter 23 The “Real” Iodine and Bromine Monofluorides (pages 133–138): Shlomo Rozen
Chapter 24 The Versatile Chemistry of Acetyl Hypofluorite: The First Hypofluorite Not Bonded to a Polyhaloalkyl Group (pages 139–145): Shlomo Rozen
Chapter 25 Direct Fluorination of Organic Compounds with Elemental Fluorine (pages 146–153): Shlomo Rozen
Chapter 26 The Surprising Chemistry of Bromine Trifluoride (pages 154–172): Shlomo Rozen
Chapter 27 Preparation of Silicon? and Sulfur?Based Fluorinated Methane Derivatives as Versatile Fluoromethylation Reagents (pages 173–204): G. K. Surya Prakash and Fang Wang
Chapter 28 Pentafluoroethyl Lithium: Reactions with Carbonyl Compounds and Epoxides (pages 205–209): Olesya Kazakova and Gerd?Volker Roschenthaler
Chapter 29 Synthesis of ??Hydroxy??,??difluoromethylenephosphonates (pages 210–213): Olesya Kazakova and Gerd?Volker Roschenthaler
Chapter 30 Synthesis of Pentafluoro??6?sulfanyl?Substituted Acetylenes for Liquid Crystals (pages 214–219): Olesya Kazakova, Maxim Ponomarenko and Gerd?Volker Roschenthaler
Chapter 31 Delocalized Lipophilic Cations as a Source of Naked Fluoride and Phase?Transfer Catalysts (pages 220–226): Nataliya Kalinovich, Olesya Kazakova and Gerd?Volker Roschenthaler
Chapter 32 Methyltrifluoropyruvate Imines Possessing N?oxalyl and N?Phosphonoformyl Groups: Precursors to a Variety of ??CF3???Amino Acid Derivatives (pages 227–231): Olesya Kazakova and Gerd?Volker Roschenthaler
Chapter 33 Rhodium?Mediated Synthesis of (3,3,3?Trifluoropropyl)trimethoxysilane and (3,3,3?Trifluoropropyl)triphenylsilane (pages 232–234): Falk Wehmeier and Thomas Braun
Chapter 34 Rhodium?Mediated Synthesis of a Tetrafluoropyridyl?2?boronate Ester (pages 235–236): Michael Teltewskoi and Thomas Braun
Chapter 35 Palladium?Mediated Synthesis of 4?Vinyltetrafluoropyridine and 2,3,5,6?Tetrafluoropyridine (pages 237–239): David Breyer and Thomas Braun
Chapter 36 Preparation of Polyfluoroaryl?1,2?difluorovinylsilanes (pages 240–242): Donald J. Burton and Ba V. Nguyen
Chapter 37 Preparation of (Z)?2?iodo?1,2?Difluorostyrenes (pages 243–245): Donald J. Burton and Ling Xue
Chapter 38 Preparation of 1,4?Bis(Z?2?iodo?1,2?difluoroethenyl)benzene (pages 246–247): Donald J. Burton and Craig A. Wesolowski
Chapter 39 Stereospecific Carboamidation Route to (Z)?N?Phenyl?2,3?difluoro?3?(triethylsilyl) acrylamide (pages 248–249): Donald J. Burton and Craig A. Wesolowski
Chapter 40 Preparation of 2?Trifluoromethyl?3,3,3?trifluoropropanal (pages 250–251): Donald J. Burton and Donald A. Wiebe
Chapter 41 Synthesis of Tetrafluorocatechol (pages 252–255): Sudharsanam Ramanathan, Dayong Sang, Vivek Kumar and David M. Lemal
Chapter 42 Preparation of an Unsymmetrical Bis((perfluoroalkyl)sulfonyl)imide (pages 256–261): Darryl D. DesMarteau and Thomas D. Hickman
Chapter 43 Preparation of Perfluoroalkyl Sulfilimines and Sulfoximines (pages 262–265): Emmanuel Magnier
Chapter 44 Preparation of Trifluoromethylsulfonium Salts (pages 266–269): Emmanuel Magnier
Chapter 45 Preparation of Organometallic Fluorides of Main Group and Transition Elements (pages 270–274): Herbert W. Roesky
Chapter 46 Preparation of Pentafluorosulfanyl Carbonyl Compounds (pages 275–278): John T. Welch
