Carbon-Centered Radicals I

General introduction....Pages 1-5
1.0 Introduction....Pages 1-1
1.1.1 Primary alkyl radicals....Pages 2-6
1.1.2 Secondary alkyl radicals....Pages 6-11
1.1.3 Tertiary alkyl radicals....Pages 11-19
1.1.4 Cyclo alkyl radicals....Pages 19-21
1.1.5 Acyl radicals....Pages 21-21
1.1.7 Radicals with 3 conjugated electrons....Pages 22-24
1.1.8 Radicals with 5 conjugated electrons....Pages 24-30
1.1.9 Radicals with 7 conjugated radicals....Pages 30-40
1.1.11 Radicals with 11 conjugated electrons....Pages 40-41
1.1.12 Radicals with 13 conjugated electrons....Pages 41-47
1.1.13 Radicals with 15 conjugated electrons....Pages 48-48
1.1.15 Polymer radicals....Pages 49-51
1.2 Cross reactions: Two carbon-centered radicals....Pages 51-56
1.3.1 Primary alkyl radicals....Pages 56-58
1.3.2 Secondary alkyl radicals....Pages 59-59
1.3.3 Tertiary alkyl radicals....Pages 60-61
1.3.4 Cyclic alkyl radicals....Pages 61-62
1.3.5 Acyl radicals....Pages 62-63
1.3.6 Radicals with 7 conjugated electrons....Pages 63-63
1.3.8 Radicals with 13 conjugated electrons....Pages 64-75
1.3.9 Radicals with 19 conjugated electrons....Pages 75-75
References for 1....Pages 76-77
2.0 Introduction....Pages 79-80
2.1 Primary alkyl radicals....Pages 80-88
2.2 Noncyclic secondary alkyl radicals....Pages 97-110
[CCl3] - [C4H9]....Pages 111-125
[C4H9] - [C10H17O4]....Pages 126-140
2.4 Cyclic and bicyclic radicals....Pages 141-155
2.5 Benzyl radicals....Pages 155-158
2.6 Vinyl, acyl and phenyl radicals....Pages 158-168
References for 2....Pages 169-170
3.0 Introduction....Pages 171-171
3.1 Fragmentation reactions....Pages 172-181
3.2.1 Aryl migration....Pages 182-182
3.2.2 Vinyl migration....Pages 183-184
3.2.3 Hydrogen-atom migration....Pages 184-190
3.2.4 Heteroatom migration....Pages 190-193
3.2.5 Other migrations....Pages 194-195
3.2.6.1 Butenyl and related radicals....Pages 195-196
3.2.6.2 Pentenyl and related radicals....Pages 196-197
3.2.6.3 Hexenyl and related radicals....Pages 197-211
3.2.6.4 Radicals related to heptenyl and higher homologs....Pages 211-213
3.2.7.1 Three-membered rings....Pages 214-224
3.2.7.2 Four-membered rings....Pages 224-228
3.2.7.3 Five-membered rings....Pages 228-230
3.2.7.4 Six-membered and higher rings....Pages 230-231
3.2.7.5 Other ring openings....Pages 231-232
3.2.8 Ring expansion....Pages 232-233
3.3 Conformational change....Pages 234-245
3.4 Configurational change....Pages 246-253
3.5 Valence bond tautomerism....Pages 253-253
References for 3....Pages 254-257
Remarks, TOCs of Vols. 13 and 18....Pages 1-8
I Organic and inorganic radicals....Pages 1-52
II Not completely identified e{-} and/or OH-adducts to compounds....Pages 1-3
III Radicals derived from polymers and from high molecular biological compounds....Pages 1-2
IV Biradicals....Pages 1-4
V Compounds with known redox potentials....Pages 1-4
VI Carbenes....Pages 1-3