Comprehensive Organometallic Chemistry 3ed Vol 06 Grp 8

Comprehensive Organometallic Chemistry III.pdf......Page 1
Cobalt Organometallics......Page 2
Hydridocobalt Complexes......Page 3
Hydridocobalt Complexes in the Hydroformylation Reaction......Page 4
Hydridocobalt Complexes with Phosphine Ligands......Page 5
Hydridocobalt Complexes with Co-E Bonds (E=Si, Ge, Sn)......Page 6
Hydridocobalt Complexes with Nitrogen Ligands......Page 7
Organocobalt(-i) Complexes......Page 9
Organocobalt(0) Complexes......Page 10
Organocobalt(i) complexes with isocycanide ligands......Page 11
Organocobalt(i) complexes with carbene ligands......Page 14
Trispyrazolyl boratocobalt(ii) complexes......Page 17
Organocobalt(iii) complexes with non-macrocyclic ligands......Page 20
Organocobalt(iii) complexes with nitrogen-containing macrocyclic ligands......Page 29
Organocobalt(iii) complexes with oxime ligands......Page 33
Organocobalt(iii) complexes with Schiff base ligands......Page 41
Diels-Alder reactions......Page 42
Dechlorination reactions......Page 45
Miscellaneous applications......Page 49
Fullerene-containing compounds......Page 52
eta2-Alkyne complexes of cobalt......Page 54
eta2-C=O complexes of cobalt......Page 56
Organocobalt Complexes with eta3-Ligands......Page 57
eta4-(Cyclobutadiene) cobalt compounds formed by [2+2]-cycloaddition of alkynes......Page 60
Ring enlargements of cyclobutadiene cobalt units......Page 62
Superphane complexes stabilized with CpCo units......Page 64
eta4-Cyclobutadiene cobalt units as building blocks for the elaboration of supramolecular architectures......Page 67
eta4-cyclobutadiene cobalt units as part of new ligands......Page 71
Organocobalt complexes with new types of substituted eta5-Cp ligands......Page 72
Chirality at Cp......Page 75
Organocobalt complexes with eta5-Cp ligands displaying synthetically important chemistry......Page 78
CH activation on CoCp units......Page 80
C-C bond activation on CoCp units......Page 81
CpCo in polymerization of ethylene processes......Page 82
Binuclear and polynuclear complexes......Page 83
Anion receptors......Page 85
Dendrimeric cobaltocenium derivatives......Page 89
Cluster Complexes of Cobalt......Page 91
Synthesis of Co3 Clusters......Page 92
Ligand-substitution reactions on previously reported Co3 clusters......Page 95
Co3 clusters with a face-capping cyclopolyene ligand......Page 99
Polyhydride Co3 clusters......Page 100
Cluster Complexes with Four and More Cobalt Atoms......Page 102
Co9 and Co11......Page 105
Co12......Page 109
Co18 and Co6 and Co8......Page 110
References......Page 112
Rhodium Organometallics......Page 121
Binary halocarbonyl and hydridecarbonyl complexes......Page 122
Sulfur- and selenium-donor ligands......Page 123
Monodentate nitrogen-donor ligands......Page 124
Bidentate nitrogen-donor ligands......Page 125
Tridentate nitrogen-donor ligands......Page 127
Monodentate phosphorus-donor ligands......Page 128
Bidentate P-P ligands......Page 129
Bidentate P-O, P-S and P-N ligands......Page 132
Tridentate and tetradentate phoshorus ligands......Page 133
Thiocarbonyl, Carbon Disulfide, and Carbon Dioxide Complexes......Page 135
Isocyanide complexes containing O- and N-donor ligands......Page 137
Cp complexes......Page 139
Substituted Cp complexes (excluding Cp*)......Page 140
Compounds with group 16 and 17 donor ligands......Page 145
Complexes with group-15 and -14 containing ligands......Page 150
Cluster compounds......Page 160
Metathesis and transmetallation reactions......Page 162
Metallation of C-X bonds......Page 164
Insertion into Rh-X bonds (including migratory insertion of carbonyls)......Page 168
Metallation of C-H bonds......Page 171
Miscellaneous including insertions into C-C bonds......Page 177
Metallacyclic complexes......Page 180
Carbene and carbyne complexes......Page 184
Groups 16 and 17 donor ligands......Page 192
Group 15 donor ligands......Page 193
Cp and eta5-indenyl ligands......Page 197
Cumulene complexes......Page 199
Alkyne complexes......Page 200
Compounds with group 15 ligands......Page 203
Compounds with groups 16 and 17 ligands......Page 210
Other cod, nbd, and tfb complexes......Page 213
Conjugated bis-alkenes......Page 214
eta-Arene Complexes......Page 215
Allyl Complexes......Page 220
Rhodacarboranes......Page 223
References......Page 225
Introduction......Page 237
Computational Studies......Page 238
Carbon Monoxide as the Ligand......Page 240
Phosphites as Ligands......Page 241
Monophosphines......Page 243
Diphosphines......Page 245
1-Alkenes......Page 247
2-Alkenes......Page 249
Mechanistic studies......Page 250
New Developments......Page 252
Introduction......Page 254
Mechanism and Side Reactions......Page 255
Oxidative Addition of MeI; the Rate-limiting Step......Page 256
Ligands Design......Page 258
Trans-diphosphines in Methanol Carbonylation; Dinuclear Systems?......Page 261
References......Page 262
Iridium Organometallics......Page 266
Organization of the Material......Page 267
Monocarbonyl Complexes......Page 268
Dicarbonyl Complexes......Page 286
Polycarbonyl Complexes......Page 293
Carbonyl Cluster Complexes......Page 296
Alkyl and Aryl Complexes......Page 302
Alkenyl Complexes......Page 318
Iridium Alkynyl Complexes......Page 323
Iridium Complexes in C-C Bond-forming Catalysis......Page 334
Carbene Complexes, Ir=CRR1......Page 343
Cumulenylidene Complexes, Ir=C=(C)n=CRR1......Page 351
Higher Cumulenylidene Complexes, Ir=C=(C)n=CRR1 (n1)......Page 357
Carbyne Complexes, Irz.tbnd\rCR......Page 360
Cyclopentadienyl Complexes......Page 361
Indenyl Compounds......Page 384
Arene Compounds......Page 387
Iridium Fullerene Complexes......Page 390
Iridium Hydride Complexes......Page 393
Monohydride Complexes......Page 394
Dihydride Complexes......Page 398
Polyhydride Complexes......Page 404
Dihydrogen Bonding and Molecular Hydrogen Complexes......Page 405
Polynuclear Iridium Hydrides......Page 408
References......Page 411
Introduction......Page 425
Process Considerations......Page 426
Reactivity of [Ir(CO)2I2]-......Page 429
Reactivity of [Ir(CO)2I3Me]- and Related Ir(iii) Methyl Complexes......Page 432
Structural Studies of Iridium Complexes......Page 435
Overall Catalytic Mechanism......Page 436
Manufacture of (S)-metolachlor......Page 438
Mechanism......Page 439
References......Page 441