Catalysis of Organic Reactions

Front cover......Page 1
Contents......Page 12
Board of Editors......Page 22
Chronology of Organic Reaction Society Conferences......Page 23
Preface......Page 24
I. Symposium on Catalytic Hydrogenation......Page 26
a. Hydrogenation on Raney-Type Catalysts......Page 27
Introduction......Page 28
ECH of Polycyclic Aromatics......Page 29
ECH of Lignin Models and Lignins......Page 31
Synthetic Aspects of Electrohydrogenation of Nitro Compounds at Raney Metal (RM) Electrodes in Aqueous Alcohols......Page 33
Mechanistic Aspects of Electrohydrogenation of Nitro Compounds at Raney Metal (RM) Electrodes in Aqueous Alcohols......Page 37
Conclusions......Page 40
References......Page 41
Introduction......Page 44
Experimental Section......Page 46
Results and Discussion......Page 48
References......Page 51
Introduction......Page 52
Results and Discussion......Page 53
Experimental Section......Page 59
References......Page 60
Introduction......Page 62
Results and Discussion......Page 64
Experimental Section......Page 67
References......Page 68
Introduction......Page 70
Experimental Section......Page 71
Results and Discussion......Page 72
References......Page 74
b. Anchored and Supported Hydrogenation Catalysts......Page 76
Results and Discussion......Page 78
Experimental Section......Page 81
References......Page 82
Introduction......Page 84
Results and Discussion......Page 85
References......Page 87
Introduction......Page 90
Acknowledgements......Page 93
References......Page 94
Introduction......Page 96
Results and Discussion......Page 97
Experimental Section......Page 99
References......Page 100
Introduction......Page 102
Results......Page 104
Discussion......Page 106
Conclusions......Page 108
References......Page 109
Experimental Section......Page 110
Results......Page 112
Discussion......Page 113
Acknowledgements......Page 114
References......Page 115
Introduction......Page 116
Experimental Section......Page 117
Results and Discussion......Page 118
References......Page 124
Introduction......Page 126
Experimental Section......Page 127
Results and Discussion......Page 128
Conclusions......Page 133
References......Page 134
DeLinkTM – a New Generation of Pd/C Catalysts......Page 136
Other Supported Palladium Catalysts......Page 142
Pt/C Powder Catalyst......Page 143
Supported Rh Homogeneous Catalyst: Tethering Technology......Page 144
References......Page 146
c. Hydrogenation of Interesting Substrates and Renewable Sources......Page 148
Introduction......Page 150
Results and discussion......Page 151
Effect of Catalyst Concentration......Page 152
Effect of Hydrogen Pressure......Page 153
Effect of Temperature......Page 154
Product Viscosity......Page 155
References......Page 159
Introduction......Page 160
Experimental Section......Page 161
Results and Discussion......Page 162
References......Page 167
Introduction......Page 170
Experimental Section......Page 171
Results and Discussion......Page 175
References......Page 179
Introduction......Page 180
Background......Page 181
Results and Discussion......Page 184
Experiment II rose sharply from the initial pH of 3 to a final pH of 9. The......Page 185
Experiment I and II is shown in Figure 5. Under the reaction conditions......Page 186
References......Page 188
Introduction......Page 190
Experimental Section......Page 191
Results and Discussion......Page 193
Acknowledgements......Page 197
References......Page 198
a. Featured Technology Area: Combinatorial and Parallel Methods in Catalyst Design, Optimization and Utilization......Page 200
Introduction......Page 202
Results and Discussion......Page 204
Experimental Section General procedure for Suzuki coupling reaction. A 100 mL of round-bottomed......Page 205
General procedure for the Negishi coupling. A solution of o-tolylmagnesium......Page 207
References......Page 208
Introduction......Page 210
Results and Discussion......Page 211
Interactions between catalyst components in lead based systems......Page 212
Lead co-catalysts......Page 214
Optimization of lead based DPC catalysts......Page 216
Catalytic packages containing NaBr......Page 217
Conclusions......Page 218
References......Page 219
Introduction......Page 220
Experimental Section......Page 221
Results and Discussion......Page 222
References......Page 225
Introduction......Page 226
Results and Discussion......Page 227
Experimental Section......Page 232
References......Page 233
Introduction......Page 236
Results and Discussion......Page 237
Pd nanoclusters, sodium triethylborohydride (Na(Et)3BH) method. This is a......Page 239
References......Page 240
b. General Papers......Page 241
Introduction......Page 242
Results and Discussion......Page 243
References......Page 251
Introduction......Page 252
Results and Discussion......Page 256
References......Page 260
Introduction......Page 262
Results and Discussion......Page 263
Experimental Section......Page 265
References......Page 266
Introduction......Page 268
Experimental Section......Page 269
Results and Discussion......Page 270
R eferences......Page 275
Introduction......Page 276
Results and Discussion Process Description......Page 278
Reactivity......Page 281
Characterizations......Page 282
