Dioxygen Activation and Homogeneous Catalytic Oxidation, Proceedings of the Fourth International Symposium on Dioxygen Activation and Homogeneous Catalytic Oxidation

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Page iii

Copyright page
Page iv

Preface
Page v
László I. Simándi

International Advisory Board and Organizing Committee
Page xiii

Sponsors
Page xiv

The Selective Functionalisation of Saturated Hydrocarbons. Gif and All That Original Research Article
Pages 1-10
Derek H.R. Barton, Darío Doller

Catalytic oxidation of hydrocarbons. New approaches Original Research Article
Pages 11-19
A.E. Shilov

Studies of Mechanism in Thermal and Photochemical Alkane Functionalization Reactions Catalyzed by Oxidatively Resistant Metalloporphyrin Analogues (IMAs) and Isopolytungstates Original Research Article
Pages 21-29
C.L. Hill, R.F. Renneke, M. Faraj

Selective functionalisation of saturated hydrocarbons by oxo ruthenium complexes Original Research Article
Pages 31-45
M.M. Taqui Khan

Over-Oxidation of Cyclohexane by the Gif System in an Atmosphere of Pure Oxygen Original Research Article
Pages 47-54
U. Schuchardt, E.V. Spinacé, V. Mano

Selective Oxidation of some Hydrocarbons Original Research Article
Pages 55-64
Kyu Wan Lee, Kyung Yun Choi, Ki Won Jun, D.H.R. Barton

Oxidation of a methyl group in 2, 3-dihydro-2, 2, 4-trimethyl-1H-1, 5-benzodiazepine by o2 in the presence of metal ions Original Research Article
Pages 65-69
Z. Szeverényl, L.I. Simándi

A perspective of catalytic oxidation Original Research Article
Pages 71-81
G. Read

The Activation of Molecular Oxygen by Transition Metal Complexes Original Research Article
Pages 83-91
Russell S. Drago

Cobalt-Schiff Base Complex Promoted Oxygenation of Alkynes Original Research Article
Pages 93-102
Akira Nishinaga, Kazushige Maruyama, Takahiro Mashino, Kohei Yoda, Hiromitsu Okamoto

Nitrate-and Nitrite-Ligands as Mediators in Palladium-Catalyzed Oxidation of Olefins Original Research Article
Pages 103-112
V.A. Likholobov

Metalloporphyrin - Catalyzed Epoxidation of Propylene Original Research Article
Pages 113-120
R. Iwanejko, P. Leduc, T. Mlodnicka, J. Poltowicz

Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations Original Research Article
Pages 121-127
R. Neumann, M. Levin

Ruthenium catalyzed oxidation of nitrogen-containing heteroaromatic compounds Original Research Article
Pages 129-136
T. Hara, M. Horii

Oxidation of Naphhthalene on Palladium Based Catalyst Original Research Article
Pages 137-145
Kazuo Sasaki, Atsutaka Kunai, Yasushi Kuroda, Tomoyuki Kitano

Selective Oxidation of Alcohols by Dioxiranes Original Research Article
Pages 147-154
R. Curci, M. Fiorentino, C. Fusco, R. Mello

Oxidation of Alcohols by Ruthenium(II)-Complexes Original Research Article
Pages 155-161
Mario Bressan, Mario Mengarda, Antonino Morvillo

On The Mechanism of Ironporphyrin-Catalyzed Aerobic Carbon-Carbon Bond Cleavage of Vic-Diols in the Presence of Nad (P) H Model Compounds Original Research Article
Pages 163-170
Ken Sasaki, Masahiko Tachiban, Akira Murakawa, Masami Nakano, Mutuji Sakai, Yasumasa Sakakibara, Tadashi Okamoto

Cobalt phthalocyanine catalysis in autoxidation of 2-aminophenol by O2 Original Research Article
Pages 171-178
Z. Szeverényi, E.R. Milaeva, L.I. Simándi

Cobalt Complex with 2.2′-Bipyridyl Immobilized on Disperse Silica Surface in the Reaction of P-Hydroquinone Oxidation. Comparison of the Homogeneous and Heterogeneous Catalysis Results Original Research Article
Pages 179-188
T.N. Yakubovich, N.I. Ermokhina, Y.I. Bratushko, Y.L. Zub, A.A. Chuiko

