11th International Congress on Catalysis - 40th Anniversary. Baltimor, 1996

Front Cover......Page 1
11th International Congress on Catalysis-40th Anniversary......Page 4
Copyright Page......Page 5
Table of Contents......Page 6
Preface......Page 20
P-1 Driving Forces for Innovation in Applied Catalysis......Page 22
P-2 Constrained Geometry and Other Single Site Metallocene Polyolefin Catalysts: A Revolution In Olefin Polymerization......Page 32
P-3 Characterization and Chemical Design of Oxide Surfaces......Page 42
P-4 Photocatalysis: State of the Art and Perspectives......Page 56
P-5 Towards Molecular Design of Solid Catalysts......Page 72
R-1 A Retrospective View of Advances in Heterogeneous Catalysis: 1956-1996, Science......Page 84
R-2 A Retrospective View of Advances in Heterogeneous Catalysis: 1956-1996 Technology......Page 90
A-1 An Example of Novel Basic Catalysts: The Aluminophosphate Oxynitrides or “AIPONs......Page 98
A-2 Reaction Kinetics of the Hydrodenitrogenation of Decahydroquinoline over NiMo(P)/Al2O3 Catalysts......Page 108
A-3 Effect of Spillover Hydrogen on Amorphous Hydrocracking Catalysts......Page 118
A-5 Hydrodesulfirization of Benzothiophene Catalyzed by Molybdenum Sulfide Cluster Encapsulated into Zeolites......Page 128
A-6 Role of Adsorbed Hydrogen Species on Ruthenium and Molybdenum Sulfides. Characterization by Inelastic Neutron Scattering, Thermoanalysis Methods and Model Reactions......Page 138
A-7 Characterization of a Zeolite Membrane for Catalytic Membrane Reactor Application......Page 148
A-8 Catalytic Reduction of SO3 Stored in SOx Transfer Catalysts - A Temperature- Programmed Reaction Study......Page 158
A-9 Effect of Tunnel Structures of BaTi4O9 and Na2Ti6O13 on Photocatalytic Activity and Photoexcited Charge Separation......Page 164
A-10 Organochromium Complexes in Homogeneous Olefin Polymerization......Page 174
A-11 Selective Catalytic Oxidation with Air of Glycerol and Oxygenated Derivatives on Platinum Metals......Page 182
A-12 Selective Methylation of Catechol: Catalyst Development and Characterisation......Page 192
A-13 Selective Oxidation with Copper Complexes Incorporated in Molecular Sieves......Page 202
A-14 Discovering the Role of Au and KOAc in the Catalysis of Vinyl Acetate Synthesis......Page 212
A-15 Formation of Citraconic Anhydride by Vapor-Phase Decarboxy-Condensation of Pyruvic Acid......Page 222
A-16 Heterogeneous Enantioselective Dehydration of Butan-2-ol......Page 232
A-17 Enantioselective Hydrogenation Catalysed by Palladium......Page 242
A-18 Stereochemical Studies of the Enantio-differentiating Hydrogenation of Various Prochiral Ketones over Tartaric Acid-Modified Nickel Catalyst......Page 252
A-19 Enantio-differentiation over Heterogeneous Catalysts. The Shielding Effect Model......Page 262
A-20 Racemization of (1S)-(-)-exo-2,4-Dideuteroapopinene over Pd: Evidence for an Intramolecular 1,3-Deuterium Shij......Page 272
A-21 Fe/MgO Catalysts for the Selective Hydrogenation of Nitriles......Page 278
A-22 Selective Synthesis of Ethylenediamine from Ethanolamine over Modified H-Mordenite Catalyst......Page 288
A-23 Competitive Reaction Pathways in Propane Ammoxidation over V-Sb-Oxide Catalysts: An IR and Flow Reactor Study......Page 298
A-25 ‘Seeing’ the Active Site in Catalysis. STM and Molecular Beam Studies of Surface Reactions......Page 308
A-26 Catalytic Formation of Carbon-Carbon Bonds in Ultrahigh Vacuum: Cyclotrimerization of Alkynes on Reduced TiO2 Surfaces......Page 318
A-27 A New Approach to Understanding the Rochow Process: Synthesis of Methylchlorosilanes from CH3 + C1 Monolayers on Cu3Si in Vacuum......Page 328
A-28 Ruthenium as Catalyst for Ammonia Synthesis......Page 338
A-29 Surface-Structure-Dependent Reaction Pathways of Methyl Groups on NI(lO0) and NI(111) Surfaces......Page 348
A-30 Normalization by oxygen Uptake of the Rates of Oxidative Dehydrogenation of Methanol and Ethanol......Page 358
