Clathrate Compounds, Molecular Inclusion Phenomena, and Cyclodextrins: Proceedings of the Third International Symposium on Clathrate Compounds and Molecular Inclusion Phenomena and the Second International Symposium on Cyclodextrins, Tokyo, Japan, July 23–27, 1984

Front Matter....Pages 1-18
Front Matter....Pages 19-19
Inclusion Phenomena in a System Designed For Exclusion — A Cavitary Problem and a Model....Pages 21-34
Host-Guest Interactions with Hydrophobic Cyclophanes in Aqueous Media....Pages 35-47
Molecular Motion and Phase Transition in Hydroquinone Clathrate Compounds....Pages 49-59
Clathrate Formation in Wateer-Peralkylonium Salts Systems....Pages 61-72
The Design and Synthesis of a Family of Multimolecular Host-Guest Inclusion Complexes....Pages 75-83
Generation of Plane Chirality via Specific Host-Guest Interaction by a Macrocyclic Heterocyclophane in the Crystal Phase....Pages 85-89
Optical Resolution by Inclusion Complex Formation....Pages 91-98
Isolation and Crystal Structure of Alcohol Inclusion Complexes....Pages 99-102
New “Open-Chain Cryptands” with Specific Ion Transport Abilities....Pages 103-110
On-Off-Switched Crown-Metal Complexation by Photoinduced Intramolecular Tail(Ammonium)-Biting....Pages 111-118
Clathrate-Like Structure of Water around some Nonelectrolytes in Dilute Solution as Revealed by Computer Simulation and X-Ray Diffraction Studies....Pages 119-126
Complexes of Apatitic Layered Compound Ca 8 (HPO 4 ) 2 (PO 4 ) 4 ·5H 2 0 with Dicarboxylates....Pages 127-134
Resonance Raman Spectroscopic Study of Cation Radicals of Aromatic Molecules Formed in the Interlayer of Transition-Metal Exchanged Montmorillonites....Pages 135-142
Chiral Recognition Properties of Chiral 18-Crown-6 Ethers with Aromatic Substituents....Pages 145-151
Sulphonester Podands. A New Class of Clathrates....Pages 153-159
The Structures of Noncyclic Polyether Carriers Exhibiting Lithium Ion-Selective Transport....Pages 161-169
Kinetics and Equilibria of Dialkylthallium(III) Complexes of Some Thiacrown-Ethers in Acetonitrile....Pages 171-178
Antifungal Activity of Crown Ethers....Pages 179-184
Dissolving Metal Reduction....Pages 185-194
Synthesis of Diaza-Crown Ethers on Solid Supports....Pages 195-197
Front Matter....Pages 19-19
New Ionizable Ligands from p.t-Butylcalix [4] Arene....Pages 199-206
Synthesis of (AZA) n [3 n ]Cyclophanes as Host Molecules 1) ....Pages 207-214
The Structures of Macrocyclic Heterocyclophane Inclusion Complexes....Pages 215-222
Synthesis of Macrocycles Having Tröger Base Skeletons....Pages 223-229
Some Structural and Thermodynamic Studies of Clathrate Hydrates....Pages 231-238
 2 H and 13 C NMR study of guest molecule orientation in clathrate hydrates*....Pages 239-247
The Effect of Car Boxy Late Anions on the Formation of Clathrate Hydrates Of Tetrabutylammcnium Carboxylates....Pages 249-257
Clathrate Hydrates of Tetrabutylammonium Carboxylates and Dicarboxylates....Pages 259-266
Raman Spectroscopic Study of Hydrophobic Hydration of Organic Molecules in Aqueous Solution....Pages 267-273
Studies on Clathrasils: VII. A New Clathrate Compound of Silica: Synthesis, Crystallographic, And Thermal Properties.....Pages 275-278
Non-Stoichiometry and Lithium Intercalation in ZrSe 2 ....Pages 279-287
Lithium Intercalation in Layer Structured Compound β-ZrNCl....Pages 289-295
Preparation And Properties of the Layered Organic Derivatives Of γ-Zirconium Phosphate, Zr (CH 3 -(OCH 2 CH 2 ) n -OPO 3 ) (HPO 4 ) (n = 1−3)....Pages 297-304
