Comprehensive Hard Materials volume 3 Super Hard Materials

COMPREHENSIVE HARD MATERIALS
......Page 4
Section I - THEORY
......Page 22
3.01.2 Ab Initio and Semiempirical Methods......Page 24
3.10.1 Introduction......Page 239
3.01.3 Materials, Bonding, and Mechanical Properties......Page 29
3.04.4 Some Applications......Page 33
3.25.2 Synthesis of New Boron Allotrope, Orthorhombic γ-B28......Page 0
3.25 - High-Pressure Synthesis of Novel Superhard Phases......Page 36
3.06.1 Introduction......Page 122
3.02.2 Hardness and Elastic Constants......Page 38
3.02.3 Diamond and Related Cubic Superhard Structures......Page 40
3.02.4 Superhard Borides......Page 45
3.11.5 Different Concepts for a Scaling-up: Ir on Large Oxide Single Crystals versus Silicon-Based Multilayer Structures......Page 314
Acknowledgments......Page 51
3.07.1 Introduction......Page 56
3.03.2 One-Component Systems......Page 57
3.20.5 The Structural Transition Sequence in С60 at Thermobaric Treatment......Page 551
3.18 - Single Color Centers in Diamond: Materials, Devices, and Applications......Page 80
3.04.2 Brief Overview of the Models of Hardness. Li's Model. Accounting for Structural Topology and Distortions......Page 81
3.04.3 Global Optimization and its Application for the Discovery of Superhard Materials......Page 85
3.04.5 Conclusions......Page 98
3.10.6 Conclusion......Page 281
3.09.1 Introduction......Page 102
3.05.3 Wear Models and Wear Modeling......Page 109
3.12.4 Electrical Properties......Page 114
References......Page 509
Section II - MATERIALS: GROWTH,
PROPERTIES AND
APPLICATIONS:
CARBON-BASED DLC
......Page 120
3.06.4 Deposition Mechanism of DLC......Page 129
3.06.5 Basic Properties......Page 132
3.06.9 Some Applications of DLC......Page 147
References......Page 157
Section III - NANO– AND POLY–DIAMOND
......Page 162
3.07.2 Stability of Diamond at the Nanoscale......Page 165
3.19.3 Electrochemical Properties of BDD as Electrode Materials......Page 515
3.07.5 Brief Survey of Applications of Nanodiamond Particles as Superhard Additives......Page 184
3.07.6 Future Directions of Production and Applications......Page 188
References......Page 189
3.08 - Nanopolycrystalline Diamond without Binder and its Application to Various High-Pressure Apparatus......Page 194
3.08.2 Synthesis of NPD Using Large-Volume KMA......Page 196
3.08.3 Nature of NPD......Page 198
3.14.5 Surface Electronic Properties of Diamond in Electrolyte Solutions......Page 208
Acknowledgments......Page 210
Section IV - SINGLE CRYSTALLINE
DIAMOND
......Page 214
3.09.2 HPHT Synthesis of High-Purity Large Single Crystal Diamond......Page 218
3.09.4 Physical Properties......Page 226
3.09.6 Applications......Page 234
References......Page 235
3.10 - Ultrafast Deposition of Diamond by Plasma-Enhanced CVD......Page 238
3.10.3 Means for Studying the Plasma: Modeling and Optical Diagnostics......Page 241
3.22.4 Conclusions......Page 601
References......Page 283
3.11 - Single Crystal Diamond Growth on Iridium......Page 290
3.16.2 The Surface of Nanoscale Diamond......Page 401
3.11.3 Oriented Diamond Deposition on Heterosubstrates......Page 293
Acknowledgments......Page 397
3.11.7 Present State-of-the-Art Heteroepitaxial Diamond Films......Page 318
References......Page 321
3.17.2 Historical Outline......Page 329
3.12.3 Electronic Properties......Page 333
3.12.5 Ohmic Contact Issue in n-Type Diamond......Page 336
References......Page 339
3.15 - Polycrystalline CVD Diamond for Industrial Applications......Page 342
3.13.2 Physical Effects Limiting the Spatial Resolution......Page 343
3.13.5 Conclusions......Page 354
Acknowledgments......Page 355
Section V - SELECTED PROPERTIES
OF DIAMOND AND
APPLICATIONS
......Page 358
3.14.2 Dipole Effects on Diamond Surfaces......Page 360
3.14.4 Surface Electronic Properties of Diamond Covered with Adsorbates......Page 365
References......Page 383
3.15.2 CVD of Diamond......Page 386
3.20.3 Mechanical Properties Research under Pressure in Shear Diamond Anvil Cells on Ultrahard Fullerite and Superhard Nanotubes......Page 543
3.15.5 3D CVD Diamond Components......Page 394
3.16 - Diamond Nanoparticles: Surface Modifications and Applications......Page 400
3.21.5 Transitional Phase Diagram of Fullerite C60......Page 420
References......Page 424
3.17 - Diamond for Particle and Photon Detection in Extreme Conditions......Page 428
3.17.3 Detector Physics......Page 432
3.25.4 Novel Superhard Diamond-like Ternary B–C–N Phases......Page 436
3.17.6 Diamond Applications in Hot Environments......Page 468
References......Page 483
3.19.1 Introduction......Page 514
References......Page 526
References......Page 527
Section VI - OTHER CARBON PHASES
......Page 534
3.20 - Superhard Materials Based on Fullerenes and Nanotubes......Page 536
3.20.4 The Superhard and Ultrahard Carbon Materials Mechanical Properties Comparative Analysis......Page 545
3.20.6 Conclusion......Page 555
References......Page 556
3.21.3 High Elastic Moduli and Bridge to Ideal Mechanical Characteristics......Page 562
3.21.4 Experimental Details......Page 565
3.21.6 Regions of Hard Carbon Phases......Page 568
3.21.7 Hard Nanostructured Carbon Modifications Prepared at Moderate Pressures and High Temperatures......Page 571
3.21.9 Correlation between Density, Elasticity, and Hardness for New Carbon Phases......Page 577
3.21.10 Nonhydrostatic Stresses and Anisotropy of Mechanical Properties of Hard Carbon Phases......Page 578
References......Page 581
3.22.1 Introduction to Graphene......Page 586
Section VII - III-V BASED AND NOVEL
MATERIALS
......Page 606
3.23 - Synthesis and Properties of Single Crystalline cBN and Its Sintered Body......Page 608
3.23.2 cBN Sintered Body......Page 618
3.23.3 Summary and Future Perspective......Page 623
3.24.1 Introduction......Page 628
3.24.5 Properties and Applications of cBN Films......Page 641
3.25.1 Introduction......Page 662
3.25.3 New Superhard Binary B–C and B–N Phases......Page 664
References......Page 671
INDEX......Page 674