The Copper(II)–Catalysed Autoxidation of Catechol in Aqueous Solution Original Research Article
Pages 189-194
József Balla, Tamás Kiss

Selective oxidations with dioxygen catalyzed by ruthenium and rhodium complexes Original Research Article
Pages 195-212
Brian R. James

Transformation of Fe(III)TMP N-Oxide to a Two Electron Oxidized Equivalent of Fe(III)TM P Complex Original Research Article
Pages 213-220
Yoshihito Watanabe, Katsuomi Takehira, Masao Shimizu, Takashi Hayakawa, Hideo Orita, Masahiro Kaise

Electroassisted Oxidation of Cis-Cyclooctene and Adamantane by Molecular Oxygen Catalyzed by Polypyrrole Manganese Porphyrin Films Original Research Article
Pages 221-228
F. Bedioui, S. Gutierrez Granados, L. Gaillon, C. Bied-Charreton, J. Devynck

Enhanced Electronic Delocalization in Face-to-Face Diporphyrins. Implication in the Unique Reactivity of the Cobalt Derivatives Towards Dioxygen and in the 4-Electron Reduction Mechanism of O2 Original Research Article
Pages 229-235
Y. Le Mest, M. L'her, J.P. Collman

Biomimetic Binding and Activation of Dioxygen with Copper Complexes Original Research Article
Pages 237-248
Zoltán Tyeklár, Kenneth D. Karlin

Kinetics and thermodynamics of dioxygen interaction with copper Original Research Article
Pages 249-257
A.D. Zuberbühler

Preparation and Reactions of μ-Peroxo Complexes of Copper and Iron as Models for Tyrosinase and Methane Monooxygenase Original Research Article
Pages 259-268
Nobumasa Kitajima, Yoshihiko Moro-Oka

Quercetin 2,3-dioxygenase Mimicking Chemistry Original Research Article
Pages 269-278
Gábor Speier

Novel Oxidation of Phenols by a Copper(II) Complex Catalyst/O2 System Original Research Article
Pages 279-284
K. Takehira, M. Shimizu, Y. Watanabe, T. Hayakawa, H. Orita

Iron- and cobalt-induced activation of HOOH and of dioxygen for the ketonization of methylenic carbons, the dioxygenation of arylolefins and catechols, and the monooxygenation of hydrocarbons Original Research Article
Pages 285-296
Donald T. Sawyer, Ceshing Sheu, Hui-Chan Tung, Andrzej Sobkowiak

Reaction of Iron(Iii) Tetra(4-N-Methylpyridyl)Porphyrin with Tertiary-Butyl Hydroperoxide in Aqueous Solution Original Research Article
Pages 297-303
M.J. Davies, R.E. Gammon, J.R. Lindsay Smith, R.J. Lower

Heme-Hydrogen Peroxide Complex Formation as Studied by ESR and Optical Spectroscopy Original Research Article
Pages 305-311
Kunihiko Tajima, Masato Shigematsu, Junichi Jinno, Kazuhiko Ishizu, Hiroaki Ohya-Nishiguchi

The Role of Threonine 252 in the Oxygen Activation by Cytochrome P-450 cam: Mechanistic Studies by Site-directed Mutagenesis Original Research Article
Pages 313-319
Hideo Shimada, Yoshihito Watanabe, Michiyo Imai, Ryu Makino, Hideo Koga, Tadao Horiuchi, Yuzuru Ishimura

EPR and Optical Studies on Non-heme Iron, Substrate and Dioxygen Ternary Complexes in the Catechol Dioxygenase Model Reaction Systems Original Research Article
Pages 321-329
Satoshi Fujii, Hiroaki Ohya-Nishiguchi, Noboru Hirota

Binding and Activation of Molecular Oxygen Within the Cavity of the Dinuclear Cobalt Bisdien Macrocyclic Complex; Reactions with Bridging Coordinated Bifunctional Reducing Substrates Original Research Article
Pages 331-336
Arthur E. Martell, Ramunas J. Motekaitis

