Catalyst Deactivation, Proceedings of the 7th International Symposium

Content: 
Preface
Page xiii
Calvin H. Bartholomew, Gustavo A. Fuentes

Roles of acidity and pore structure in the deactivation of zeolites by carbonaceous deposits Original Research Article
Pages 1-19
M. Guisnet, P. Magnoux, D. Martin

Impact of sulfur on three-way automotive catalyst performance and catalyst diagnostics Original Research Article
Pages 21-38
D.D. Beck

Solid state reactions in catalysts: An approach to real active systems and their deactivation Original Research Article
Pages 39-51
Bernard Delmon

Coke formation in catalytic processes: Kinetics and catalyst deactivation Original Research Article
Pages 53-68
G.F. Froment

Catalyst deactivation: How we cannot yet subvert nature Original Research Article
Pages 69-86
John B. Butt

Catalyst deactivation: Opportunity amidst woe Original Research Article
Pages 87-98
Eugene E. Petersen

The relationship between metal particle morphology and the structural characteristics of carbon deposits Original Research Article
Pages 99-109
R.T.K. Baker, M.S. Kim, A. Chambers, C. Park, N.M. Rodriguez

Self-poisoning and aging of Pd-Ag/Al2O3 in semi-hydrogenation of 1,3-butadiene: Effects of surface inhomogeneity caused by hydrocarbonaceous deposits Original Research Article
Pages 111-118
A. Sarkany

Influence of the support on the deactivation of nickel zeolite catalysts during the conversion of phenylacetylene Original Research Article
Pages 119-125
E.D. Gamas, I. Schifter

Activation and deactivation of the zeolite Ferrierite for olefin conversions Original Research Article
Pages 127-138
Krijn P. de Jong, Henk H. Mooiweer, John G. Buglass, Paul K. Maarsen

Deactivation of ferrierite during the 1-Butene skeletal isomerization Original Research Article
Pages 139-145
R.A. Comelli, Z.R. Finelli, N.S. Fígoli, C.A. Querini

Alcohol dehydration reactions as chemical precursors for coke formation and acidity probes in tungstated zirconia catalysts Original Research Article
Pages 147-152
Gustavo Larsen, Edgar Lotero, Mark Nabity, Lucía Petkovic, Carlos A. Querini

Determination of coke deposition on metal active sites of propane dehydrogenation catalysts Original Research Article
Pages 153-158
P. Praserthdam, T. Mongkhonsi, S. Kunatippapong, B. Jaikaew, N. Lim

The role of coke deposition in the conversion of methanol to olefins over SAPO-34 Original Research Article
Pages 159-166
De Chen, Hans Petter Rebo, Kjell Moljord, Anders Holmen

Deactivation and regeneration of alkane dehydrogenation catalysts Original Research Article
Pages 167-174
S.D. Jackson, J. Grenfell, I.M. Matheson, S. Munro, R. Raval, G. Webb

A novel mechanism of catalyst deactivation in liquid phase synthesis Gas-to-DME reactions Original Research Article
Pages 175-182
X.D. Peng, B.A. Toseland, R.P. Underwood

Activity, selectivity and coking of bimetallic Ni-Co-spinel catalysts in selective hydrogenation reactions Original Research Article
Pages 183-190
J.C. Rodríguez, C. Guimon, A.J. Marchi, A. Borgna, A. Monzón

Stability and regeneration of supported PtSn catalysts for propane dehydrogenation Original Research Article
Pages 191-198
Cristina L. Padró, Sergio R. de Miguel, Alberto A. Castro, Osvaldo A. Scelza

Deactivation and shape selectivity effects in toluene nitration over zeolite catalysts Original Research Article
Pages 199-206
Jeffrey M. Smith, Haiyang Liu, Daniel E. Resasco

Regeneration of VPMeO Catalysts for n-butane oxidation by means of mechanochemical and barothermal treatments Original Research Article
Pages 207-212
V. Zazhigalov, A. Kharlamov, J. Haber, J. Stoch, V. Yaremenko, I. Bacherikova, L. Bogutskaya

