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ویرایش: نویسندگان: David Acaster, Lawrie Ryan, Brian Ratcliff, Helen Eccles, Anne McCarthy سری: ISBN (شابک) : 9780521746045, 0521746043 ناشر: سال نشر: تعداد صفحات: [247] زبان: English فرمت فایل : PDF (درصورت درخواست کاربر به PDF، EPUB یا AZW3 تبدیل می شود) حجم فایل: 19 Mb
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COAS_C2_Imprint_it.unlocked COAS_C2_Intro_it.unlocked COAS_C2_Contents_it.unlocked Combined COAS_C2_Ch01_it AS level organic chemistry revisited Some revision Naming organic compounds Isomerism Summaries of reactions from AS Chemistry Summary COAS_C2_Ch02_it Arenes Benzene Energetic stability of benzene Substitution reactions Addition of halogens to benzene Phenols and their properties Summary Questions COAS_C2_Ch03_it Carbonyl compounds Aldehydes and ketones Physical properties of the carbonyl group Preparation: oxidation of alcohols Reduction Characteristic tests Summary Questions COAS_C2_Ch04_it Carboxylic acids and esters Carboxylic acids Esters Summary Questions COAS_C2_Ch05_it Amines Primary amines The preparation of amines Amines as bases Making salts with amines Reactions specific to phenylamine Summary Questions COAS_C2_Ch06_it Amino acids and chirality Amino acids Proteins and polypeptides Stereoisomerism Summary Questions COAS_C2_Ch07_it Polyesters and polyamides The formation of polymers Degradable plastics Summary Questions COAS_C2_Ch08_it Synthesis How do we design molecules? Routes to new molecules Chirality in pharmaceutical synthesis Summary Questions COAS_C2_Ch09_it Chromatography Mechanisms of chromatographic separation Paper chromatography Thin-layer chromatography Gas chromatography (GC) Gas chromatography-mass spectrometry (GC-MS) Summary Questions COAS_C2_Ch10_it Spectroscopy Nuclear magnetic resonance Combined techniques Summary Questions COAS_C2_Ch11_it How fast? The rate equation Order of reaction Concentration against time graphs Half-life and reaction rates Finding the order of reaction using raw data Rate constants and temperature changes Rate equations and mechanisms Summary Questions COAS_C2_Ch12_it How far? Equilibria in organic reactions The amounts of substances present at equilibrium Kc and Le Chatelier’s principle Summary Questions COAS_C2_Ch13_it Acids, bases and buffers Definitions of acids and bases The role of water Base behaviour and neutralisation Introducing Kw, the ionic product of water Introducing pH Ionic equilibria: the definition of Ka and pKa Calculating the pH of a weak acid Calculating [H+] from a pH value Calculating the Ka of a weak acid Measuring pH Acids with alkalis: monitoring change Buffer solutions Calculating the pH of a buffer solution Summary Questions COAS_C2_Ch14_it Lattice enthalpy The Born-Haber cycle Trends in the lattice enthalpy Enthalpy change of solution Enthalpy change of hydration Using enthalpies of solution and hydration Summary Questions COAS_C2_Ch15_it Entropy Entropy changes Free energy Summary Questions COAS_C2_Ch16_it Electrode potentials and fuel cells Oxidation and reduction Electrode potentials Standard electrode potentials Measuring a standard electrode potential The meaning of E values Using E values to predict cell voltages Using E values to predict whether or not a reaction will occur Using E values to predict cell voltages Using E values to predict whether or not a reaction will occur Using cell voltage to predict whether or not a reaction will occur Limitations of the standard electrode potential approach Reaction rate has a role to play too Storage cells Fuel cells The hydrogen economy Summary Questions COAS_C2_Ch17_it Transition elements Electronic structures Properties of transition elements and their compounds Complexes Redox behaviour Summary Questions COAS_C2_SAQs_it COAS_C2_Glossary_it.unlocked COAS_C2_Appendix_it.unlocked COAS_C2_Index_it.unlocked