Effect of Process Parameters on the Avada Process......Page 284
References......Page 285
Introduction......Page 286
Results and Discussion......Page 288
Conclusions......Page 290
References......Page 291
Introduction......Page 292
Experimental Section......Page 293
Results and Discussion......Page 296
Acknowledgments......Page 302
References......Page 303
Introduction......Page 304
Results and Discussion......Page 306
Conclusions......Page 315
References......Page 316
Introduction......Page 318
Results and Discussion......Page 319
Entry Catalyst t (h) Sel (%) Eq/ax......Page 321
Experimental Section......Page 325
References......Page 326
Introduction......Page 328
Experimental Section......Page 329
Results......Page 330
Discussion......Page 334
References......Page 336
What is Scaleup?......Page 338
Reaction Kinetics......Page 339
Catalyst Handling......Page 342
Heat Transfer......Page 345
Mass Transfer, Mixing......Page 346
Mass Transfer, Crystallization and Cake Washing......Page 347
Other Brief Topics, Including Economics......Page 348
References......Page 350
III. Symposium on Acid-Base Catalysis......Page 351
Abstract......Page 352
Introduction......Page 353
Experimental Section......Page 354
Results and Discussion......Page 355
References......Page 360
Introduction......Page 362
Experimental Section......Page 363
Results and Discussion......Page 365
Acknowledgements......Page 369
References......Page 370
Introduction......Page 372
Results and Discussion......Page 373
Experimental Section......Page 380
References......Page 381
Introduction......Page 382
References......Page 386
Introduction......Page 388
Results......Page 389
Mass of molecular ion Products H2 D2 Relative amount (%) in D2 reaction......Page 392
Discussion......Page 393
Condensation and Hydrogenation Products......Page 396
References......Page 397
Introduction......Page 398
Results and Discussion......Page 400
Esterification of succinic acid......Page 401
Experimental Methods and Analysis Esterification of lactic acid......Page 402
References......Page 403
Introduction......Page 404
Results and Discussion......Page 406
References......Page 408
Introduction......Page 410
Results and Discussion......Page 411
Experimental Section......Page 415
References......Page 416
IV. Symposium on Catalytic Oxidation......Page 417
Experimental Section Catalyst preparation. One library of catalysts, indicated below with the name......Page 418
Catalyst testing. The materials prepared were tested in a quartz......Page 420
Results and Discussion Effect of catalyst composition. Figures 1 and 2 show the effect on the......Page 421
Effect of W/F variation. In order to examine in more detail the reaction......Page 424
References......Page 427
Introduction......Page 428
Results and Discussion......Page 429
Acknowledgements......Page 435
References......Page 436
Introduction......Page 438
Results and Discussion......Page 439
Experimental Section......Page 445
References......Page 446
Introduction......Page 448
Results and Discussion......Page 449
References......Page 452
Results and Discussion......Page 454
Experimental Section......Page 456
References......Page 458
a. General Papers......Page 459
Palladium-Catalyzed Annulation of Alkynes......Page 460
Palladium Migration Chemistry......Page 466
References......Page 472
Introduction......Page 474
References......Page 482
Introduction......Page 484
Results and Discussion......Page 485
Syntheses of complexes 1 – 4. To a stirred suspension of [acacRh(CO)2]......Page 492
References......Page 493
Introduction......Page 496
Results and Discussion......Page 497
Experimental Section......Page 500
References......Page 501
Introduction......Page 504
Results and Discussion......Page 505
Experimental Section......Page 507
References......Page 508
b. Deprotection......Page 509
Introduction......Page 510
Results and Discussion......Page 511
References......Page 517
Introduction......Page 518
Results and Discussion......Page 519
Experimental Section......Page 521
References......Page 522
Abstract......Page 524
Experimental Section......Page 525
Results and Discussion......Page 526
References......Page 534
c. Asymmetric Catalysis......Page 536
Introduction......Page 538
Results and Discussion......Page 539
Experimental Section......Page 541
References......Page 542
Results and Discussion......Page 544
Experimental Section General procedure for phosphinito ligands. To a flask containing the N,C-protected......Page 547
References......Page 548
Introduction......Page 550
Results and Discussion......Page 554
Conclusion......Page 558
References......Page 559
Introduction......Page 560
Results......Page 561
Acknowledgements......Page 564
References......Page 565
Introduction......Page 566
Experimental Section......Page 567
Results and Discussion......Page 568
References......Page 570
Introduction......Page 572
Results and Discussion......Page 573
Acknowledgements......Page 575
References......Page 576
Introduction......Page 578
Results and Discussion......Page 579
Experimental Section......Page 583
References......Page 584
Author Index......Page 586
Keyword Index......Page 592
Back cover......Page 602