Sulfur tolerance of Cu-and H-mordenite zeolite catalysts for the reduction of NO by hydrocarbons Original Research Article
Pages 213-224
Moon Hyeon Kim, In-Sik Nam, Young Gul Kim

Deactivation of Cu-ZSM-5 during selective catalytic reduction of NO by propane under wet conditions Original Research Article
Pages 225-230
A. Martínez, S.A. Gómez, G.A. Fuentes

H-mordenite deactivation during the SCR of NOx. Adsorption and diffusion of probe molecules on fresh and deactivated catalysts Original Research Article
Pages 231-238
E.E. Miró, L. Costa, J.M. Dereppe, J.O. Petunchi

Deactivation of Pt/alumina catalysts for the hydrodechlorination of 1,1,1-trichloroethane Original Research Article
Pages 239-250
Kevin A. Frankel, Ben W-L Jang, George W. Roberts, James J. Spivey

Understanding claus catalyst deactivation mechanisms: Optimization of alumina using physico-chemical parameters Original Research Article
Pages 251-258
Christophe Nédez, Jean-Louis Ray

Deactivation by poisoning and the improvement of three way catalysts for natural gas-fueled engines Original Research Article
Pages 259-266
Takeshi Tabata, Hideo Kawashima, Kenji Baba

Deactivation of manganese-cerium oxide catalysts during wet oxidation of phenol Original Research Article
Pages 267-274
P. Oelker, A. Bernier, P. Ruiz, B. Delmon, P. Isnard

Coke deactivation of hydrotreating catalysts: A variable site model Original Research Article
Pages 275-282
F.E. Massoth

On the metal deposition process during the hydrodemetallation of vanadyl-tetraphenylporphyrin Original Research Article
Pages 283-294
J.P. Janssens, R.M. de Deugd, A.D. van Langeveld, S.T. Sie, J.A. Moulijn

Coke formation in fluid catalytic cracking Original Research Article
Pages 295-302
M.A. den Hollander, M. Makkee, J.A. Moulijn

Mathematical modeling of deactivation by coke formation in the cracking of gasoil Original Research Article
Pages 303-310
H.S. Cerqueira, E.C. Biscaia Jr., E. Falabella, S. -Aguiar

Catalyst decay by simultaneous sintering and poisoning: Effects of intraparticle and interfacial gradients Original Research Article
Pages 311-318
M. Chocron, N. Amadeo, M. Laborde

A model for catalyst deactivation in industrial catalytic reforming Original Research Article
Pages 319-325
L.M. Rodríguez Otal, T. Viveros García, M. Sánchez Rubio

Effects of the metal-metal interactions on the stability of Pt-Re/Al2O3-Cl reforming catalysts Original Research Article
Pages 327-334
J. Barbier, P. Marecot, C.L. Pieck

Temperature programmed oxidation of deactivated Pt/Nb2O5 catalysts Original Research Article
Pages 335-342
D.A.G. Aranda, J.C. Alfonso, R. Frety, M. Schmal

Effects of sulfidation of Mo nitride and CoMo nitride catalysts on thiophene HDS Original Research Article
Pages 343-350
Son-Ki Ihm, Do-Woan Kim, Dong-Keun Lee

Catalyst deactivation by metals and coke during hydrodemetallation Original Research Article
Pages 351-357
M. Núñez, E. Gómez, C. Suarez, E. Carmona

Deactivation of Pt-Sn/Al2O3 catalysts by coking: Influence of the preparation method Original Research Article
Pages 359-366
G. Corro, P. Marecot, J. Barbier

New developments in FCC catalyst deactivation by metals: Metals mobility and the vanadium mobility index (VMI) Original Research Article
Pages 367-374
Lori T. Boock, Joanne Deady, Tow Foon Lim, George Yaluris

Stability of an FCC catalyst matrix for processing gas oil with resid Original Research Article
Pages 375-382
P. Gamero M., C. Maldonado M., J.C. Moreno M., O. Guzman M., E. Mojica M., R. Gonzalez S

