Diffusion in Solid Metals and Alloys

1.1 Fick’s laws, flux of particles, isotropic and anisotropic diffusion....Pages 1-2
1.2 Solutions of diffusion equations for constant diffusivity....Pages 2-7
1.4 The various diffusion coefficients....Pages 7-10
1.5 Atomistic mechanisms of diffusion....Pages 10-13
1.6 Methods of measuring diffusion coefficients....Pages 13-24
1.8 Temperature dependence of diffusion....Pages 25-27
1.9 Mass- and pressure dependence of diffusion....Pages 27-27
1.11 Further readings....Pages 28-29
1.12 References for 1....Pages 30-31
2.1 Introduction....Pages 32-33
2.2.1 Alkali metals....Pages 34-37
2.2.2 Alkaline earth metals....Pages 37-38
2.2.3 Scandium group and rare earth metals....Pages 38-40
2.2.4 Titanium group metals....Pages 41-43
2.2.5 Vanadium group metals....Pages 44-46
2.2.6 Chromium group metals....Pages 47-48
2.2.8 Iron group metals....Pages 49-51
2.2.9 Cobalt group metals....Pages 51-52
2.2.10 Nickel group metals....Pages 52-54
2.2.11 Noble metals....Pages 54-58
2.2.12 Zinc group metals....Pages 58-59
2.2.13 Aluminum group metals....Pages 60-61
2.2.14 Group IVB metals....Pages 61-62
2.2.15 Group VB semimetals....Pages 62-63
2.2.16 Group VIB semimetals....Pages 63-64
2.2.17 Actinide group metals....Pages 64-66
Figures for 2....Pages 66-80
2.3 References for 2....Pages 81-84
3.1 Introduction....Pages 85-87
3.2.1 Alkali metals....Pages 88-91
3.2.2 Alkaline earth metals....Pages 91-94
3.2.3 Scandium group and rare earth metals....Pages 95-99
3.2.4 Titanium group metals....Pages 100-112
3.2.5 Vanadium group metals....Pages 112-118
3.2.6 Chromium group metals....Pages 118-123
3.2.8 Iron group metals....Pages 124-130
3.2.9 Cobalt group metals....Pages 131-132
3.2.10 Nickel group metals....Pages 132-136
3.2.11 Noble metals....Pages 136-149
3.2.12 Zinc group metals....Pages 149-150
3.2.13 Aluminum group metals....Pages 151-156
3.2.14 Group IVB metals....Pages 157-161
3.2.15 Group VB semimetals....Pages 161-161
3.2.16 Actinide group metals....Pages 162-166
Figs. 1 - 26....Pages 166-177
Figs. 27 - 41....Pages 178-191
Figs. 42 - 53....Pages 192-202
3.3 References for 3....Pages 203-212
List of alloys....Pages 213-217
Ag-Al - Cu-Sn....Pages 218-230
Cr-Zn - V-Zr....Pages 231-243
Figs. 1 - 45....Pages 244-254
Figs. 46 - 86....Pages 255-265
Figs. 87 - 120....Pages 266-275
References for 4....Pages 276-278
5.1 Introduction....Pages 279-281
Ag-Al - Co-Ni....Pages 282-297
Co-Pd - Fe-Mo....Pages 298-311
Fe-Ni - Nb-U....Pages 312-327
Nb-V - U-Zr....Pages 328-339
Figs. 1 - 53....Pages 340-352
Figs. 54 - 111....Pages 353-365
5.3 References for 5....Pages 366-371
6.2 Solutions of diffusion equations for constant ternary interdiffusion coefficients....Pages 372-375
6.3 Concentration-dependent ternary interdiffusion coefficients....Pages 375-377
6.4 Determination of ternary intrinsic diffusion coefficients with inert markers....Pages 377-378
6.5 L{ij} phenomenological coefficients, atomic mobilities and vacancy wind parameter....Pages 378-379
6.7 Use of the tables and figures....Pages 379-379
Ag-Al-Zn - Cr-Ni-Si....Pages 380-392
Cu-Mn-Ni - Ti-V-Zr....Pages 393-400
6.8.2 Ternary intrinsic diffusion coefficients....Pages 401-402
6.8.3 Atomic mobilities and vacancy wind parameters....Pages 402-403
6.8.4 Tracer diffusion coefficients for ternary alloys....Pages 404-408
Figs. 1 - 20....Pages 409-421
Figs. 21 - 36....Pages 422-434
6.9 References for 6....Pages 435-436