Application of Intercalated Compound of Montmorillonite and N, N’- Diphenyl-P-Phenylenediamine to Antioxidant for Rubber Materials....Pages 305-315
On The Clathratogenic Properties of the Ni (NCS) 2 (4-Vinylpyridine) 4 Host....Pages 317-325
Some Symmetry Aspects of Layered-Clathrate Structures Formed by Ni (NCS) 2 (4-Methylpyridine) 4 ....Pages 327-332
Clathrate Formation in the [M(4-MePy) 2 (NCS) 2 ]-4-Mepy Systems, Where M = Co(II), Ni(II), Zn(II), Cd(II); 4-Mepy = 4-Methylpyridine....Pages 333-340
The Crystal Structures of α, ω-Diaminoalkanecadmium(II) Tetracyanonickelate(II)-Aromatic Molecule Inclusion Compounds. I. 1, 4-Diaminobutanecadmium(II) Tetracyanonickelate(II)-2,5-Xylidine (1/1): Cd(NH 2 (CH 2 ) 4 NH 2 )Ni(CN) 4 . (CH 3 ) 2 C 6 H 3 NH 2 ....Pages 341-349
The Crystal Structures Of α,ω-Diaminoalkanecadmium(II) Tetracyanonickelate(II)-Aromatic Molecule Inclusion Compounds. II. 1, 6-Diaminohexanecadmium(II) Tetracyanonickelate(II)- o -Toluidine (1/1): Cd(NH 2 (CH 2 ) 6 NH 2 )Ni(CN) 4. o -CH 3 C 6 H 4 NH 2 ....Pages 351-357
Selective N- Mono alkylation of Aniline Derivatives by Use of Alkali Cation Exchanged X- And Y-Type Zeolites....Pages 359-366
Front Matter....Pages 19-19
From Crown Ethers to Zeolites: Reaction of EtAlCl 2 with Crown Ethers....Pages 367-376
Crystalline Complexes of N,N′-Ditritylurea (DTU) and N-Tritylurea (NTU) Hosts with Molecular Guests....Pages 377-389
Inclusion Polymerization of Various Diene Monomers in Apocholic Acid Canals....Pages 391-398
The Formation of Inclusion Compounds of Alginic Acid in Aqueous Solution....Pages 399-408
Clathrate and Inclusion Compounds. Part 9 [1]. The Use of the Spectral Subtraction and Addition Techniques in Analysing the Vibrational Spectra of Inclusion Compounds....Pages 409-416
Thermodynamic Properties of a Shell Molecule-Gas Particles System....Pages 417-421
Construction of Literature Databases for Clathrate and Inclusion Compounds....Pages 423-429
Front Matter....Pages 431-431
An Artificial Acyl-Enzyme and An Artificial Enzyme....Pages 433-444
Crystal Packing Patterns of Cyclodextrin Inclusion Complexes....Pages 445-454
Site-Selective C-C Bond Formation Using Cyclodextrin as Catalyst....Pages 455-466
Prostaglandins and Their Cyclodextrin Complexes....Pages 467-474
Biomedical Applications of Complexation Agents/Solubilizers....Pages 477-485
Limits of Cyclodextrin Application in Oral Drug Preparations....Pages 487-501
Examples of the Application of Cyclodextrin in Formulation of Oral Drug Preparations....Pages 503-510
Inclusion Complex of Cinnarizine with β-Cyclodextrin in Aqueous Solution and in Solid State....Pages 511-521
Interaction of Tri-O-Methyl-β-Cyclodextrin with Drugs....Pages 523-531
Facile Separation of Enantiomers, Geometrical Isomers, and Routine Compounds on Stable Cyclodextrin LC Bonded Phases....Pages 533-545
Determination of Some Physical Constants of Cyclodextrin Complexes by Electrochemical Methods....Pages 547-554
Binding and Catalytic Behavior of Modified γ-Cyclodextrins....Pages 555-563
Geometry of α-Cyclodextrin Inclusion-Complexes with Some Substituted Benzenes Deduced from C-13 Nmr Chemical Shifts....Pages 565-572
Front Matter....Pages 431-431
Thermodynamic Parameters for the Molecular Inclusion Reactions of Some AZO Compounds with α-Cyclodextrin....Pages 573-581
Crystal Structures of Cyclodextrin Complexes with Chiral Molecules....Pages 583-594
Comparative Study on Inclusion Complexations of Antiinflammatory Drug Flurbiprofen with β-Cyclodextrin and Methylated β-Cyclodextrins....Pages 597-604
Influence of Cyclodextrins on Nitrosation of Drugs....Pages 605-611