Kinetics of coke combustion during temperature-programmed oxidation of deactivated cracking catalysts Original Research Article
Pages 383-390
Cam Le Minh, Chaoen Li, Trevor C. Brown

Activity, selectivity and deactivation of Y zeolite: A compromise in fluid catalytic cracking catalysts Original Research Article
Pages 391-398
C. Maldonado M., P. Gamero M., F. Hernández B., J.A. Montoya F., J. Navarrete, J.A. Toledo A., A. Vázquez R., A. Vargas

M/H-MFI catalyst deactivation and reaction kinetics for n-Octane transformation Original Research Article
Pages 399-406
J. Papa, F. Santos, M.J. Becerra, G. Giannetto, F. Yanez, L. García

Isobutane alkylation with C4 olefins: Low temperature regeneration of solid acid catalysts with ozone Original Research Article
Pages 407-414
C.A. Querini, E. Roa, C.L. Pieck, J.M. Parera

Influence of chloride during coke burning of a naphtha reforming catalyst coked in a commercial cycle Original Research Article
Pages 415-420
M.C. Rangel, M.N.M. Barbosa, C.L. Pieck, N.S. Fígoli

Deactivation of Pt-Au/Al2O3 catalysts prepared by surface redox reaction: Effects of sulfur and coke deposition Original Research Article
Pages 421-426
G. Espinosa, G. Del Angel, J. Barbier, P. Marecot, I. Schifter

Nature of coke formed from Tri-isopropylbenzene over USY zeolites with different rare Earth content Original Research Article
Pages 427-432
C.A. Henriques, E. Falabella, S. Aguiar, M.L. Murta Valle, S. Varela, J.L.F. Monteiro

Differential effect of coke burning with oxygen or ozone on Pt-Re interaction in Pt-Re/Al2O3 Original Research Article
Pages 433-438
C.L. Pieck, J.M. Parera

Hydrodesulfurization of dibenzothiophene on a nitrided supported molybdena-alumina catalyst Original Research Article
Pages 439-445
Masatoshi Nagai, Yosuke Goto, Hiroshi Sasuga, Shinzo Omi

Industrial evaluation of selective hydrogenation catalyst poisoning Original Research Article
Pages 447-454
B. Didillon, J. Cosyns, C. Cameron, D. Uzio, P. Sarrazin, J.P. Boitiaux

The mechanism of metal poisoning by cyclic deactivation in fluid cracking catalysts Original Research Article
Pages 455-462
F. Hernandez, R. García de León, E. Mógica, J.C. Moreno, R. González, E. Garcíafigueroa

AFM and XPS studies of thiophene and 1-butanethiol deactivation of Pd/Al2O3 model catalysts during 1,3-butadiene hydrogenation Original Research Article
Pages 463-470
K-H Lee, R. Catani, R. Miglio, E.E. Wolf

Sulfur poisoning of nickel-based hot gas cleaning catalysts in synthetic gasification gas Original Research Article
Pages 471-478
J. Hepola, P. Simell

Effects of H2S on bifunctional catalysts Original Research Article
Pages 479-486
C. Flego, L. Galasso, S. Vidotto, G. Faraci

Performance of Ni/Al2O3 pellets poisoned by thiophene Original Research Article
Pages 487-494
D. Rusic, S. Zrncevic

Study of the simultaneous deactivation by coke and sulfur of naphtha reforming catalysts using a bifunctional test reaction Original Research Article
Pages 495-500
A. Borgna, T.F. Garetto, C.R. Apesteguía

Deactivation and attrition of iron catalysts in synthesis gas Original Research Article
Pages 501-516
Nancy B. Jackson, Abhaya K. Datye, Linda Mansker, R.J. O\'Brien, Burtron H. Davis

Temperature-programmed reaction study of carbon transformations on iron fischer-tropsch catalysts during steady-state synthesis Original Research Article
Pages 517-526
S.A. Eliason, C.H. Bartholomew

