Chemistry of Nanocontainers

Topics in Current Chemistry 319\r......Page 1
Chemistry of Nanocontainers......Page 3
Copyright page\r......Page 4
Aims and Scope......Page 7
Preface......Page 9
Contents......Page 10
Molecular Cages and Capsules with Functionalized Inner Surfaces......Page 11
1 Introduction......Page 12
2 Cage-Type Receptors Containing Metal Ions......Page 16
3 Cage-Type Receptors Containing Hydrogen Bond Acceptors......Page 22
4 Cage-Type Receptors Containing Hydrogen Bond Donors......Page 27
5 Cage-Type Receptors Containing Hydrogen Bond Acceptors and Donors......Page 35
6 Conclusions......Page 41
References......Page 42
Drug Delivery by Water-Soluble Organometallic Cages......Page 45
1 Introduction......Page 46
2 Inorganic Metalla-Assemblies......Page 47
3 Organometallic Metalla-Assemblies......Page 49
4 Organometallic Metalla-Assemblies Composed of Half-Sandwich Complexes......Page 52
5 Organometallic Assemblies Composed of Half-Sandwich Complexes for Biological Applications......Page 54
6 Organometallic Assemblies Composed of Half-Sandwich Complexes for Drug Delivery......Page 58
References......Page 62
Reversibly Expanded Encapsulation Complexes......Page 66
1 Introduction......Page 67
2 The Steric Environment......Page 69
3 The Magnetic Environment......Page 71
4 Compression of Guests......Page 72
5 Isolated Hydrogen Bonds......Page 74
6 Arrangements of Guests......Page 77
7.1 Light......Page 78
7.2 Acid/Base......Page 81
References......Page 84
1 Introduction......Page 88
2 M4L6 Tetrahedron for the Stabilisation of White Phosphorus and Gas Separation......Page 94
3 M4L4 Tetrahedra with Successive Guest Exchange......Page 97
4 M4L6 Tetrahedra as a Chemical Sensors......Page 98
5 Various Nearly Closed Coordination Cages......Page 100
References......Page 104
Molecular Capsules Derived from Resorcin[4]arenes by Metal-Coordination......Page 108
1.1 General......Page 109
2 Cavitands and Calix[n]arenes: Building Blocks for Supramolecular Capsules......Page 110
3.1 Receptor Units at the o,o Position of the Cavitand......Page 112
4 Terpyridines as Building Blocks for Coordination Cages......Page 118
5 Synthesis of a Large Metallo-Supramolecular Cage from a Cavitand-Terpy Building Block [64]......Page 123
References......Page 130
Coronates, Spherical Containers, Bowl-Shaped Surfaces, Porous 1D-, 2D-, 3D-Metallo-Coordination Polymers, and Metallodendrimers......Page 134
1 Introduction......Page 135
2.1 Coronates and Sandwich Complexes......Page 136
2.2 One-Dimensional Coordination Polymers from Metallocoronates: Threading Cesium Ions......Page 138
2.3 {2}-Metallocryptates of Iron(III)......Page 139
2.4.1 One-Dimensional Linear Strings......Page 140
2.4.2 Meandering One-Dimensional Strings......Page 142
3 Bis-Bidentate Chelators: Mixed-Valent Tetranuclear Chelate Complexes of Iron [M{Fe4-nIIFenIII(L6)6}]0 with Endohedral Guests......Page 144
4.1 Unoccupied Tetranuclear Chelate Complexes [Fe4(L7)4] and......Page 146
4.2 Occupied Tetranuclear Chelate Complexes [M{In4III(L9)4}] from an N-Centered Tripodal Heptadentate Chelator......Page 147
5 Bis-Bidentate Chelators: Tetranuclear Chelate Complexes of Metal(II) Ions [(R2NH3)4{M4II(L10,11)6}] with Exohedral Guests......Page 151
5.1 Enantiomerization of Tetrahedral Homochiral\r[(RNH3)4\\ {Mg4(L12)6}] Chelate Complexes:\rEnantiotopization of Diastereotopic Protons via\rEnantiomerization\r......Page 154
6 Six- and Eight-Membered Iron(III) Coronates from Triethanolamine with Sodium- or Cesium-Ions as Endohedral Guests......Page 156
7.1 Compartmentation Through Interdigitation......Page 157
7.2 Porosity of 3D-pi-pi-Stacked Ferric Wheels......Page 158
8 Metallodendrimers......Page 160
9.1 Mononuclear- and Polynuclear Chelate Complexes of Iron(III)- and Iron(II) Ions......Page 161
9.2 3D- and 2D-Coordination Polymers of Copper(II)-Ions from Tetrazolyl- or Pyrrolinyl Enolates......Page 163
9.3 Ligand Programmed 1D-Coordination Polymers......Page 168
9.4 Induction of Helicity via Stereogenic Centers: Asymmetric Synthesis of (P)- and (M)-1D-Coordination Polymers......Page 170
9.5 Reduction of Dimensionality by Using a Group 1 Metal......Page 171
9.6 A meso-Helical 1D-Coordination Polymer......Page 172
10 Summary and Perspectives......Page 173
References......Page 174
Index......Page 180