Effect of β-Cyclodextrin on Disposition of Hexobarbital and Phenobarbital in Mice....Pages 613-621
Improvement of Some Pharmaceutical Properties of Carmoful by Cycrodextrin Complexation....Pages 623-630
Non-Oral Drug Preparations Containing Cyclodextrin Complexes....Pages 631-636
Alleviation of the Chlorpromazine-Induced Muscular Tissue Damage by β-Cyclodextrin Complexation....Pages 637-644
Evaluation of Cyclodextrin Polymer as a Disintegrating Agent....Pages 645-654
Preparation of Cyclodextrin Membrane and its Selective Permeation....Pages 655-660
Synthesis of Two Regiospecific Isomers of Monotosyl-γ-Cyclodextrin....Pages 661-667
Synthesis and Reactivity of β-Cyclodextrin-Histamine as Enzyme Model....Pages 669-674
The Explanation of High Specificity of Discriminating Optical Isomers in Enzymatic Reactions by the Molecular Anvil Model of Enzyme....Pages 675-682
ATP and AMP Formation from ADP in the Presence of Cyclodextrin....Pages 683-688
X-ray Structural Studies on Two Forms of β-Cyclodextrin·barbital Complexes....Pages 689-699
The Crystal and Molecular Structure of the β-Cyclodextrin Inclusion Complex with Aspirin and Salicylic Acid....Pages 701-714
Spectroscopic Investigation of Cyclodextrin Monomers, Derivatives, Polymers and Azo Dyes (1)....Pages 715-724
Study of Polysaccharides by the Fluorescence Method. V. Interaction of 2- p -Toluidinylnaphthalene-6-sulfonate with Amylose and its Related Compounds in Aqueous Solution....Pages 725-735
Three-Component Complexes of Cyclodextrins. Exciplex Formation in Cyclodextrin Cavity....Pages 737-746
Induced Circular Dichroism Spectra Of Cyclobuta[1,2- b :3,4- b ’]-Diquinoxaline....Pages 747-753
Front Matter....Pages 431-431
The Cyclodextrin-Quinone Inclusion Compounds in an Aqueous Solution at 77 K. I. 9,10-Anthraquinone Sulfonates and 1,4-Naphthoquinones....Pages 755-764
Molecular Inclusion Reactions between Metal Complexes of Azo Complexons and α-Ciclodextrin in Aqueous Solution....Pages 765-773
Calorimetric Determination of Enthalpies, Gibbs Energies,and Entropies of Inclusion of Some Alcohols Into α- and β-Cyclodextrins in Aqueous Solutions....Pages 775-780
Molecular Interaction of Phlorizin and Cyclodextrins....Pages 781-789
Preparation and Properties of Cyclodextrin Inclusion Compounds of Organometallic Complexes. Ferrocene Inclusion Compounds....Pages 791-798
Molecular Rotation and Lattice Dynamical Properties for Cyclodextrin-Terrocene and some its Ring-Substituted Derivative Clathrates....Pages 799-806
Complexation of Copper(II)-Montmorillonite with a Modified Cyclodextrin....Pages 807-813
Acceleration of the Photodimerization of Water-Soluble Anthracenes Included by β- and γ-Cyclodextrins....Pages 815-822
Selective Synthesis of 4-Hydroxybenzoic Acid using Immobilized Cyclodextrin....Pages 823-827
Asymmetric Halogenation and Hydrohalogenation of Trans -Cinnamic Acid in Crystalline Cyclodextrin Complexes....Pages 829-839
Asymmetric Halogenation and Hydrohalogenation of Ethyl trans -Cinnamate in Crystalline Cyclodextrin Complexes....Pages 841-850
Solid-State Photoreaction on an Inclusion Compound of Coumarin with β-Cyclodextrin....Pages 851-860
Chiral Conformations Induced by Cyclodextrin....Pages 861-867
Preparation of Macro Crown Ether-Like Compounds by the Smith Degradation of Cyclodextrins....Pages 869-875
Enzymatic Degradation of Cyclodextrins; Preparation and Application of their Fragments....Pages 877-884
Second Harmonic Generation in Inclusion Complexes....Pages 885-890
Preparation of Cyclosophoraose-A and Its Complex-Forming Ability....Pages 891-899
Back Matter....Pages 901-913