Chapter 47 Preparation of Power?Variable Electrophilic Trifluoromethylating Agents, S?(Trifluoromethyl)dibenzothiophenium Salts Series (pages 279–289): Teruo Umemoto
Chapter 48 Synthesis of Fluorine?Containing Heterocycles from ?,??Dihydropolyfluoroalkylsulfides and Fluorinated Thiocarboxylic Acids Derivatives (pages 290–307): Vadim M. Timoshemko and Yuriy G. Shermolovich
Chapter 49 Synthesis of Octafluorocyclooctatetraene (pages 308–314): John M. Buzby, Aldos C. Barefoot, Michael W. Grayston, Evan D. Laganis, Roy F. Waldron and David M. Lemal
Chapter 50 Preparation of Fluoroolefins (pages 315–333): Moritz F. Kuehnel and Dieter Lentz
Chapter 51 Preparation of Ionic Liquids of Fluorocomplex and Oxofluorocomplex Anions by Fluoroacid–Base Reactions (pages 334–337): Kazuhiko Matsumoto and Rika Hagiwara
Chapter 52 Synthesis of Difluorocyclopropyl Building Blocks: 2,2?Difluorocyclopropylmethanol and 2?(Bromomethyl)?1,1?difluorocyclopropane (pages 338–342): Wei Xu and William R. Dolbier
Chapter 53 Preparation of 1,1,2,2,9,9,10,10?Octafluoro[2.2]paracyclophane and Perfluoro[2.2]paracyclophane (pages 343–348): William R. Dolbier, Jian?Xi Duan, Alex J. Roche and Lianhao Zhang
Chapter 54 Synthesis and Application of gem?Difluoromethylenated and Trifluoromethylated Building Blocks (pages 349–364): Feng?Ling Qing and Xiao?Long Qiu
Chapter 55 1,3?Dipolar Cycloaddition Reactions to Fluoroalkenes (pages 365–369): Hanna Wojtowicz?Rajchel and Henryk Koroniak
Chapter 56 Synthesis of Fluorinated Vinyl Derivatives of Nucleic Acid Bases (pages 370–374): Hanna Wojtowicz?Rajchel, Donata Pluskota?Karwatka and Henryk Koroniak
Chapter 57 Synthesis of CF3?Substituted Aziridine Ring by the Gabriel Reaction (pages 375–378): Tomasz Cytlak, Bartosz Marciniak and Henryk Koroniak
Chapter 58 Preparation of ??Fluoro Amino and ??Fluoro Enamino Reagents (pages 379–384): Justyna Walkowiak and Henryk Koroniak
Chapter 59 Synthesis of Original Fluoromonomers and Their Radical Copolymerization with Vinylidene Fluoride (pages 385–395): Bruno Ameduri
Chapter 60 Convergent 18F Radiosynthesis (pages 396–399): V. Gouverneur and O. Lozano
Chapter 61 Asymmetric Fluorocyclization Reactions (pages 400–404): V. Gouverneur and O. Lozano
Chapter 62 Preparation of Allylic Fluorides (pages 405–411): V. Gouverneur and O. Lozano
Chapter 63 Dehydroxyfluorinations of Primary or Secondary Alcohols Using Perfluoro n?Butylsulfonyl Fluoride (Nonaflyl Fluoride) in Combination with 1,8?Diaza?bicyclo[5.4.0]undec?7?ene (pages 412–414): Orlin Petrov, Matthias Schneider, Rolf Bohlmann, Stephan Vettel and Helmut Vorbruggen
Chapter 64 Preparation of Rare Earth Fluorosulfides and Oxyfluorosulfides (pages 415–424): A. Demourgues and A. Tressaud
Chapter 65 Preparation of Carbon–Fluorine Compounds and Fluoride or Oxide Fluoride?Intercalated Graphites (pages 425–432): Tsuyoshi Nakajima
Chapter 66 Safe Synthesis of Superstoichiometric Mesoporous Fluorocarbons (pages 433–441): Valentin N. Mitkin
Chapter 67 Preparation of Fluorinated ??Alumina (pages 442–446): Erhard Kemnitz, Tomaz Skapin and John M. Winfield
Chapter 68 High?Yield Synthesis of a Single Asymmetric Isomer of C70(CF3)10 by High?Temperature Radical Trifluoromethylation (pages 447–449): Natalia B. Shustova, Steven H. Strauss and Olga V. Boltalina