7.1 General remarks....Pages 437-438
7.2 The effect of different production methods....Pages 438-438
7.3 Methods of diffusion investigations on amorphous alloys....Pages 439-441
7.4 Use of the tables and figures....Pages 441-441
7.5.1 Cobalt-base amorphous alloys....Pages 442-443
7.5.2 Copper-base amorphous alloys....Pages 443-444
7.5.3 Iron-base amorphous alloys....Pages 444-454
7.5.4 Nickel-base amorphous alloys....Pages 454-460
7.5.5 Palladium-base amorphous alloys....Pages 460-462
7.5.7 Zirconium-base amorphous alloys....Pages 463-465
Figures for 7....Pages 466-468
7.6 References for 7....Pages 468-470
8.1 Introduction....Pages 471-472
8.2 Diffusion tables for C, N, and O in metals....Pages 473-485
Figures for 8....Pages 485-499
8.3 References for 8....Pages 500-503
9.2 Methods of measurernents of diffusion coefficients of hydrogen in metals....Pages 504-509
9.3 Further readings....Pages 509-510
9.4.3 Scandium group and rare earth metals....Pages 511-512
9.4.4 Titanium group metals....Pages 512-515
9.4.5 Vanadium group metals....Pages 515-526
9.4.6 Chromium group metals....Pages 526-528
9.4.8 Iron group metals....Pages 528-533
9.4.9 Cobalt group metals....Pages 533-534
9.4.10 Nickel group metals....Pages 534-544
9.4.11 Noble metals....Pages 544-546
9.4.12 Zinc group metals....Pages 546-546
9.4.13 Aluminum group metals....Pages 547-548
9.4.15 Actinide group metals....Pages 548-548
Figures for 9....Pages 549-556
Be - W....Pages 556-563
Fe - U....Pages 563-573
10.1 Mass dependence of diffusion....Pages 574-577
10.2 The isotope effect tables for diffusion in solid metallic elements....Pages 577-590
10.3 Isotope effect tables for diffusion in binary alloys....Pages 591-592
Figures for 10.2 and 10.3....Pages 593-597
References for 10.2 and 10.3....Pages 598-599
10.4 Pressure dependence of diffusion....Pages 600-603
10.5 Pressure effect tables for diffusion in solid elements....Pages 604-612
10.6 Pressure effect tables for diffusion in homogeneous binary alloys....Pages 613-614
10.7 Pressure effect tables for interdiffusion in binary alloys....Pages 614-616
Figures for 10.5 - 10.7....Pages 616-623
References for 10.4 - 10.7....Pages 624-625
11.2 Methods of measurement....Pages 626-627
11.3 Presentation of results....Pages 627-629
11.4 References for 11....Pages 629-629
12.1 Introduction....Pages 630-639
12.2.1 Grain boundary self-diffusion in pure materials....Pages 640-646
12.2.2 Grain boundary tracer impurity diffusion in pure materials....Pages 647-656
12.2.3 Grain boundary tracer diffusion in alloys....Pages 657-668
12.2.4 Interphase boundary tracer diffusion....Pages 669-670
12.2.5 Grain boundary chemical diffusion....Pages 671-674
12.2.6 Interphase boundary chemical diffusion....Pages 675-675
Figs. 1 - 47....Pages 676-686
Figs. 48 - 84....Pages 687-697
Figs. 85 - 112....Pages 698-707
12.3 References for 12....Pages 708-716
13.1 Introduction....Pages 717-718
13.2 Mechanisms of surface diffusion....Pages 718-719
13.3 Anisotropy of surface diffusion....Pages 719-719
13.5 Adsorbate-modified surface self-diffusion....Pages 720-721
13.7 Measuring techniques....Pages 721-726
13.8 Systematics of surface diffusion coefficients....Pages 726-727
13.9 Commentary to tables....Pages 727-728
13.10 Surface diffusion tables....Pages 728-733
Figures for 13....Pages 734-743
13.11 Special references: review articles....Pages 743-744
13.12 References for 13....Pages 744-747