A Textbook of Physical Chemistry: States of Matter and Ions in Solution (SI Unit), 5e, Volume 1

Title
Contents
1. GASEOUS STATE
	1.1 The Three States of Matter
	1.2 Experimentally Derived Gas Laws
	1.3 Equation of State
	1.4 Application of Equation of State
	1.5 Concepts of Partial Pressure and Partial Volume
	1.6 The Kinetic Gas Equation
	1.7 Some Derivation from the Kinetic Gas Equation
	1.8 Real Gases
	1.9 Van Der Waals Equation of State for a Real Gas
	1.10 Other Equations of State for Real Gases
	1.11 Reduction of Van Der Waals Equation to Virial Equation
	1.12 Critical Constants
	1.13 Continuity of State
	1.14 Isotherms of Van Der Waals Equation
	1.15 The Law of Corresponding States
	1.16 Maxwellian Distribution of Molecular Speeds
	1.17 Derivation of Some Expressions from the Maxwell Distribution
	1.18 Barometric Distribution Law
	1.19 Molecular Collisions in a Gas
	1.20 Viscosity
	1.21 Self Diffusion and Effusion Processes
	1.22 Thermal Conductivity
	1.23 Electrical Conductivity
	1.24 Law of Equipartition of Energy
	1.25 Degress of Freedom and the Average Energy of a Molecule
	1.26 Heat Capacities
	1.27 Comparison of Theoretical and Experimental Heat Capacities
2. PHYSICAL PROPERTIES OF LIQUIDS
	2.1 Introduction
	2.2 Vapour Pressure
	2.3 Viscosity
	2.4 Surface Tension
3. The Solid state
	3.1 Introduction
	3.2 Faces, Edges and Interfacial Angle of a Crystal
	3.3 Haüy’s Idea and Space Lattice
	3.4 Crystal Systems
	3.5 The Fourteen Bravais Lattices
	3.6 Point Groups
	3.7 Space Groups
	3.8 Crystal Cleavage and Development of Its Faces
	3.9 Designation of Planes
	3.10 Interplanar Distances for Cubic Systems
	3.11 Diffraction of Electromagnetic Radiation
	3.12 Diffraction of X-rays by Crystals
	3.13 Bragg’s Equation
	3.14 Powder Method
	3.15 Diffraction Pattern of a Cubic System
	3.16 Crystal Structure of Sodium Chloride
	3.17 Crystal Structure of Potassium Chloride
	3.18 Density of Cubic Crystals
	3.19 Classification of Crystals Based on Bond Type
	3.20 General Discussion on Structure of Liquids
		Annexure I: Symmetry Elements and Symmetry Operations
		Annexure II: Supplementary Materials
4. IONIC EQUILIBRIA
	4.1 The Dissolution Process
	4.2 Classification of Substances
	4.3 The Arrhenius Theory of Dissociation
	4.4 Effect of Dilution on Degree of Dissociation
	4.5 Dissociation of Pure Water
	4.6 The pH-Scale
	4.7 Classification of Acids and Bases in Water
	4.8 Exact Treatment for lonization of a Monoprotic Acid
	4.9 Exact Treatment for lonization of a Base
	4.10 Exact Treatment for lonization of a Diprotic Acid
	4.11 Dissociation of Polyprotic Acid
	4.12 Solutions of Salts in Water: Hydrolysis
	4.13 Exact Treatment of Hydrolysis of Salt Formed from a Weak Acid and a Strong Base
	4.14 Exact Treatment of Hydrolysis of Salt Formed from a Strong Acid and a Weak Base
	4.15 Exact Treatment of Hydrolysis of Salt Formed from a Weak Acid and a Weak Base
	4.16 Exact Treatment of Hydrolysis of Salt Involving Weak Conjugate Cation and an Amphiprotic Anion
	4.17 Exact Treatment of Hydrolysis of Salt Involving Strong Conjugate Cation and Amphiprotic Anion
	4.18 Hydrolysis of a Salt Containing Multivalent Cation or Anion
	4.19 Exact Treatment of a Mixture of a Weak Acid (HA) and Salt of Its Conjugate Base (MA)
	4.20 Exact Treatment of a Mixture of a Weak Base (BOH) and Salt of Its Conjugate Acid (BA)
	4.21 Exact Treatment of a Mixture of a Strong Acid and a Weak Acid
	4.22 Exact Treatment of a Mixture of Two Weak Acids
	4.23 Buffer Solutions
	4.24 Acid-Base Indicators
	4.25 Titration of a Strong Monoprotic Acid with a Strong Base
	4.26 Titration of a Weak Monoprotic Acid with a Strong Base
	4.27 Titration of a Weak Base with a Strong Monoprotic Acid
	4.28 General Treatment of Titration of an Acid with a Strong Base
	4.29 Titration of a Dibasic Acid with a Strong Base
	4.30 General Treatment of Titration of a Diprotic Acid with a Strong Base
	4.31 Titration of Sodium Carbonate Solution with Hydrochloric Acid
	4.32 Solubility Product
	4.33 Equilibria Involving Complex Ions
	4.34 Amphoterism
	4.35 Some Concepts of Acids and Bases
	4.36 Acid and Base Strengths and Structure
5. CONDUCTANCE
	5.1 Introduction
	5.2 Metallic Conduction
	5.3 Electrolytic Conduction
	5.4 Electrolysis
	5.5 Conductance of Solutions
	5.6 Equivalent and Molar Conductivities
	5.7 Variation of Conductivity and Molar Conductivity with Concentration
	5.8 Conductivity at High Electric Fields and High Frequencies
	5.9 Kohlrausch’s Law of Independent Migration of Ions
	5.10 Values of Limiting Ionic Molar Conductivities
	5.11 Transport Numbers
	5.12 Ionic Speed and Ionic Mobility
	5.13 The Walden’s Rule
	5.14 Application of Conductance Measurements
Appendix I: A Note on Changing Concepts in Physical Chemistry
Appendix II: Units and Conversion Factors
Index