Chemorheology of Thermosetting Polymers

Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Process Automation A Rheological and Chemical Overview of Thermoset Curing......Page 9
Literature Cited......Page 32
2 Cure Kinetics and Mechanical Properties of a Resin Matrix Effects of Impurities and Stoichiometry......Page 33
Experimental......Page 34
Results and Discussion......Page 41
Conclusions and Comments......Page 54
Literature Cited......Page 55
3 Kinetics of Acetylene-Terminated Resin Cure and Its Effects on Dynamic Mechanical Properties......Page 56
TICA Experiments......Page 57
Kinetics of ATS Cure......Page 58
Glass Transition Temperatures (Tg)......Page 60
TICA Experiment......Page 61
Literature Cited......Page 66
4 Acetylene-Terminated Resin Cures Air and Nitrogen Effects......Page 67
RESULTS AND DISCUSSION......Page 68
THERMAL SCANS IN AIR/NITROGEN......Page 69
ISOTHERMAL CURE......Page 72
SCANS OF PRECURED SPECIMENS......Page 74
CONCLUSION......Page 84
Literature Cited......Page 87
Experimental......Page 88
Dicussion......Page 96
Acknowledgment......Page 98
Literature Cited......Page 99
Experimental......Page 100
Discussion......Page 101
Literature Cited......Page 116
Experimental......Page 118
Discussion......Page 119
Literature Cited......Page 123
8 Chemiluminescence of Thermosetting Resins......Page 125
Experimental......Page 126
Results......Page 130
Literature Cited......Page 142
9 Poly(n-Butyl Methacrylate) and Poly(Butyl Methacrylate-co-Acrylic Acid) Films Dried from Solutions of Hydrogen Bonding Capability......Page 144
Experimental......Page 145
Results......Page 146
Discussion......Page 149
Literature Cited......Page 151
10 Cure of Intaglio Printing Inks......Page 152
Background......Page 153
Experimental Section......Page 154
Results and Discussion......Page 156
Literature Cited......Page 169
11 Curing Behavior of Segmented Polyurethane Adhesives......Page 171
Structure......Page 172
Experimental......Page 173
Results......Page 175
Conclusions......Page 185
Literature Cited......Page 187
12 Rheological Cure Transformation Diagrams for Evaluating Polymer Cure Dynamics......Page 189
Instrument Requirements......Page 190
Sample Handling......Page 191
Applications......Page 192
Experimental......Page 193
Literature Cited......Page 201
13 Curing Kinetics of Unsaturated Polyester and Vinyl Ester Resins......Page 202
Experimental......Page 205
Results......Page 206
Discussion......Page 217
Literature Cited......Page 222
14 Dynamic Mechanical and Dielectric Properties of an Epoxy Resin During Cure......Page 223
EXPERIMENTAL......Page 225
Results and Discussion......Page 226
Conclusions......Page 245
Literature Cited......Page 248
Appendix......Page 249
15 Reactive Systems—Finite Element Analysis......Page 251
Theoretical background......Page 252
Computer Model......Page 253
Selected Numerical Result......Page 254
Literature Cited......Page 261
16 Kinetic Model of Cure Reactions Aids to Property and Processing Predictions......Page 263
KINETIC THEORY OF THE CURE REACTION......Page 264
EXPERIMENTAL RESULTS AND DISCUSSION......Page 266
CONCLUSION......Page 276
Literature Cited......Page 278
17 Thermosetting Coatings—Analytical and Predictive Capability by Chemorheology......Page 280
Experimental Section......Page 281
Background......Page 282
Cure Curve Analysis and Interpretation......Page 283
Cure Modeling......Page 288
Conclusions......Page 298
Literature Cited......Page 299
18 Predictive Models as Aids to Thermoset Resin Processing......Page 300
EXPERIMENTAL......Page 301
RESULTS AND DISCUSSION......Page 303
CONCLUSION......Page 315
Literature Cited......Page 317
C......Page 318
Ε......Page 319
H......Page 320
P......Page 321
S......Page 322
U......Page 323
V......Page 324