Deactivation of iron-based catalysts for slurry phase Fischer-Tropsch synthesis Original Research Article
Pages 527-533
Ajoy P. Raje, Robert J. O\'Brien, Liguang Xu, Burtron H. Davis

Effects of reduction and regeneration conditions on the activity of CuO-ZnO catalysts Original Research Article
Pages 535-541
C.E. Quincoces, N.E. Amadeo, M.G. González

Effects of promoters and supports on coke formation on Pt catalysts during CH4 reforming with CO2 Original Research Article
Pages 543-550
Susan M. Stagg, Daniel E. Resasco

Ni-based catalysts for methane conversion with carbon dioxide. Catalyst pellet deformation induced by coking and gasification Original Research Article
Pages 551-559
L.A. Rudnitsky

Carbon formation from decomposition of CH4 on supported Ni catalysts Original Research Article
Pages 561-566
R. Lødeng, M. Barrè-Chassonnery, M. Fathi, O.A. Rokstad, A. Holmen

On limitations of regenerating an HZSM-5 catalyst for the MTG Process Original Research Article
Pages 567-572
A.T. Aguayo, A.G. Gayubo, J.M. Ortega, A.L. Morán, J. Bilbao

Asymptotic behavior during sintering of supported catalysts Original Research Article
Pages 573-583
Gustavo A. Fuentes, Elizabeth Salinas-Rodríguez

Sintering and redispersion of supported metals: Perspectives from the literature of the past decade Original Research Article
Pages 585-592
Calvin H. Bartholomew

The existence of an unusual reversible deactivation phenomenon associated with preferential surface segregation in bimetallic systems Original Research Article
Pages 593-599
R.T.K. Baker, A. Chambers, C. Park, N.M. Rodriguez

Vaporization-assisted degradation of high temperature combustion catalysts Original Research Article
Pages 601-607
J.G. McCarty, K.-H. Lau, D.L. Hildenbrand

Deactivation by sintering and coking of Sol-Gel NiO-Al2O3-TiO2 hydrogenation catalysts Original Research Article
Pages 609-616
J.C. Rodríguez, T. Viveros, A. Monzón

Sintering of Ni/SiO2 catalysts prepared by impregnation and deposition-precipitation during CO hydrogenation Original Research Article
Pages 617-624
G. Martra, H.M. Swaan, C. Mirodatos, M. Kermarec, C. Louis

An experimental protocol for studying kinetics and catalyst deactivation: Application to heptane reforming on Pt-Re/Al2O3 Original Research Article
Pages 625-638
K. Liu, S.C. Fung, T.C. Ho, D.S. Rumschitzki

Characterizing the framework demetallation of environmentally relevant zeolites using IR, NMR and neutron diffraction techniques Original Research Article
Pages 639-646
Mark T. Paffett, János Szanyi, Richard M. Jacubinas, Kevin C. Ott, Robert VonDreele, Craig D. Hughes, William L. Earl

Study of the deactivation of an HY zeolite pellet using 129Xe NMR spectroscopy and 1H NMR imaging Original Research Article
Pages 647-654
T. Domeniconi, J.-L. Bonardet, M.-A. Springuel-Huet, J. Fraissard, J.-M. Dereppe

AFM study of carbon formation on a manganese oxide catalyst Original Research Article
Pages 655-663
N. Batina, L.M. Ioffe, Y.G. Borodko

Novel regeneration method for deactivated noble metal catalysts Original Research Article
Pages 665-672
L.A. Camacho, C. Park, N.M. Rodriguez

Estimation of reversible and irreversible coke by transient experiments Original Research Article
Pages 673-680
Mikael Larsson, Niklas Henriksson, Bengt Andersson

Deactivation studies of Ni/Al2O3 ZSM-5 catalysts: Effect of nickel incorporation Original Research Article
Pages 681-686
Jolanta R. Grezechowiak, Aleksandra Masalska, Leszek Kępiński, Jacek Rynkowski

Author index
Pages 687-689