A-31 Some Evidences of a Bifunctional Mechanism for the Reduction of NO on Pd Based Catalysts......Page 366
A-32 Characterization of Pd-based Automotive Catalysts......Page 376
A-33 Process Development for the Selective Hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32)......Page 390
A-34 Catalytic Fluorination over Chromium Oxides. Preparation of Hydrofluorocarbons......Page 400
A-35 Oxidative Coupling of Methane to Ethylene with 85% Yield in a Gas Recycle Electrocatalytic or Catalytic Reactor-Separator......Page 408
A-36 The Active Oxygen for Direct Oxidation of Methane to Methanol in the Presence of Hydrogen......Page 418
A-37 Photocatalytic Production of Methanol and Hydrogen from Methane and Water......Page 428
A-38 Role of A- and B-Cations in Catalytic Property of Substituted Hexaaluminate (ABAI11O19-α) for High Temperature Combustion......Page 438
A-39 Au/Metal Oxides for Low Temperature CO Oxidation......Page 448
A-40 Photocatalytic Oxidation of Air Contaminants by Chlorine (Cl) or Hydroxyl (OH) Radicals or Holes (h+): Mechanistic Correlations......Page 456
A-41 Partial Oxidation of Methane to Synthesis Gas over Ru/TiO2 Catalysts......Page 464
A-42 The Oxidative Transformation of Methane over the Nickel-Based Catalysts Modified by Alkali Metal Oxide and Rare Earth Metal Oxide......Page 474
A-43 Design of Stable Catalysts for Methane-Carbon Dioxide Reforming......Page 484
A-44 Comparison of Perovskite and Hexaaluminate-type Catalysts for CO/H2-fieled Gas Turbine Combustors......Page 494
A-45 Hydrocarbon Activation and Oxidation on Transition Metal Mixed Oxides: Ft-IR and Flow Reactor Studies......Page 504
A-46 Biomimetic Oxidation on Fe Complexes in Zeolites......Page 514
A-4 A Molecular Approach to Synergy Generation in Co-Mo Binary Sulfide Catalysts for Hydrodesulfurization......Page 524
A-24 Electrochemical Promotion of NO Reduction by CO and by Propene......Page 534
B-1 Promotion of Molecular Hydrogen on Solid Acid Cracking Activity......Page 544
B-2 Selective Isomerization of Alkanes on Supported Tungsten Oxide Acids......Page 554
B-3 Tungsta and Platinum-Tungsta Supported on Zirconia Catalysts for Alkane Isomerization......Page 564
B-4 n-Butane Isomerization on Ni-promoted Sulfated Zirconia Catalysts......Page 574
B-5 Rare Earth Modified Silica-Aluminas as Supports for Bifunctional Catalysis......Page 584
B-6 What NMR Has Told Us about Solid Acidity......Page 594
B-7 Novel Microporous Solid “Superacids”: CsxH3-xPW12O40 (2<=x<= 3)......Page 602
B-8 Comparison of the Reactivities of H3PW12O40 and H4SiW12O40 and their K+, NH4+ and Cs+ Salts in Liquid Phase Isobutane/Butene Alkylation......Page 612
B-9 Coupling of Alcohols to Ethers: the Dominance of the Surface SN2 Reaction Pathway......Page 622
B-10 Characterization of Two Different Framework Titanium Sites and Quantification of Extra-famework Species in TS-1 Silicalites......Page 632
B-11 Influence of Sulfur Dioxide on the Selective Catalytic Reduction of NO by Decane on Cu Catalysts......Page 642
B-12 CoPt Clusters in NaMordenites as Catalysts for SCR of NOx......Page 652
B-13 Decomposition of Nitrous Oxide over ZSM-5 Catalysts......Page 662
B-14 On the Role of Free Radicals NO2 and O2 in the Selective Catalytic Reduction (SCR) of NOx with CH4 over CoZSM-5 and HZSM-5 Zeolites......Page 672
B-15 An Infared Study of NO Reduction by CH4 Over Co-ZSM-5......Page 682
B-16 Precious Metal Loaded In/H-ZSM-5 for Reduction of Nitric Oxide with Methane in the Presence of Water Vapor......Page 692
B-17 Interfacial RhO2/CeO2 Sites as Locations for Low Temperature N2O Dissociation......Page 702
B-18 The Activity of VOx/ZrO2 for the Selective Catalytic Reduction of NO......Page 712
B-19 Selective Reduction of NOx by Propene over Au/γ-Al2O3 Catalysts......Page 722
B-20 The Role of Surface-Generated Gas-Phase Methyl Radicals in the Reduction of NO by CH4 over a Sr/La2O3 Catalyst......Page 732