Interaction of Molecular Oxygen with Transition Metal Centers in Electrocatalytic Synthesis of Peroxo Species Original Research Article
Pages 337-346
G. Costa, C. Tavagnacco, G. Balducci, Rakesh Kumar

A Study of the Intermediate of Catechol Dioxygenase Model Reaction by Co(III)tetramine Complexes and Catechols Original Research Article
Pages 347-356
Satoru Nakashima, Hiroaki Ohya-Nishiguchi, Noboru Hirota, Sei Tsuboyama, Tamiko Chijimatsu

Electronic-Structural Correlations of Dioxygen Binding and Activation by Binuclear Copper and Cobalt Complexes Original Research Article
Pages 357-366
Edward I. Solomon, Michael J. Baldwin, Paul K. Ross, Felix Tuczek

Intramolecular reactivity of oxo-alkyl complexes of molybdenum and tungsten Original Research Article
Pages 367-374
Henri Arzoumanian, Heinz Krentzien, Helena Teruel

Oxidation of alcohols and diols by peroxometal complexes Original Research Article
Pages 375-384
S. Campestrini, F. Di Furia, G. Modena, F. Novello

Titanium-Promoted Enantioselective Oxidation of Thioethers and Synthetic Applications Original Research Article
Pages 385-394
V. Conte, F. Di Furia, G. Licini, G. Modena, G. Sbampato

Ruthenium and Osmium Carboxylato Oxo Complexes as Organic Oxidants Original Research Article
Pages 395-400
W.P. Griffith, J.M. Jolliffe

Reactivity of organopalladium compounds towards early transition metal peroxides: O-insertion vs. C-X-coupling Original Research Article
Pages 401-403
P.L. Alsters, H.T. Teunissen, J. Boersma, G. van Koten

Lactonization of Cyclic Ketones with Hydrogen Peroxide Catalyzed by Platinum(II) Complexes Original Research Article
Pages 405-410
M. Del Todesco Frisone, R. Giovanetti, F. Pinna, G. Strukul

A Novel Oxidation of Internal Alkynes with Hydrogen Peroxide Catalyzed by Peroxotungstophosphates Original Research Article
Pages 411-416
Yasutaka Ishii, Yasuyuki Sakata

The mechanism of catalytic chemiluminescence of luminol Original Research Article
Pages 417-427
H. Ojima, K. Nonoyama

Thermal and photochemical catalysis by polyoxometallates Regeneration of catalyst by dioxygen Original Research Article
Pages 429-435
A. Hiskia, E. Papaconstantinou

Epoxidation of Cyclohexene Catalysed by Oxoperoxome Tallates under Phase-Transfer Conditions Original Research Article
Pages 437-443
László J. Csányi, Károly Jáky

Structure and Reactivity of Fe(III)TPP-Oxygen-Skatole Ternary Complex in Tryptophan Dioxygenase Model Reaction System Original Research Article
Pages 445-453
Kunihiko Tajima, Miwa Yoshino, Takeshi Edo, Kazuhiko Ishizu, Hiroaki Ohya-Nishiguchi

Hydroxylation of Phenol Catalyzed by Metal Phthalocyanines Original Research Article
Pages 455-460
Y. Masri, M. Hronec

Phthalocyanine Derivatives as Catalysts for Soft Peroxidative Oxidation Original Research Article
Pages 461-470
V.M. Derkacheva, S.V. Barkanova, O.L. Kaliya, E.A. Luk' yanets

Hydroperoxide Oxidation of Cyclohexane Catalyzed by Metal Complexes of Azaporphines Original Research Article
Pages 471-479
S.V. Barkanova, I.A. Zheltukhin, O.L. Kaliya, V.N. Kopranenkov, E.A. Luk'yanets

Polymer-Bound Iron(III) Porphyrins as Oxidation Catalysts in Aqueous Solution Original Research Article
Pages 481-488
R.J. Lower, J.R. Lindsay Smith

Cobalt-Schiff Base Complex Catalyzed Dehydrogenation of Amines with T-Butyl Hydroperoxide Original Research Article
Pages 489-495
Kazusige Maruyama, Takahiro Kusukawa, Yoshihiko Higuchi, Akira Nishinaga

