Carbon-Centered Radicals I

General introduction....Pages 1-4
1.0 Introduction....Pages 5-5
1.1.1 Primary alkyl radicals....Pages 6-13
1.1.2 Secondary alkyl radicals....Pages 14-20
Part 1....Pages 21-30
Part 2....Pages 31-40
1.1.4 Cycloalkyl radicals....Pages 41-48
1.1.5 Acyl radicals....Pages 48-49
1.1.7 Aryl radicals....Pages 49-50
1.1.8 Vinyl radicals....Pages 50-52
1.1.9 Radicals with 3 conjugated pi-electrons....Pages 52-59
Part 1....Pages 59-70
Part 2....Pages 71-83
1.1.11 Radicals with 7 conjugated pi-electrons....Pages 83-95
1.1.12 Radicals with 9 conjugated pi-electrons....Pages 96-97
1.1.13 Radicals with 11 conjugated pi-electrons....Pages 97-98
1.1.14 Radicals with 13 conjugated pi-electrons....Pages 98-104
1.1.15 Radicals with 19 conjugated pi-electrons....Pages 104-114
1.1.17 Radicals with 25 conjugated pi-electrons....Pages 114-115
1.1.20 Polymer radicals....Pages 115-125
1.2 Cross reactions....Pages 125-127
1.3 Relative rate constants....Pages 127-129
References for 1.1 - 1.3....Pages 130-134
2.0 Introduction....Pages 135-136
Part 1....Pages 136-147
Part 2....Pages 148-159
Part 1....Pages 160-167
Part 2....Pages 168-176
2.3 Cycloalkyl radicals....Pages 176-188
2.4 Cumyl radical....Pages 188-189
2.5 Alkyl radicals containing heteroatoms....Pages 189-202
Part 1....Pages 202-212
Part 2....Pages 213-223
Part 3....Pages 224-233
2.7 Vinyl and acyl radicals....Pages 234-234
2.8 Aromatic radical cations....Pages 235-235
2.9 Polymer radicals....Pages 236-248
References for 2....Pages 248-251
3.0 Introduction....Pages 252-252
3.1 Fragmentation reactions....Pages 253-262
3.2.1 Aryl migration....Pages 262-266
3.2.2 Vinyl migration....Pages 266-267
3.2.3 Hydrogen-atom migration....Pages 267-270
3.2.4 Heteroatom migration....Pages 270-274
3.2.5.1 Butenyl and related radicals....Pages 274-275
Part 1....Pages 275-284
Part 2....Pages 285-293
3.2.5.3 Heptenyl, octenyl and related radicals....Pages 294-295
3.2.6 Ring-opening....Pages 295-308
3.2.7 Conformational change....Pages 308-313
3.2.8 Configurational change....Pages 313-315
References for 3....Pages 315-317
Errata....Pages 1-1