Comprehensive Coordination Chemistry. Late Transition Elements

Volume 5: Late Transition Elements......Page 4
Contents......Page 6
Preface......Page 8
Contributors to Volume 5......Page 10
Contents of All Volumes......Page 12
50 Nickel......Page 16
50.1 INTRODUCTION......Page 17
50.2 NICKEL(0)......Page 20
50.3 COMPLEXES WlTH eta3-BONDED SPECIES......Page 48
50.4 NICKEL(I)......Page 51
50.5 NICKEL(II)......Page 60
50.6 NICKEL(III) AND NICKEL(IV)......Page 302
50.7 REFERENCES......Page 316
51.1 INTRODUCTION......Page 1114
51.2 COORDINATION COMPLEXES OF PALLADIUM(0)......Page 1116
51.3 PALLADIUM(I) COMPLEXES AND CLUSTERS......Page 1118
51.4 PALLADIUM(II): OXYGEN DONOR COMPLEXES......Page 1127
51.5 PALLADIUM(llI): NITROGEN DONOR COMPLEXES......Page 1130
51.6 PALLADIUM(IV) COMPLEXES......Page 1137
51.7 REFERENCES......Page 1139
51.8.1 INTRODUCTION......Page 1146
51.8.2 UNIDENTATE LIGANDS......Page 1147
51.8.3 BIDENTATE AND MULTIDENTATE LIGANDS......Page 1161
51.8.4 REFERENCES......Page 1167
51.9.2 PHOSPHINE, ARSINE AND STIBINE COMPLEXES......Page 1172
51.9.3 PHOSPHITE, PHOSPHONITE, PHOSPHINITE AND OTHER COMPLEXES......Page 1181
51.9.4 SOME REACTIONS OF COORDINATED LIGANDS......Page 1182
51.9.5 REFERENCES......Page 1183
52 Platinum......Page 366
52.1 INTRODUCTION......Page 368
52.2 PLATINUM HYDRIDE COMPLEXES......Page 369
52.3 PLATINUM COMPLEXES OF GROUP IIIA LIGANDS......Page 387
52.4 PLATINUM COMPLEXES OF GROUP IVA LIGANDS......Page 390
52.5 PLATINUM COMPLEXES OF GROUP VA LIGANDS......Page 437
52.6 COMPLEXES WITH GROUP VI LIGANDS......Page 478
52.7 COMPLEXES OF GROUP VII LIGANDS......Page 503
52.8 COMPLEXES OF GROUP VIII LIGANDS......Page 506
52.9 SUBSTITUTION REACTIONS AND REACTION MECHANISMS......Page 507
52.10 REFERENCES......Page 515
53 Copper......Page 548
53.1 INTRODUCTION......Page 549
53.3 COPPER(I)......Page 550
53.4 COPPER(II)......Page 609
53.5 MIXED COPPER(II)/(III) COMPLEXES......Page 759
53.6 COPPER(III) COMPLEXES......Page 760
53.8 REFERENCES......Page 765
54 Silver......Page 790
54.1 SILVER(I) COMPOUNDS......Page 792
54.2 SILVER(II) COMPOUNDS......Page 854
54.3 SILVER(III) COMPOUNDS......Page 864
54.4 REFERENCES......Page 866
55 Gold......Page 876
55.2 REVIEWS OF GOLD CHEMISTRY......Page 877
55.3 A SURVEY OF OXIDATION STATES IN GOLD COMPLEXES......Page 878
55.4 BONDING IN GOLD COMPLEXES......Page 882
55.5 HYDRIDE COMPLEXES OF GOLD(I)......Page 884
55.6 HALIDE COMPLEXES OF GOLD(I)......Page 885
55.7 COMPLEXES OF GOLD(I) WITH OXYGEN DONOR LIGANDS......Page 886
55.8 COMPLEXES OF GOLD(I) WITH SULFUR AND SELENIUM DONOR LIGANDS......Page 887
55.9 COMPLEXES OF GOLD(I) WITH NITROGEN DONOR LIGANDS......Page 894
55.10 COMPLEXES OF GOLD(I) WITH PHOSPHORUS, ARSENIC AND ANTIMONY DONOR LIGANDS......Page 896
55.11 COMPLEXES OF GOLD(I) CARBON DONOR LIGANDS......Page 900
55.12 COMPLEXES OF GOLD(II)......Page 901
55.13 HALIDE COMPLEXES OF GOLD(III)......Page 904
55.15 COMPLEXES OF GOLD(III) WITH OXYGEN DONOR LIGANDS......Page 906
55.16 COMPLEXES OF GOLD(III) WITH SULFUR, SELENIUM AND TELLURIUM DONOR LIGANDS......Page 907
55.17 COMPLEXES OF GOLD(III) WITH NITROGEN DONOR LIGANDS......Page 909
55.18 COMPLEXES OF GOLD(III) WITH PHOSPHINE, ARSINE AND STIBINE LIGANDS......Page 912
55.20 COMPLEXES OF GOLD(V)......Page 913
55.21 COMPLEXES WITH GOLD-GOLD BONDS......Page 914
55.22 COMPLEXES WiTH GOLD-MAIN GROUP METAL BONDS......Page 918
55.23 COMPLEXES WITH GOLD-TRANSITION METAL BONDS......Page 919
55.24 REFERENCES......Page 926
56.1 Zinc and Cadmium......Page 940
56.1.2 THE APPLICATION OF PHYSICAL TECHNIQUES TO THE STUDY OF COORDINATION AT ZINC AND CADMIUM......Page 941
56.1.4 NITROGEN LIGANDS......Page 946
56.1.5 PHOSPHORUS LIGANDS......Page 974
56.1.7 SULFUR LIGANDS......Page 987
56.1.8 HALIDES AND PSEUDOHALIDES......Page 996
56.1.9 MULTINUCLEAR COMPLEXES OF ZINC AND CADMIUM......Page 1003
56.1.10 ZINC(I) AND CADMIUM(I)......Page 1004
56.1.11 MACROCYCLIC COMPLEXES......Page 1005
56.1.12 KINETICS AND REACTIVITY......Page 1011
56.1.13 APPLICATIONS......Page 1012
56.1.14 ASPECTS OF THE BIOLOGICAL CHEMISTRY OF ZINC AND CADMIUM......Page 1016
56.1.15 REFERENCES......Page 1037
56.2 Mercury......Page 1062
56.2.2 MERCURY COORDINATION COMPOUNDS WITH MERCURY OXIDATION NUMBERS LOWER THAN +1......Page 1063
56.2.3 MERCURY(I) COORDINATION COMPOUNDS......Page 1064
56.2.4 MERCURY(II) COORDINATION COMPOUNDS......Page 1074
56.2.5 APPENDIX......Page 1100
56.2.6 REFERENCES......Page 1103
Subject Index......Page 1186
Formula Index......Page 1204