Homolytic Reactivity of Peroxovanadium Complexes Original Research Article
Pages 497-504
M. Bonchio, V. Conte, F. Coppa, F. Di Furia, G. Modena

Interaction of Hydrogen Peroxide and Copper (II): A Peroxidic Oxidizing Reagent Original Research Article
Pages 505-511
Patrice Capdevielle, Michel Maumy

Kinetic Resolution of Oxiranes by Chiral Molybdenum(VI) (Oxodiperoxo) α-Hydroxy Acid Amide/Diol Reagents Original Research Article
Pages 513-520
F. Betschinger, K. Hintzer, U. Leyrer, V. Schurig

New insights into the catalytic activity of polyoxometalates for oxidation with hydrogen peroxide Original Research Article
Pages 521-529
J.-M. Brégeault, C. Aubry, G. Chottard, N. Platzer, F. Chauveau, C. Huet, H. Ledon

Oxidation of primary and secondary aliphatic amines by Mo(O)(O2)2L′L″ (L′ = H2O, L″ = hexamethylphosphoramide) Original Research Article
Pages 531-536
F. Porta, S. Tollari, F. Ragaini, C. Crotti

The Sharpless Epoxidation of 3-Methyl-2-buten-1-ol Using Various Organic Hydroperoxides Original Research Article
Pages 537-543
E. Höft, H.-J. Hamann, L. Rüffer, M. Jáky

Attempted Catalytic Epoxidation of Alkenes Using a Metal Hydroperoxide: Dioxygen Insertion into a Pt-H Bond Original Research Article
Pages 545-554
Timothy T. Wenzel

1,2,4-Trioxanes, The Chemistry of A New Class of Saturated Heterocycles Original Research Article
Pages 555-564
C.W. Jefford

Regioselectivity of singlet oxygen ene reactions. The non-bonding large group effect Original Research Article
Pages 565-571
Michael Orfanopoulos, Manolis Stratakis, Yiannis Elemes, Ioulia Smonou

Industrial Catalytic Oxidations: An Overview Original Research Article
Pages 573-594
Roger A. Sheldon

Catalytic Cu(II) Induced Reactions Original Research Article
Pages 595-601
W. Buijs, R. Offermanns, L. Frijns

Why Not Ozone? Original Research Article
Pages 603-611
Henry Ledon

Deactivation Mechanisms in Liquid Phase Oxidations Caused by Carboxylic Acids Original Research Article
Pages 613-621
W. Partenheimer, J.A. Kaduk

Hydroperoxides in Hydrocarbons Liquid Phase Oxidation Original Research Article
Pages 623-629
S. Ciborowski

Alkylcarbonate synthesis by new catalytic system Original Research Article
Pages 631-640
Mi-Yon Lee, Dae-Chul Park

Oxidation of Ethylbenzene by Phenazine-Di-N-Oxide Radical Cation Original Research Article
Pages 641-647
Elena M. Koldasheva, Yurii V. Geletii, Vladimir V. Strelets, Alexandr E. Shilov

Syntheses and catalytic properties of iron triphenylphosphine oxide complexes Original Research Article
Pages 649-654
I. Ondrejkovičová, V. Vančová, G. Ondrejovixsč

A Mechanistic Study of the Formation of Maleic Anhydride on A Vanadyl Pyrophosphate Surface Original Research Article
Pages 655-664
B. Schiøtt, K.A. Jørgensen

Oxo Transfer from Amines N-Oxides to Copper Salts: Resulting Copper(III) Mediated Oxidation of Organic Ligands Original Research Article
Pages 665-673
M. Maumy, P. Capdevielle

Cobalt-Schiff Base Complex Catalyzed Epoxidation of Olefins with Naoc1 Original Research Article
Pages 675-680
Akira Nishinaga, Kazushige Maruyama, Mitsuo Kakutani, Takahiro Mashino, Takasi Umeda

Synthesis and Molecular Structure of A Novel Biomimetic Tetranuclear Manganese Aggregate Original Research Article
Pages 681-687
Robert T. Stibrany, Sergiu M. Gorun

Author Index
Pages 689-690

Subject Index
Pages 691-696